Two‐phase production of cyclohexene and cyclooctene oxides in water as an approach to pollution prevention

Liquid–liquid two‐phase epoxidation from cyclohexene and cyclooctene in aqueous potassium peroxymonosulfate (commercially available as Oxone^®) solution was studied as an application in pollution prevention. To avoid potential emissions of volatile organic compounds an aqueous solution was employed to replace the usual chlorinated solvents used in epoxide production. A droplet column reactor and stirred tank reactor were used to investigate two‐phase synthesis of epoxide. An aqueous Oxone^® solution was used to oxidize a dispersion of alkene droplets and form epoxide. The study of aqueous epoxidation in both reactors showed that the epoxidation of alkenes can be represented as a first order reaction with respect to alkene. The salting out effect of Oxone^® concentration was studied in both reactors and found to be very similar at optimal conditions. In comparing the two reactors, it was found that the droplet column reactor produces larger quantities of product per unit reactor volume for the same reaction time. The objective of this study is to provide an alternative reactor design and synthesis route that can meet pollution prevention goals. Copyright © 2004 Society of Chemical Industry     

Coupling of free surface and groundwater flows

In this paper we present some preliminary results about the coupling of shallow water equations for free surface flows and Darcy equation for groundwater flows. A suitable set of interface conditions is discussed: the Beavers and Joseph formula for the bottom stress is used. An iterative algorithm to solve the coupled problem is proposed and some numerical results are presented.     

天铁炼钢厂四流中间包流场的水模实验及优化

介绍了天铁炼钢厂中间包水模实验原理和过程，分析了斜、直、圆三种型式挡渣墙模拟结果，提出了合理的挡渣控流方案，在生产实践中使用效果良好。     

煤代油方式的经济性分析

对两种煤代油方式——水煤浆和煤制混合煤气进行了燃料价格、设备投资及运行费用的分析对比。结果表明，两种代油方法均有可观的经济效益，燃料费用可分别节约52．4％和45．2％。如果原燃油工业炉窑由于工艺需要已装有除尘设备而又可用产生的蒸汽做雾化剂时，则水煤浆代油更具有经济优势。     

膜分离技术在水处理领域的应用

对2000年底巴黎“饮用水和工业用水制造领域中的膜技术”国际会议进行了简单的回顾，根据会议经历对当今膜分离技术在水处理领域的应用市场进行分析，提出今后液体膜分离技术的研究和发展的重点。最后对我国液体分离膜技术的发展提出一些建议。     

Bench-Scale Testing of Nanofiltration for Seawater Desalination

A dual-staged nanofiltration process is being evaluated as an alternative to reverse osmosis for seawater desalination. The primary goal of this system is to reduce energy consumption while producing potable water at an acceptable recovery rate. Investigation of this system at the bench-scale level focused on membrane surface characterization, ion rejection (including boron, bromide, and iodide rejection), and flux decline. Results from this study showed that two commercially available nanofiltration membranes can effectively desalinate seawater. Although fouling was apparent—and resulted in approximately 20% flux decline over 3 days—a critical flux was not identifiable. Operation of the system at different cross-flow velocities revealed the significance of hydrodynamic conditions on the polarization modulus, and hence on membrane performance.     

Particle Penetration through Inclined and L-Shaped Cracks

This paper presents a particle penetration model predicting particle penetration coefficient (Pp) through a narrow crack of arbitrary incline angles (θ). The objective was to simulate Pp for outdoor-to-indoor particle penetration for residential infiltration conditions. This model assumes laminar infiltration flow and considers particle deposition from both gravitational sedimentation and Brownian diffusion. For micron-sized particles, modeling results indicate that gravitational sedimentation is the major deposition mechanism. Pp increases monotonically with ∣θ∣ because effective particle sedimentation velocity (vs?cos?θ) decreases monotonically with ∣θ∣. For submicron-sized particles (0.1?μm), Brownian diffusion is the major particle deposition mechanism. Because Brownian diffusion is a nondirectional deposition mechanism, crack inclination did not affect Pp. This study applied this model to estimate Pp for L-shaped cracks, and validated modeling results with experiments. Experimental results indicated that inertial impaction and crack entrance cutoff effects were not significant particle deposition mechanisms for the test micron-sized particles. Gravitational sedimentation was the major deposition mechanism. An L-shaped crack can be simulated as the combination of horizontal and vertical sections. This model agreed reasonably with experimental results.     

特低渗油藏渗流特征及增产技术研究

从特低渗储层渗流机理研究出发，分析了其渗流规律——非达西渗流特征；根据储层中上覆岩石围压变化，通过室内试验表述了其对渗透率伤害。研究提出了改善渗流特征的注水条件、井网优化和压裂对策，可以有效提高这类油藏的开发效果。     

一种复合型数值方法的改进与算法实现

文中对原有的复合方法进行了改进,提出了一种新的复合型数值方法,这种方法解决了原方法求解含源项的问题时存在数值震荡的缺点。为了验证算法的有效性,对计算流体力学中一阶浅水波问题的两个典型的算例进行了数值模拟,在解的光滑性、锐利性等几个方面做了分析,结果表明改进后的方法既消除了数值震荡现象,又能准确地逼近真解,求出锐利的间断,是一种行之有效的数值方法。     

井冈山水厂设计体会

阐述水厂设计中对水厂规模、水源地、净水厂位置及净水工艺的确定过程，根据原水的特点，通过分析对无阀滤池进行改良。