Influence of the preparation conditions on the properties of gold catalysts for the oxidation of glucose

In this work, two deposition–precipitation methods for the preparation of gold catalysts for glucose oxidation were investigated. Thus far, gold colloids immobilized on carbon have been used for catalytic glucose oxidation, but the long-term stability of these systems was not sufficient. To improve the long-term stability we used the deposition–precipitation methods using NaOH (DP NaOH) or urea (DP urea) as precipitation agents as they were described by Haruta and Dekkers, respectively, using alumina as a support material. With these methods, it was possible to prepare highly active and selective catalysts which showed an excellent long-term stability. DP urea was found to be the preferred method, because in contrast to DP NaOH, no losses of gold occurred during the preparation, and it was possible to adjust various gold contents up to 10 wt% Au.     

结晶垢结垢过程的传热传质模型

通过对结晶垢结垢过程传热传质机理的分析,证明了垢层表面温度随时间的变化会对结垢过程产生重大影响.据此提出了考虑垢层表面温度变化的描述结垢过程的传热传质模型.对恒壁温和恒热流条件下的结垢过程进行了详尽的分析和讨论.结果表明,对恒壁温情况必须考虑垢层表面温度随时间的变化,这一变化是导致结垢过程渐近特性的重要原因之一;而对恒热流情况,垢层表面温度随时间的变化很小,可以忽略它所带来的对结垢过程的影响.与实验数据比较表明,模型预测是正确可靠的.     

有机固相沉积对储层的损害

定性分析有机同相沉积对储层的影响,定量研究有机固相沉积后储层的损伤情况.利用岩石-毛细管模型描述地层孔隙空间,并用孔隙度、渗透率与比面等的相互关系推导出有机同相沉积量与储地层参数的变化关系式.     

ENSO与我国东部夏季雨型异常关系的年代际变化

利用1951-2002年NCEP/NCAR再分析资料、CPC(气候预测中心)Nino3区海表温度序列和NOAA的ERSST资料,研究了ENSO与我国东部夏季雨型的相互关系及其年代际变化.结果表明:我国东部夏季雨型对ENSO事件的响应在1978年有一个明显的突变,在突变前,降水雨型与赤道东太平洋的海温为弱的负相关,而在突变后转为显著的正相关;滑动相关结果显示,近20 a是整个研究时段中二者相关性最强的时期;东亚夏季风和ENSO的相互关系在1978年也经历了一次明显的年代际变化,由弱的正相关转为显著的负相关.这可能是引起ENSO和夏季雨型异常关系年代际变化的原因.     

加权马尔可夫链预测模型的优化方法及应用

借鉴自回归模型,采取添加随机项的方法对加权马尔可夫链预测模型进行优化,并把优化后的模型应用于郑州市年降雨量的预测,通过与原模型和自回归模型预测结果的对比分析发现,优化后的模型弥补了原模型预测结果缺乏波动性的不足,同时使预测结果不仅在精度上有一定的提高,而且在趋势上更接近于实测值.     

Precipitation and stability of reversed austenite in 9Ni steel

A new method was used to analyze the factors affecting the precipitation of reversed austenite during tempering. The samples were kept at various tempering temperatures for 10 min and their length changes were recorded. Then, the precipitation of reversed austenite which led to the length reduction was shown by thermal expansion curves. The results show that the effects of process parameters on the precipitation of reversed austenite can be determined more accurately by this method than by X-ray diffraction...     

Influence of isothermal aging onσprecipitation in super duplex stainless steel

The time-temperature-transformation (TTT) curve of the 00Cr25Ni7Mo4N duplex stainless steel was obtained with a Formastot-digital thermal dilatometer,and the influence of isothermal aging on σ precipitation was studied by metallographic observation,X-ray diffraction (XRD),and transmission electron microscopy (TEM).The results show that the decomposition of ferrite phase is accompanied by the formation of σ phase at 750-1000℃,especially in the range of 800-900℃.The longer the aging time,the higher the amount of σ precipitation.The area fraction of various phases remains at a certain value upon the completion of ferrite deformation.The temperature of 850℃ is the most sensitive transaction temperature,the incubation time for the formation of o precipitation is less than 1 min,and aging for 20 min leads to the complete transformation of ferrite.The o phase is formed preferentially at the α/α/γ junction,and then grows along the α/α boundary in the matrix.     

Preparation and sintering of nano Fe coated Si3N4 composite powders

Fe/Si₃N₄ composite powder was synthesized by the heterogeneous precipitation-thermal reduction process, and then pressed into flakes under a pressure of 10 MPa. Flakes were sintered by pressureless and hot-pressing at 1 600 °C under 0.1 MPa N₂. The chemical composition, phases and microstructure of composite powder and sintered flakes were investigated by energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results show that the structure of composite powders is Si₃N₄ coated by nano Fe. The crystal phases of sintered flakes by pressureless are Fe(Si) compound, SiC and Si₃N₄. The crystal phases of the sintered samples by hot-pressing are Fe, Fe(Si) compound and Si₃N₄. It is found that crystal phases flakes obtained by pressureless and hot-pressing are very different. Foundation item: Project(50804016) supported by the National Natural Science Foundation of China     

黑龙江省夏季旱涝灾害区划及对策研究

采用全省81个站夏季6-8月气温、降水资料,计算变异系数;进行正态化处理,计算Z指数。确定重旱轻旱？重涝轻涝和降水、温度指标,求出发生概率结果进行灾害3级区划,即重？中？轻区划。另外进行了全省主旱区和主涝区区划,并提出了7点对策。     

ENSO事件对松花江流域夏季降水的影响

对1951—2000年的ENSO事件对松花江流域夏季(6—8月)降水的影响进行了分析,结果显示:赤道中东太平洋海温异常与松花江流域夏季降水有很好的相关性,特别是ENSO事件出现后,El Nino事件影响年通常对应于松花江流域夏季降水偏多,La Nina事件影响年松花江流域夏季降水则较常年偏少,且二者通过了置信度α=0.05的显著性检验.这种相关性可用于进行松花江流域夏季降水的预测.