PMO对GCr15轴承钢连铸坯中MnS夹杂物的影响

为了研究PMO对GCr15轴承钢连铸坯中MnS夹杂物的影响,首先采用自动扫描电镜(Aspex Explorer)分析脉冲磁致振荡(Pulse Magneto-Oscillation,PMO)技术对钢中MnS类夹杂物组成和形貌的影响,然后利用电子探针测量固液界面前沿的元素含量,并在此基础上,计算了PMO处理后MnS析出温度变化。结果表明,PMO处理促进了内弧1/4、中心和外弧1/4处的大于8 μm的MnS夹杂物数量百分比的降低;PMO处理后固液界面前沿S元素质量分数在试样凝固50%和70%处分别降低60%和36%,而Mn元素含量变化不大;同时,PMO处理可降低MnS夹杂物的析出温度。     

卷取温度对超低碳T-3CA第二相析出的影响

 为研究卷取温度对超低碳T-3 CA中第二相粒子析出行为的影响,采用金相、TEM等检测手段,分析了580、630、680 ℃ 3个典型卷取温度下超低碳T 3 CA中第二相粒子的析出特性,结果发现卷取温度越高,热轧形成的TiC粒子尺寸越粗大,分布越稀疏。结合相关动力学计算分析了卷取温度对TiC粒子沉淀析出时临界晶核尺寸、相对形核率、相对沉淀析出时间的影响。结果表明,随着卷取温度由580提高到680 ℃,TiC粒子沉淀析出时临界晶核尺寸增大约1.0 nm,相对形核率降低约1.0个数量级,相对沉淀析出孕育时间增大约0.8个数量级。     

Comparison of functional properties and secondary structures of defatted wheat germ proteins separated by reverse micelles and alkaline extraction and isoelectric precipitation

The functional properties and secondary structures of defatted wheat germ protein separated by reverse micelles (DWGRMPI) were investigated and compared with those of defatted wheat germ protein separated by alkaline extraction and isoelectric precipitation (DWGPI). The results showed that DWGRMPI had a higher nitrogen solubility index, fat absorption capacity, foaming capacity, foaming stability and emulsifying stability compared to DWGPI, whilst water holding capacity, surface hydrophobicity and emulsifying activity of DWGRMPI were relatively lower than those of DWGPI. DWGRMPI contained high levels of threonine, histidine, alanine, arginine, glycine, serine, cysteine, proline and especially lysine compared to DWGPI. The denaturation temperature and denaturation enthalpy of DWGPI were both lower than those of DWGRMPI, and DWGPI contained more random coil and less α-helix than DWGRMPI, which suggested that DWGPI has lost its ordered secondary structure. This may possibly due to the conditions the used in protein extraction.     

白酒中晶体状沉淀成因探析与预防

通过对白酒中晶体状沉淀的成因探析,探明了白酒中晶状沉淀的产生是由于加浆水硬度过大,所含的Ca2＋和SO42-形成白色晶体状沉淀CaSO4.2H2O,硬度越大、温度越低,沉淀也越多。通常情况下,采用软水加浆工艺,即可解决此类沉淀的产生,较为经济、简便。     

Regulating the multifactor during wet chemical synthesis to obtain calcium phosphate powders with controllable phase purity for bone repair

Calcium phosphate ceramics are widely used as bone repair materials owing to their excellent biocompatibility, bone conductivity, bone induction, and degradability. Although there are many methods for synthesizing calcium phosphate and controlling its phase composition, it is necessary to explore effective preparation methods by understanding the formation of calcium phosphate and its influencing factors. In this study, calcium phosphate powders with controllable phase compositions were synthesized using a wet chemical precipitation method by adjusting the process parameters (aging time, bipolar solution, initial Ca-P molar ratio, capping agent concentration, and system concentration). Subsequently, a certain biphasic proportion of (biphasic calcium phosphate, BCP) products was prepared, and pure (β-tricalcium phosphate, β-TCP) can be obtained according to the customer's requirements. BCP ceramics with desired phase compositions were obtained by pressing and sintering different calcium-deficient powders. Specifically, β-TCP powder with a purity of 99.83 wt% was obtained when the aging time, bipolar solution, initial Ca-P molar ratio, capping agent concentration, and system concentration were 0 h, 50% ethanol, 1, 0.27 M, and 0.0135 M, respectively. The BCP synthesized in this study shows great application potential in the field of bone tissue repair materials.     

化学沉淀法脱除焦化废水中氨氮的研究

采用化学沉淀法处理高浓度氨氮废水,研究了药剂配比、pH值等因素对氨氮去除率的影响。在适当的条件下,可得到纯净的MAP晶体,氨氮的去除率可达98%。在温度为100℃、加热3h将MAP分解后,分解物重复用于脱除废水中的氨氮,氨氮的去除率可达93%,既可大幅度降低药品成本,又可回收废水中的氨。     

9Cr马氏体耐热钢膨胀-温度曲线上的斜率变化研究

9Cr马氏体耐热钢在发生α→γ相变前的升温过程中其膨胀-温度曲线的斜率发生了偏折,偏折点处的温度为660 ℃左右.采用相同的升温速率将该钢样品升温至600、660和750℃三个温度,保温15 min后水淬,利用金相显微镜和扫描电镜分析各样品中组织的差异.研究结果表明,9Cr钢加热至660 ℃和750℃的样品中析出相的数量较600℃明显增加,因此钢中碳氮化物在偏折点温度处的大量析出是膨胀曲线斜率发生明显改变的原因.     

Fe_(16)N_2 的沉淀效应

含氮马氏体室温时效和低于１７５℃回火时有Ｆｅ１６Ｎ２沉淀。Ｆｅ１６Ｎ２的沉淀效应显著,于１００℃回火时沉淀效应最大,ＨＶ、ｃ／ａ比和α（２２０）半高宽均达到最大值。Ｆｅ１６Ｎ２淀淀具有很高的强化效果,纯铁和２０钢渗氮后于１００℃回火,硬度分别提高５８％和６２％。Ｆｅ１６Ｎ２的沉淀效应具有广泛的应用前景     

温度对Ni-Al-Cr合金沉淀影响的微观相场模拟

基于三元微观相场动力学模型,结合原子图像和体积分数等手段模拟了Ni75Al6Cr19合金在不同温度下的沉淀行为。结果表明:随着时效温度从873 K升高至1 023 K,Ni75Al6Cr19合金由DO22和L12两相共存组织转变为DO22单相组织;受弹性畸变能影响,有序相颗粒沿[100]和[010]方向排列,且时效温度升高,择优取向性愈发显著。平衡时,先析出DO22相的体积分数大于后析出L12相的体积分数。