破碎覆岩回采巷道临界宽度研究

为了有效控制破碎覆岩回采巷道变形,根据其赋存特征采用工字钢架棚支护技术,分析破碎覆岩普氏拱结构的形成原理和研究回采巷道临界宽度。针对破碎覆岩回采巷道具有围岩破碎、强度低和不具有可锚性等特点,采用普氏拱理论,计算回采巷道围岩压力;当棚梁工字钢最大正应力等于工字钢屈服极限时推导出破碎覆岩条件下回采巷道临界宽度计算公式。以106煤矿为工程实例进行分析,结果表明：破碎覆岩回采巷道的合理临界宽度为4.4m;增大支护强度和减小巷道高度可有效提高破碎覆岩回采巷道临界宽度;如果需要更大的巷道宽度,可通过降低棚间距或增大型钢型号方法实现。     

Boundary layer model for char combustion and gasification

A non-steady boundary layer model is developed for numerical simulation of combustion and gasification of a single shrinking char particle. The model considers mass and energy conservation coupled with heterogeneous char reactions producing CO and homogeneous oxidation of CO to CO₂ in the boundary layer surrounding the char particle. Mass conservation includes accumulation, molecular diffusion, Stefan flow and generation by chemical reaction. Energy conservation includes radiation transfer at the particle surface and heat accumulation within the particle. Simulation results predict experimentally measured conversion and temperature profiles of a burning Spherocarb particle in a laminar flow reactor. Effects of bulk oxygen concentration and particle size on the combustion process are addressed. Predicted particle temperature is significantly affected by boundary layer combustion of CO to CO₂. With increasing particle size, char gasification to char combustion ratio increases, resulting in decreasing particle temperature and increasing peak boundary layer temperature.     

Durability of Adhesion Between Metals and Polymers

Adequate adhesion between metals and polymers is primarily the result of chemical bonds in the boundary layer. This region, however, is subject to degradation by moisture. Three modes of deterioration are observed. The first is a largely reversible weakening effect in the polymer layer near the metal oxide surface. The structure of this layer differs from that of the bulk and is influenced by the chemical and physical properties of the surface. The second is a slow transformation of the oxide by hydration and a diffusion of oxide constituents into the polymer. This process is irreversible and is influenced by the state of the surface and chemical properties of the polymer. The third is a fast deterioration of the oxide by primary corrosion usually initiating at an unprotected edge but occasionally arising within the body of a joint.     

柔性无机材料外墙保温隔热涂料的研制

以弹性丙烯酸乳液为成膜物,以玻化微珠、空心玻璃微珠、膨胀蛭石、岩棉纤维为填料,在助剂的配合下,制备柔性保温隔热涂料。以薄涂型施工于建筑外墙作保温层,其涂层具有生态环保、安全稳固、保温隔热、防水防火、柔韧抗裂、施工简便等优点,适用于夏热冬暖、夏热冬冷地区的建筑物外墙作保温施工。     

流程加工CAN测控网络的应用层协议研究

为提高CAN测控网络的适应性和通信效率,以CAN2.0A技术规范为基础,针对流程加工测控网络的特点,设计面向流程加工领域的CAN总线应用层协议ProCAN。在明确流程加工概念及范围的基础上,分析流程加工测控系统结构模型的特征,提出通信报文的类型,定义标准数据帧仲裁域与数据域的编码格式,并讨论ProCAN协议的通信模式、通信状态、通信异常及长报文误帧重传控制。利用OPNET网络仿真软件进行实验,结果表明,ProCAN协议能实现报文通信,并且具有延时短、实时性强、可靠性高的特点,尤其当网络负载较大时,效果更为明显。     

A New Method for Identifying Osmotically Limited and Gel Layer Controlled Pressure Independent Flux in Ultrafiltration

An unequivocal determination of whether pressure independent flux regime is osmotically controlled or gel layer dominated, is still open for discussion in the membrane literature. The present work reports a method that could be used to address this issue. It is shown that analysis of post steady state transient filtration data leads to clear demarcation of osmotically limited and gel layer controlled filtration. The method proposed in this work can also be used to estimate the additional filtration resistance offered by the polarization layer to the permeate flow in macromolecular ultrafiltration and has been verified experimentally. It has also been shown that the polarization layer thickness is not sensitive to the feed pressure but varies as a function of the bulk solute concentration; higher the bulk concentration, thicker is the polarization layer.     

用T621A石墨炭源合成出高强度金刚石

介绍了合成高强度(22．5kg～25．8kg)粗颗粒(40／50～25／30)单晶金刚石所需的炭源材料，触媒合金种类、装填方式、合成参数与合成效果。讨论了原料、合成工艺条件对生长高强度粗颗粒的优质金刚石的影响及合成机理。     

三层PE防腐新技术在埋地管道中的应用

简要介绍先进的埋地管道防腐工艺——管道三层PE防腐,在埋地天然气管道、给排水管道中的应用,三层PE管道防腐工艺逐渐取代传统的管道防腐工艺。     

Photoinduced Polymerization in the Wall of Hollow Capsules

Summary: Novel light‐sensitive hollow capsules were fabricated from the small molecule 3‐sulfopropylacrylate potassium (SPA) and poly(allylamine hydrochloride) (PAH). With UV irradiation, SPA could be photopolymerized in the wall of hollow capsules. After photopolymerization the capsule size and surfaces showed pronounced differences. The capsules became much more rigid as indicated by an increase in the modulus of more than a factor of 5.

CLSM image of SPA/PAH hollow capsule emission at 554 nm, from rhodamine B after photopolymerization.     

K_2O－CaO－Al_2O_3－SiO_2系统自释釉瓷化学组成的研究

本文从酸度系数着手，证实了Ｋ２Ｏ－ＣａＯ－Ａｌ４Ｏ久－ＳｉＯ２系统中存在自释釉组成，限定了其组成范围，０．６７％＜Ｋ２Ｏ＜１．２８％，１０．６４％＜ＣａＯ＜１３．６２％，１１．５３％＜Ａｌ４Ｏ３＜１５．３２％，７２．７３％＜ＳｉＯ２＜７４．０４％，并讨论了自释釉瓷的性能。