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21.
Aimin Xiang Zhongjie Du Qinghua Zeng Chen Zhang Hangquan Li 《Polymer International》2005,54(10):1366-1370
This paper presents recent efforts on the preparation of flexible polyhedral particles via concentrated emulsion templating polymerization in which the hydrophilic monomer (acrylamide) and hydrophobic monomer (butyl acrylate) are polymerized simultaneously in the continuous and dispersed phase, respectively. Such templating polymerization has been enhanced in our systems owing to the introduction of acrylamide monomer and their higher polymerization rate in continuous phase as compared with butyl acrylate in dispersed phase. Diffusion between the different phases was also inhibited. Furthermore, the stability of the concentrated emulsion and the molecular weight of the produced poly(butyl acrylate) were found to be significantly affected by the amount of redox initiator. The morphology of the particles could be controlled by varying the volume fraction of the dispersed phase and the polyhedral particles were achieved at higher volume fraction. Copyright © 2005 Society of Chemical Industry 相似文献
22.
用化学还原法合成了FeBP非晶态合金超细微粒,用电感耦合等离子体光谱(ICP)、X射线粉末衍射(XRD)、透射电子显微镜(TEM)和差热分析(DSC)等手段对其进行了物性表征,并用微型催化反应装置考察了其对PH3分解的催化作用,结果表明,非晶态合金FeBP对PH3的分解具有良好的催化作用,能使PH3的分解温度从800℃以上降到500℃左右。490℃时分解率超过90%,540℃时达100%。 相似文献
23.
Bedich ika Helena Bendov Ivan Macha
《Chemical Engineering and Processing: Process Intensification》2005,44(12):1312-1319
A procedure has been proposed for the estimation of the terminal falling velocity of non-spherical particles moving in a Carreau model fluid in the transition flow region. The procedure is based on a modification of the relationship formerly developed for the fall of spherical particles including the particle dynamic shape factor. The suitability of the proposed procedure has been confirmed by good agreement between experimental and calculated terminal falling velocity data. In the experiments, the terminal falling velocity of short cylinders and rectangular prisms in polymer solutions of different measure of shear thinning and elasticity has been measured. 相似文献
24.
秦家屯油田位于松辽盆地南部东南隆起区十屋断陷东北部,属于非均质断块层状油藏,通过示踪剂监测技术可以了解区块内井间连通情况,判断油井见水、来水方向及油层水驱动用程度,结合油藏静态资料研究,指导油田开发,改善开发效果,达到了稳产的目的。 相似文献
25.
A method to produce monodisperse magnetic composite spheres with diameters from less than 100 nm to more than 1 μm in water solution is reported. The spheres consist of a dielectric silica core and a cobalt/cobalt oxide shell which can be protected from further oxidation with an outer shell of silica or, alternatively, they can be covered with the polymer polyvinylpyrrolidone as a stabilizer. The formation of a uniform magnetic shell proceeds with the adsorption of metallic cobalt seeds, produced by the reduction of cobalt chloride with sodium borohydride, on a self‐assembled layer of polyelectrolytes on the silica core. In the second step, an outer silica shell can be formed by the hydrolysis and condensation of (3‐aminopropyl)trimethoxysilane and tetraethoxysilane. The double‐shell composite spheres show excellent sphericity, monodispersity, and a magnetic hysteresis loop at room temperature. 相似文献
26.
根据胜利油区的地层渗透率、孔隙度,在27个低渗透油田和46个中、高渗透油田的放射性同位素测井中进行了粒径为100~300μm、300~600μm、600~900μm放射性同位素131Ba微球粒径选择实验,确定了放射性同位素131Ba微球的选择原则。当油藏渗透率K<100×10-3μm2、孔隙度<20%时,放射性同位素粒径为100~300μm;当油藏渗透率K>100×10-3μm2、孔隙度>20%时,放射性同位素粒径为300~600μm或600~900μm。在此基础上得到胜利油区选用同位素粒径明细表,对于指导施工,提高放射性测井资料的可靠性具有重要意义。 相似文献
27.
The iterative finite element model, in which an element is used to represent a single particle, is generated to analyze the
global behavior of multiple-material aggregates of materially nonlinear viscoplastic particles. The generalized Maxwell model
is used to define four types of specific nonlinear viscoplastic materials, which are the elasto visco-plastic matter with
linear viscosity, the plasto visco-plastic material with linear viscosity, the elasto visco-plastic media with nonlinear viscosity,
and the plasto visco-plastic media with nonlinear viscosity. The theory and relevant penalty iterative algorithm are developed
to analyze the four representative mixed granular systems consisting of materially nonlinear viscous particles. To verify
precision of stress calculation, solutions of an axis-symmetric radial flow problem are compared with results of the literature
and they are in a great agreement. The results present here provide significant insight into the fundamental behavior of granular
media under compaction conditions, including prediction of the overall aggregates stress-strain response. 相似文献
28.
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30.
稳定同位素井间示踪技术在深层块状稠油油藏水驱特征研究的应用 总被引:4,自引:0,他引:4
经对冷43块深层块状普通稠油水驱注水5个试验井组开展的稳定同位素示踪测试,利用中子活化技术分析样品,采用先进的示踪剂定量分析与流动模拟相互结合的方法,以示踪数值模拟为手段,评价了油井连通、油层平面及纵向上的非均质性、隔层的封隔性等因素对水驱控制程度及动用状况的影响,通过优化注水推进方向及速度,强化动态调整措施,提高了稳产基础。 相似文献