碳对铁及其合金超细微粒氧化特征的影响

采用ＣＯ２激光诱导Ｆｅ（ＣＯ）５－Ｃ２Ｈ４－ＮＨ３的气相分解反应制备了Ｆｅ、Ｆｅ－Ｎ和Ｆｅ－Ｃ－Ｎ超细微粒（微粒直径小于１００ｎｍ）,用透射电子显微镜、Ｘ光衍射、Ｏ／Ｎ和Ｃ／Ｓ测试仪及振动样品磁强计等研究了微粒的结构、表面形态、表面氧的状态及磁性能等;探讨了碳对微粒的氧化特征,特别是对微粒表面氧的形态及其磁性能的影响。结果表明,微粒表面氧的状态可分为吸附态和化合态,并且二者的含量随着微粒的种类不同而变化,碳对微粒表面氧的存在状态、微粒的氧化状况及磁性能具有决定性的影响     

Fe-Ni-Si基奥氏体时效合金的马氏体相变和形状记忆效应

It is well known that the morphologies of the α martensite formed from the γ phase in ferrous alloys are classified into five types of lath, butterfly, (225)A type plate,lenticular and thin-plate. Among those α martensites, onlythe thinplate martensite, which is characterized by containing a high density of transformation twins, has a potential of exhibiting a perfect shape memory (SM) effect.Recently the present authors found in Fe-Ni-Si alloys that the thin-plate martensite is formed by the introduction of fine and coherent γ-(Ni,Fe)3Si particles with a L12 ordered structure in the austenite matrix due to ausaging. In the present study, the SM properties of the ausaged Fe-Ni-Si alloys with the thin-plate martensite are investigated by a conventional bending-test. The effects of the addition of Co to the Fe-Ni-Si alloys on the martensitic transformation and the SM properties are also investigated. It is shown that while the ausaged Fe-Ni-Si ternary alloys exhibit an imperfect SM effect due to reverse transformation from stress-induced thin-plate martensite to austenite, the SM properties are improved by the addition of Co. An almost perfect SM effect is confirmed in the Fe-Ni-Si-Co alloys by heating to 1 100 ℃ after deformation at -196 ℃.     

TiO2／SnO2超微粒及其复合LB膜的紫外—可见光吸收光谱的研究

用胶体化学方法制备ＴｉＯ２／ＳｎＯ２超微粒,ＴｉＯ２／ＳｎＯ２超微粒及其复合ＬＢ膜的紫外－可见光吸收光谱研究表明：ＴｉＯ２／ＳｎＯ２超微粒具有量子尺寸效应使吸收光谱发生“蓝移”;ＴｉＯ２／ＳｎＯ２超微粒／硬脂酸复合ＬＢ膜具有良好的抗紫外性能和光学透过性能。     

P(MMA-AN)/TiO2复合粒子的制备及光催化性能

采用原位乳液聚合方法制备了基于共价键结合的P(MMA-AN)/TiO2复合粒子,红外光谱和热失重分析结果表明P(MMA-AN)在TiO2表面接枝率为15.9%。以甲基橙溶液为目标污染物,研究了P(MMA-AN)/TiO2复合粒子和TiO2对甲基橙的吸附和光催化降解甲基橙溶液的性能,结果表明:两种粒子对甲基橙的吸附都很少;在相同时间内,P(MMA-AN)/TiO2复合粒子对甲基橙溶液的降解性能优于TiO2,紫外光照180 min后,P(MMA-AN)/TiO2复合粒子对甲基橙溶液的降解率达到了88%,而TiO2仅为74%。     

基于Packet Tracer的双核心多出口校园网设计方案

基于目前Packet Tracer网络模拟器的功能及特点,提出一种双核心多出口校园网设计方案。使用Packet Tracer完成整个方案的拓扑及配置,并进行功能的详细测试,最终得出该校园网设计方案的可行性,说明Packet Tracer在计算机网络类课程教学中能发挥重要作用。     

The Use of Distinctive Monoclonal Antibodies in FMD VLP- and P1-Based Blocking ELISA for the Seromonitoring of Vaccinated Swine

The serum neutralization (SN) test has been regarded as the “gold standard” for seroconversion following foot-and-mouth disease virus (FMDV) vaccination, although a high-level biosafety laboratory is necessary. ELISA is one alternative, and its format is constantly being improved. For instance, standard polyclonal antisera have been replaced by monoclonal antibodies (MAbs) for catching and detecting antibodies, and inactive viruses have been replaced by virus-like particles (VLPs). To the best of current knowledge, however, no researchers have evaluated the performances of different MAbs as tracers. In previous studies, we successfully identified site 1 and site 2 MAbs Q10E and P11A. In this study, following the established screening platform, the VLPs of putative escape mutants from sites 1 to 5 were expressed and used to demonstrate that S11B is a site 3 MAb. Additionally, the vulnerability of VLPs prompted us to assess another diagnostic antigen: unprocessed polyprotein P1. Therefore, we established and evaluated the performance of blocking ELISA (bELISA) systems based on VLPs and P1, pairing them with Q10E, P11A, S11B, and the non-neutralizing TSG MAb as tracers. The results indicated that the VLP paired with S11B demonstrated the highest correlation with the SN titers (R² = 0.8071, n = 63). Excluding weakly positive serum samples (SN = 16–32, n = 14), the sensitivity and specificity were 95.65% and 96.15% (kappa = 0.92), respectively. Additionally, the P1 pairing with Q10E also demonstrated a high correlation (R² = 0.768). We also discovered that these four antibodies had steric effects on one another to varying degrees, despite recognizing distinct antigenic sites. This finding indicated that MAbs as tracers could not accurately detect specific antibodies, possibly because MAbs are bulky compared to a protomeric unit. However, our results still provide convincing support for the application of two pairs of bELISA systems: VLP:S11B-HRP and P1:Q10E-HRP.     

硅胶颗粒中杂质在线识别方法与剔除装置的设计及研究

为了实现硅胶颗粒中杂质的自动剔除，提出杂质识别算法，并设计了自动化的杂质剔除装置。首先通过摄像机实时采集硅胶散料图像，利用Visual C++ 结合OpenCV将图像进行预处理、形态学运算、边缘检测等过程，将杂质识别定位。然后基于RS-232通讯协议实现与单片机通讯，传递杂质的位置信息，控制相应的剔除机构动作，最终实现硅胶与杂质的分离。经验证，本系统能够有效地对杂质的进行识别和剔除，其剔除率达到95%，满足设计要求。本装置采用了“分区域剔除算法”结合“高压气体”的方式进行杂质剔除，具有动作响应快、剔除精度高的优点，有效提高生产效率，降低生产成本。     

低功耗常温CO气敏元件

采用超细SnO2粉体为材料基体，MQ-Y1元件生产工艺制成超细CO元件。在考察了工作温度、选择性、灵敏度、稳定性、响应及恢复时间等器件参数后认为，此元件可以在稍高于室温条件（25～30℃）下工作，是一种具有重要开发应用前途的气敏元件。     

含能催化复合纳米材料的制备研究

亚铬酸铜是促进复合固体推进剂中高氯酸铵分解的一种很好的催化剂,但由于以往制备的亚铬酸铜及高氯酸铵超细微粒易发生团聚,不能有效地对高氯酸铵的分解起催化作用。本文使用高能球磨法,使纳米级亚铬酸铜嵌入或粘附于高氯酸铵晶体表面而形成复合粒子,因而大大地提高了对高氯酸铵的催化效果,使高氯酸铵的热分解反应温度区间明显前移,热分解反应的激烈程度大大提高