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91.
棒状液晶分子相变问题的机械旋转模型研究 总被引:2,自引:1,他引:1
综述一种关于棒状液晶材料的分子结构与液晶相的相关关系的研究成果。介绍了有关液晶分子的机械旋转模型。该模型将液晶分子视作一种高速旋转的转子,通过分子参数计算,对液晶材料的相变温度和分子结构之间的关系给出了一种全新的解释。最新研究表明,含氟三苯液晶材料的分子结构中存在slim和fat现象,能够对液晶材料的相变进行合理解释。该模型能够通过简单的模型方法对新型液晶材料的分子设计与合成提供有用的信息。 相似文献
92.
北京燕山石化两巨型塔器在国内首次使用整体液压连续平移技术安装成功。该项技术可缩短工期,降低费用,提高安装的平稳性。 相似文献
93.
RLL码的计算机辅助设计 总被引:1,自引:1,他引:0
本文着重讨论计算机辅助设计RLL码的具体实现问题.该过程首先根据RLL码两个参数d,k确定一个编码率p/q,然后构造出RLL码的高阶状态转换-输出符号矩阵并求相应的近似特征向量.最后通过状态分裂和状态归并过程,即可得到一个满足d,k约束的编码输出表.其中状态转换-输出符号矩阵为实现计算机辅助设计RLL码提供了有效的数据结构,而且要优化RLL码编码器,就必须有选择地进行状态分裂. 相似文献
94.
Poly(L-ornithine)s having various azo-contents in the side chains were synthesized by the water-soluble carbodiimide procedure. The photochemical properties of the polypeptides poly[Nδ-p-(phenylazo)benzoyl-L-ornithine] (PPABLO) containing 3–77 mol% azobenzene were investigated by absorption and circular dichroism spectroscopy in hexafluoro-2-propanol (HFIP) or water, and in HFIP-water or methanol-water solvent mixtures. The photochromism of the dichroic bands of the PPABLOs containing 20–77 mol% azobenzene in the visible and ultraviolet wavelength regions was found to be mostly reversible as a function of irradiation time at different wavelengths due to the photostationary state (above 80% trans-cis photoisomerization) of the azo aromatic moieties. The PPABLO containing 3.2 mol% azobenzene in water exhibited conformational changes from random coil to helix by the addition of methanol or sodium dodecyl sulphate (SDS). The photo-induced conformational change was observed in HFIP-water-SDS solvent mixtures, while no conformational change was seen in water and HFIP-water solvent mixtures. 相似文献
95.
In vertical co-current gas-liquid flow, the transition from annular to intermittent flow occurs when gas core becomes interrupted by liquid bridges due to the instability of the interfacial capillary waves. An analytical model is formulated to explain the liquid bridging in terms of the growth of finite amplitude interfacial capillary waves. Experimental results show that the longest wave length, which is associated with the transition, is about eight times the wave length of waves moving with the velocity of the liquid film. 相似文献
96.
Nd:碲酸盐玻璃的光谱和激光性质 总被引:2,自引:0,他引:2
对比了各种激光玻璃的光谱性质,指出碲酸盐玻璃是一咱理想的激光介质,并资产在室温下实现了钛宝石激光器泵浦了Nd:碲酸盐块体玻璃的激光发射,激光阈值4.20mJ,斜率效率14.7%。 相似文献
97.
98.
The glass‐transition temperature as a function of curing conversion for a modified diallylbisphenol A/diaminodiphenylsulfone/bismaleimide (BMI) resin was investigated at different temperature regimes and modeled using a modified Di Benedetto equation. Although the relationship between the glass‐transition temperature and conversion of the BMI system conforms to the Di Benedetto equation for α < 0.6 and at lower cure temperatures, at higher cure temperatures the results deviated significantly from the equation; thus, it was an inadequate model for the system. Fourier transform IR analysis showed that the major crosslinking reactions did not occur during cure for the modified BMI at and below 150°C. However, as the cure temperature was increased, the crosslinking reactions responsible for 3‐dimensional network structures became more dominant. At 190°C the C? N? Cstretch vibration of the uncured maleimide ring converted into succinimide rings in the curing process. Simultaneously, a decrease was observed for the absorbance bands of ? C? Hbending (maleimide). The higher cure temperatures induced a significantly faster initial crosslinking rate and also resulted in a shorter period of time after which further crosslinking was retarded, because the increase in the crosslinks also physically slowed further crosslinking activity. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 227–235, 2002 相似文献
99.
100.
Learning a sequence of target locations when the sequence is uncorrelated with a sequence of responses and target location is not the response dimension (pure perceptual-based sequence learning) was examined. Using probabilistic sequences of target locations, the author shows that such learning can be implicit, is unaffected by distance between target locations, and is mostly limited to first-order transition probabilities. Moreover, the mechanism underlying learning affords processing of information at anticipated target locations and appears to be attention based. Implications for hypotheses of implicit sequence learning are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献