The adsorption of dyes from aqueous solution using diatomite

Raw diatomite was calcined at 450 °C for dyes removal from aqueous solution. SEM and FTIR analysis show that the raw diatomite contains organic impurities, which are removed after the calcination. The impurities removal decreases the specific surface area and increases the average pore diameter of raw diatomite, while improves its adsorption capability of dyes. The adsorption isotherm and kinetics experiments of methylene blue onto calcined diatomite were then carried out to investigate the adsorption property. It shows that the adsorption capacity of methylene blue is about 50 mg/g. The adsorption isotherm was fitted by the Langmuir, Freundlich and Redlich-Peterson models, which reveals that the Redlich-Peterson isotherm is the best one. Two kinetic models, pseudo-first order and pseudo-second order, were rearranged for expediently investigating the adsortpion mechanisms. Fitting results show that the pseudo-first-order model is better in describing the adsorption process.     

一种用于气液间传质的新型轴流式叶轮

一种用于气液间传质的新型轴流式叶轮黄庆民林齐浩李启恩（华南理工大学化学工程研究所，广州５１０６４１）关键词气液传质轴流式叶轮１前言在液体搅拌器中，轴流式叶轮由于功耗较小且泵吸量较大而被广泛采用。在气液两相搅拌器中，由于轴流式叶轮有气泛问题，一般均采...     

喷动床反应模型的研究进展

喷动床是一种可实现热量重复循环的高效反应器 .介绍了目前喷动床研究中出现的各种反应模型 ,从等温和非等温两个方面讨论了一维轴向、流管、半分割和流动反应耦合等各类模型的基本思想和理论及各自的特点 ,并提出了进一步发展的方向 .     

石蜡沉积对储层渗透率的影响研究

油气开采过程中的蜡质、沥青质等有机固相沉积。严重影响着油田的正常生产。固相沉积物不仅堵塞油井、输油管线,而且也给油藏多孔介质造成一系列的伤害。如堵塞油藏孔隙、降低孔隙度和渗透率,改变油藏岩石的润湿性,从而影响原油采收率的提高。本文采用热力学理论建立了液固两相相平衡方程,模拟计算石蜡沉积量对储层孔隙度和渗透率影响,进而求出对油井产能的影响。     

尿素生产中尿液的不稳定流动对尿素一分塔的影响

介绍了水溶液全循环法尿素生产系统中,一分塔的精馏段由泡罩塔盘改为规整填料后出现的一系列问题,针对尿液的不稳定流动造成一分塔规整填料严重腐蚀的原因,进行分析并提出整改和预防措施。     

视觉特征对比解耦的广义零样本学习

广义零样本学习通常利用在ImageNet上预训练的深度模型来提取相应的视觉特征,然而预训练模型提取到的视觉特征不可避免地包含和语义无关的信息,这将导致语义—视觉对齐的偏差以及对不可见类的负迁移,从而影响分类结果。为解决上述问题,提出了视觉特征对比解耦的广义零样本学习模型(visual feature contrast decoupling for generalized zero-shot learning, VFCD-GZSL),通过解耦出视觉特征中的语义相关表示来降低冗余信息对分类结果的影响。具体来说,首先用条件变分自编码器生成不可见类的视觉特征。然后通过解耦模块将视觉特征解耦语义相关和语义无关的潜层表示,同时添加总相关惩罚和对比损失来鼓励两者间的相互独立,并用语义关系匹配模型衡量其语义一致性,从而指导模型学习语义相关表示。最后使用特征细化模块细化后的特征和语义相关表示联合学习一个广义零样本学习分类器。在四个数据集上的实验均取得较优的结果,证实了所提方法的有效性。     

图表示学习方法研究综述

针对图表示方法的相关解析任务进行了研究,从形式化定义出发,首先以不同核心技术作为分类标准将图表示学习方法划分为五大类,其包括基于降维解析、矩阵分解、随机游走、深度学习和其他表示学习方法。其次通过归纳与对比分析梳理各类技术发展脉络,进而深层次展现各类图表示方法的优劣。随后结合图表示学习的常用数据集、评估方法和应用领域的归纳分析,展开动态性、可扩展性、可解释性和可解析性的四维剖析。最后总结并展望了图表示学习的未来研究趋势与发展方向。     

硬约束限制的情感文本生成方法研究

预训练语言模型在情感文本的生成任务中取得了良好效果,但现有情感文本生成方法多使用软约束的方式控制文本整体的情感属性,缺乏单词和短语级别的硬性控制。为解决以上问题,提出硬约束限制下的情感文本生成方法。首先使用方面情感分析技术提取句子的方面词、情感词并判断情感极性;之后,选择目标情感的方面词和情感词作为预训练语言模型的硬约束输入来重建完整句子,其中,设计了一种新的单词权重计算方法,旨在使模型优先生成重要单词。实验结果表明,该方法生成的句子不仅具有方面级情感,在文本质量和多样性的评价指标上也有显著提高。     

Numerical solution of viscous flow past a solid sphere with the control volume formulation

The control volume formulation with the QUICK finite difference scheme is used to solveincompressible liquid flow past a solid sphere in terms of stream function and vorticity.Several tech-nical points are addressed on improving the accuracy and efficiency of numerical simulation of similarproblems of fluid flow.In particular,the importance of suitable specification of the distortion func-tion to enforcing the far field boundarv conditions is emphasized.     

Presumed joint probability density function model for turbulent combustion

A presumed joint probability density function (pdf) model of turbulent combustion is proposed in this paper. The turbulent fluctuations of reactant concentrations and temperature are described using a presumed joint pdf of three-dimensional Gaussian distribution based on first and second-order moments of reactant concentration and temperature. Mean reaction rates in both premixed and diffusion combustion are obtained by mean of integration under the presumed joint pdf. This model is applied to predict turbulent premixed combustion of sudden-expansion flow and turbulent jet diffusion methane/air flame. For turbulent premixed combustion, the predicted results of temperature distribution and maximum temperature using the proposed model agree better with the experiment than that using the conventional eddy-breakup (EBU)-Arrhenius model. For the turbulent jet diffusion methane/air flame, the predicted results of velocity, temperature and species concentrations using the proposed model, the Arrhenius, EBU-Arrhenius, and laminar flamelet models are compared with experiment data. Results obtained with the presumed pdf model and that obtained by the laminar flamelet model both agree well with experiments, while results using the other models have a significant difference. The presumed joint pdf model is used to predict the NO formation process, which also agrees well with the experiment data. A unified turbulent combustion model, in which both effects of turbulent diffusion and chemical dynamics are considered, is established for both premixed and diffusion combustion, especially for the process of NO formation.