李子溪流域水土流失及泥沙输移规律初步研究

为了探讨长江上游流域水土流失及泥沙输移规律，选取嘉陵江中游的支流李子溪为典型流域进行分析研究，在实地调查，野外测验及应用１９６０年－１９９１年实测降雨、径流、输沙资料的基础上，利用单因子相关分析和多因子回归分析，分别建立了输水利沙量、最大输沙率计算方程。在此基础上，参照径流瞬时单位线原理，以线性时不变系统为基础，建立输沙瞬时单位线模型。通过输沙单位线与时段净侵蚀量的卷积得到流域出口断面的输沙率过程     

Vapor-phase viscosity of phenol

New measurements of the vapor-phase viscosity of phenol were performed from 437 up to 624 K and for densities between 0.006 and 0.023 mol · L^–1 in an all-quartz oscillating-disk viscometer with small gaps. Thus, including our own measurements reported earlier, experimental data are available in the temperature range between 376 and 639 K and in the density range from 0.001 up to 0.023 mol · L^–1. The data were evaluated with a density series for the viscosity in which only a linear density contribution is included. The values of the second viscosity virial coefficient obtained for phenol as well as for benzene, toluene, and p-xylene were compared with results of the Rainwater-Friend theory and of the modified Enskog theory on the basis of the Lennard-Jones 12-6 potential. The agreement is reasonable, when the potential parameter ratios determined by Bich and Vogel are used. The influence of bound dimers seems to be already taken into account in the three-monomer contribution according to Hoffman and Curtiss.Paper dedicated to Professor Joseph Kestin.     

A quantitative analysis of the European Automakers’ voluntary commitment to reduce CO2 emissions from new passenger cars based on independent experimental data

The reduction of CO₂ emissions and fuel consumption from road transportation constitutes an important pillar of the European Union strategy for implementing the Kyoto Protocol. The commitment to reduce passenger car average CO₂ emissions at 140 g/km in 2008 signed by European car manufacturers and the European Commission is up to now the most important initiative towards limiting CO₂ emissions from road transportation and particularly from passenger cars. Until today, annual reports show the manufacturers’ efforts in limiting CO₂ emissions is within the intermediate target set by the commitment and these results are incorporated in emissions estimations and scientific studies. This paper analyses the origin of the progress achieved so far in CO₂ emissions and attempts an assessment of the commitment using independent experimental emission data. Additionally, the applicability of the commitment-monitoring data into policy and decision-making tools is being examined. The results indicate that a significant part of the reductions achieved so far is due to a market shift towards diesel vehicle sales and that no reduction factors should be applied yet in CO₂ emissions estimation models.     

柳海矿运输大巷返修工程深部软岩支护设计研究

通过现场调查、室内试验以及理论分析,柳海矿运输大巷支护现状进行分析研究,总结破坏原因。根据现场工程地质条件、岩石特性和破坏特点,确定软岩变形力学机制为高应力膨胀性软岩,并提出采用预留刚隙柔层支护技术进行支护。     

智能化系统在新火车站的应用——福州火车站智能化系统设计总结

福州火车站智能化系统包括到发通告、旅客引导显示、客运广播、建筑设备自动控制等7个子系统和系统总集成。     

Analysis of trace mercury in water by solid phase extraction using dithizone modified nanometer titanium dioxide and cold vapor atomic absorption spectrometry

A new method for analysis of trace mercury in water samples was developed, based on the combination of preconcentration/separation using dithizone-modified nanometer titanium dioxide (TiO2) as a solid phase extractant and determination by cold vapor atomic adsorption spectrometry (CVAAS). Dithizone was dissolved with alcohol and loaded on the surface of nano-sized TiO2 powders by stirring. The static adsorption behavior of Hg2 on the dithizone-modified nanoparticles was investigated in detail. It was found that excellent adsorption ratio for Hg2 could be obtained in the pH range of 7-8 with an oscillation time of 15 min, and a 5 mL of 3.5 mol·L-1 HCl solution could quantitatively elute Hg2 from nanometer TiO2 powder. Common coexisting ions caused no obvious influence on the determination of mercury. The mechanisms for the adsorption and desorption were discussed. The detection limit (3σ) for Hg2 was calculated to be 5 ng·L-1. The proposed method was applied to the determination of Hg2 in a mineral water sample and a Zhujiang River water sample. By the standard addition method, the average recoveries were found to be 94.4%-108.3% with RSD (n = 5) of 2.9%-3.5%.     

Effect of the degree of crosslinking on penetrant transport in polystyrene

The effect of the degree of crosslinking of glassy polymers on the transport mechanism of penetrants was investigated using a series of divinyl benzene (DVB)-crosslinked polystyrenes of nominal crosslinking ratio X from 0.001 38 to 0.060 mol DVB/mol styrene. The number average molecular weight between crosslinks, $\text{M}\text{?}{}_{\mathrm{<mtext>c</mtext>}}$, was determined from equilibrium swelling experiments in cyclohexane. Dynamic swelling experiments with cyclohexane at 30°C showed that the mechanism of penetrant transport was anomalous. An overshoot in the penetrant uptake was observed, characteristic of macromolecular relaxations and of changing solubility of the cyclohexane in the continuously swelling polystyrene. Photographs of various samples during the swelling process showed that solvent crazing occurred predominantly in loosely crosslinked samples.     

川中丘陵区一种新型小流域径流输沙模型的建立与应用

径流输沙模型对定量评价水沙的输出响应具有重要的意义。本研究在已有研究成果的基础上，通过对四川盐亭县林山西沟小流域的径流、泥沙进行现场观测与分析，提出含沙量单位线的定义及其确定方法，建立了适应该小流域的径流输沙模型。并应用实测资料进行比较，表明模型的模拟结果可靠，模拟过程确定性系数达0．8以上，为川中丘陵区小流域径流输沙过程的预测预报提供了一个新方法。     

Hybrid gas-to-particle conversion and chemical vapor deposition for the production of porous alumina films

Porous alumina films can be found in a wide variety of materials, including filters, thermal insulation components, dielectrics, biomedical and catalyst supports, coatings and adsorbents. Production methods for these films are as equally diverse as their applications. In this work, a hybrid process based upon chemical vapor deposition and gas-to-particle conversion is presented as an alternative technique for producing porous alumina films, with the main advantages of solvent-free, low substrate-temperature operation. In this process, nanoparticles were produced in the vapor phase by reaction of aluminum acetylacetonate in the presence of oxygen. Downstream of this reaction zone, these nanoparticles were collected via thermophoresis onto a cooled substrate, forming a porous film. Some deposited films were subjected to post-processing in the form of annealing in air. Fourier-transform infrared spectra and X-ray energy-dispersive spectroscopy analysis confirmed the production of alumina at processing temperatures above 973 K. X-Ray diffraction revealed that the films were amorphous. Film thickness, ranging from 30 to 250 μm, and the average deposition rate were determined from scanning electron microscopy results. From transmission electron microscopy, the average primary particle size was determined to be approximately 18 nm and the formation of nanoparticle aggregates was evident. Annealing of the films at temperatures ranging from 523 to 1173 K in the presence of air did not have an effect on particle size. The specific surface area of the powder composing the films ranged from 10 to 185 m² g⁻¹, as determined from nitrogen gas adsorption by the Brunauer–Emmett–Teller method.