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71.
单元系T—p相图的数学结构 总被引:1,自引:0,他引:1
作者以化学元素的稳定单质为基准,推演出了任意物质M_i(相态Ω)的热力学生成活度{相态Ω)的函数形式:?D_Ω数值的大小体现着相态Ω的热力学相对稳定性.根据集合论原理沿D(稳定性)座标取极大值的方法把物理性质互不连续的各个异相态连结在一起,建立了单元系在T-p面上的优势分布方程(PSDE):■作者以H_2O为实例,计算了T-p相图,与实验相图基本一致. 相似文献
72.
Huseyin Selcuk Jeosadaque J Sene Marc A Anderson 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(9):979-984
This study addresses the removal of humic acid (HA) dissolved in an aqueous medium by a photoelectrocatalytic process. UV254 removal and the degradation of color (Vis400) followed pseudo‐first order kinetics. Rate constants were 1.1 × 10?1 min?1, 8.3 × 10?2 min?1 and 2.49 × 10?2 min?1 (R2 > 0.97) for UV254 degradation and 1.7 × 10?1 min?1, 6.5 × 10?2 min?1 and 2.0 × 10?2 min?1 for color removal from 5 mg dm?3, 10 mg dm?3 and 25 mg dm?3 HA respectively. Following a 2 h irradiation time, 96% of the color, 98% of the humic acid and 85% of the total organic carbon (TOC) was removed from an initial 25 mg dm?3 HA solution in the photoanode cell. Photocatalytic removal on the same photoanode was also studied in order to compare the two methods of degradation. Results showed that the photoelectrocatalytic method was much more effective than the photocatalytic method especially at high pH values and with respect to UV254 removal. The effect of other important reaction variables, eg pH, external potential and electrolyte concentration, on the photoelectrocatalytic HA degradation was also studied. Copyright © 2003 Society of Chemical Industry 相似文献
73.
本文通过焊接试验对奥氏体不锈钢绕带容器环板与绕带焊接工艺进行了研究分析,并得出了合理的焊接方法和工艺参数。 相似文献
74.
75.
In this study forecast of Turkey's net electricity energy consumption on sectoral basis until 2020 is explored. Artificial neural networks (ANN) is preferred as forecasting tool. The reasons behind choosing ANN are the ability of ANN to forecast future values of more than one variable at the same time and to model the nonlinear relation in the data structure. Founded forecast results by ANN are compared with official forecasts. 相似文献
76.
探讨了影响煤矿矿井水检测质量的主要因素,按照全过程、全要素控制的理念提出了检测前、检测中和检测后的控制措施。 相似文献
77.
Diana Hurdowar-Castro Ioannis Tsanis Ilmar Simanovskis 《Journal of Great Lakes research》2007,33(1):232-252
A 3D transport model is used to perform a comparative analysis of several potential drinking water intakes located along the northwest shore of Lake Ontario between Toronto and Oshawa. The model is specifically used to assess each intake under both long- and short-term transport of a potential pollutant release from the Pickering Nuclear Generating Station and potential and actual pollutant releases from local land sources respectively. A model based on a 500 m grid resolution is calibrated using data collected in the aftermath of the 1992 tritium spill at the Pickering Nuclear Generation Station and subsequently used to simulate long-term transport. A model based on a 100 m grid resolution is verified using drogue studies and used to simulate short-term transport events. Both models are used to assess pollutant levels at each of nine potential intake locations under different wind scenarios and pollutant releases. Field data for the study included water quality and flow measurements from local sewers and rivers, and estimates of pollutant levels from the local waste water treatment plants. This paper describes the model setup for both the long-term and short-term transport models, calibration using field data, long-term transport modeling, short-term transport modeling, and the comprehensive analysis approach used to evaluate the nine potential intake locations proposed. Results indicated that four intakes in particular outperformed other intake locations by maintaining bottom pollutant levels within governmental standards and warning times that exceeded 20 hours. 相似文献
78.
79.
氧浓度对近临界水中纤维素分解的影响 总被引:3,自引:0,他引:3
研究了不同初始氧浓度对纤维素在近临界水中分解的影响,实验结果表明,氧浓度显著地影响产物总碳收支平衡,液相不同组分的收率、气体的产量以及气相产物的组成,微量氧对产物总碳收支平衡影响不大,而对液相不同组分的收率有一定的影响。从实验结果可以看出,离子型反应机理在纤维素水解的第一步中起主导作用。而单糖的进一步分解是一个以自由基反应机理为主的过程。 相似文献
80.
Combined shape and sizing optimization of truss structures 总被引:1,自引:0,他引:1
In this paper, an evolutionary optimization method is presented for weight minimum problem of a 3-dimensional truss structure
in terms of nodal coordinates and element cross-sectional areas. The structure is subject to stress, local buckling and displacement
constraints. Two types of design variables with different natures are optimized separately: (1) a fully stressed design (FSD)
and scaling techniques are applied to sizing variables and (2) the evolutionary node shift method is applied to shape variables.
Alternating procedure is utilized to couple the two types of variables and to combine the results. The optimum solution is
achieved gradually from the initial configuration design. Two typical truss structures are examined to illustrate the validity
of the method.
Received: 22 October 2001 / Accepted: 04 June 2002
This research work is supported by the National Natural Science Foundation of China under the guarantees no. 10072050 and
10172072, respectively. 相似文献