单元系T—p相图的数学结构

作者以化学元素的稳定单质为基准,推演出了任意物质M_i(相态Ω)的热力学生成活度{相态Ω)的函数形式:?D_Ω数值的大小体现着相态Ω的热力学相对稳定性.根据集合论原理沿D(稳定性)座标取极大值的方法把物理性质互不连续的各个异相态连结在一起,建立了单元系在T-p面上的优势分布方程(PSDE):■作者以H_2O为实例,计算了T-p相图,与实验相图基本一致.     

曲率圆弧段代替切线段的数值计算方法

为了确保安全,核工业和其它一些工业要求某些参数的计算值只能取正的相对误差且不大于5×10-3,这是它们对数值计算的基本要求.例如,反应堆带功率运行时,功率增长总是随时间上升,功率曲线是向下凹的.传统的龙格-库塔法计算值总是小于真实值,并且随着时间的增加,计算值越来越小于真实值.按计算值分析,反应堆是安全的,但实际上反应堆是不安全的.这对反应堆的安全极为不利.为此,本文开拓了一个全新的数值计算方法.与龙格-库塔法相比,该方法计算工作量小,与预测一校正法相比,该方法没有启动问题.更值得指出的是计算值高于真实值,这样,反应堆计算结果总是偏于安全的.     

Photoelectrocatalytic humic acid degradation kinetics and effect of pH,applied potential and inorganic ions

This study addresses the removal of humic acid (HA) dissolved in an aqueous medium by a photoelectrocatalytic process. UV₂₅₄ removal and the degradation of color (Vis₄₀₀) followed pseudo‐first order kinetics. Rate constants were 1.1 × 10^?1 min^?1, 8.3 × 10^?2 min^?1 and 2.49 × 10^?2 min^?1 (R² > 0.97) for UV₂₅₄ degradation and 1.7 × 10^?1 min^?1, 6.5 × 10^?2 min^?1 and 2.0 × 10^?2 min^?1 for color removal from 5 mg dm^?3, 10 mg dm^?3 and 25 mg dm^?3 HA respectively. Following a 2 h irradiation time, 96% of the color, 98% of the humic acid and 85% of the total organic carbon (TOC) was removed from an initial 25 mg dm^?3 HA solution in the photoanode cell. Photocatalytic removal on the same photoanode was also studied in order to compare the two methods of degradation. Results showed that the photoelectrocatalytic method was much more effective than the photocatalytic method especially at high pH values and with respect to UV₂₅₄ removal. The effect of other important reaction variables, eg pH, external potential and electrolyte concentration, on the photoelectrocatalytic HA degradation was also studied. Copyright © 2003 Society of Chemical Industry     

煤矿矿井水检测质量控制措施探讨

探讨了影响煤矿矿井水检测质量的主要因素,按照全过程、全要素控制的理念提出了检测前、检测中和检测后的控制措施。     

Application of a Three-dimensional Wind Driven Circulation Model to Assess the Locations of New Drinking Water Intakes in Lake Ontario

A 3D transport model is used to perform a comparative analysis of several potential drinking water intakes located along the northwest shore of Lake Ontario between Toronto and Oshawa. The model is specifically used to assess each intake under both long- and short-term transport of a potential pollutant release from the Pickering Nuclear Generating Station and potential and actual pollutant releases from local land sources respectively. A model based on a 500 m grid resolution is calibrated using data collected in the aftermath of the 1992 tritium spill at the Pickering Nuclear Generation Station and subsequently used to simulate long-term transport. A model based on a 100 m grid resolution is verified using drogue studies and used to simulate short-term transport events. Both models are used to assess pollutant levels at each of nine potential intake locations under different wind scenarios and pollutant releases. Field data for the study included water quality and flow measurements from local sewers and rivers, and estimates of pollutant levels from the local waste water treatment plants. This paper describes the model setup for both the long-term and short-term transport models, calibration using field data, long-term transport modeling, short-term transport modeling, and the comprehensive analysis approach used to evaluate the nine potential intake locations proposed. Results indicated that four intakes in particular outperformed other intake locations by maintaining bottom pollutant levels within governmental standards and warning times that exceeded 20 hours.     

氧浓度对近临界水中纤维素分解的影响

研究了不同初始氧浓度对纤维素在近临界水中分解的影响，实验结果表明，氧浓度显著地影响产物总碳收支平衡，液相不同组分的收率、气体的产量以及气相产物的组成，微量氧对产物总碳收支平衡影响不大，而对液相不同组分的收率有一定的影响。从实验结果可以看出，离子型反应机理在纤维素水解的第一步中起主导作用。而单糖的进一步分解是一个以自由基反应机理为主的过程。     

Progress in multilayer devices as X-ray optical elements

A new kind of mirror based on multilayering techniques gives the possibility of preparing artificial Bragg reflectors over all the X-UV range. The possibility to choose most of the parameters governing the reflectivity opens the possibility to get a very good efficiency, even under normal incidence. Main parameters, evaporating techniques and tests are described. Some example of recent results are compared to the theoretical predictions.     

云南省水环境状况及问题分析

根据2000年云南省主要河流水质监测评价结果，全省评价河段总长9280km中，水质为Ⅰ－Ⅲ类的河长占76．3％，总体上，云南省内各大水系水质良好，但水污染总体上正在加重，从1985－2000年，Ⅰ类河长年均减少2．3％，V类河长年均增长0．6％，废污水直接排入江河是引起污染的重要原因。水环境问题已成为社会经济可持续发展的关键问题，要切实加强水资源的保护，科学地开发利用水土资源，为了有效地改善水环境的质量，污染控制应从源头开始并采取综合治理措施。