活性炭纤维处理油田回注水的可行性

目前我国油田以向油层注水保持油层压力来提高原油采收率为主要采油手段，所注水98％都是经处理达标后的油田采出水。活性炭纤维（ACF）是一种新型高效吸附材料，孔径分布窄，比表面积大，再生条件温和，并可以根据处理吸附物质的大小调整ACF的孔隙大小，使其作为精细过滤材料处理油田回注水具有可行性，可实现吸附和过滤同时进行，提高注水水质。     

基于ZigBee技术的医院供水管网水质监控系统

针对医院供水管网水质问题,设计了基于ZigBee无线传感器网络的水质实时监控系统。监控系统由末端的不同传感器采集水温、pH值、电导率水质参数,通过ZigBee无线网络传送给网关,网关实现ZigBee和TcP/IP协议间的转换后,将数据传送给监控中心进行存储、分析和处理,监控中心可发送命令控制整个网络。该方案不仅可以实现本地和远程水质实时监控,而且很容易应用于其他环境下的水质实时监控。     

磷对饮用水中细菌再生长影响的研究

根据不同成分的水样中细菌再生长情况,研究了水中磷对生物稳定性的限制因子作用。结果显示,在测试水样中添加1 mg/L的NaAc后,细菌总数增加了100%-187%;在水样中添加15μg/L的NaH2PO4后,细菌总数增加了180%-203%。随水样中PO43-P含量的增加,细菌数目也在逐渐增加,但当水中PO43-P的含量大于等于5μg/L时,细菌已无明显增长趋势。试验结果表明磷和碳一样也是水中微生物生长的限制因素之一,并且对于该水样当PO43-P的含量为2μg/L—5μg/L之间的某个值时,磷的限制作用将会表现出来。     

碳黑水分离技术的研究

脱油沥青作为谢尔气化工艺的气化原料生产化肥在国内尚属首次,由于沥青原料中的灰分和重金属比渣油原料大得多,若仍采用石脑油萃取碳黑技术,灰分和重金属随碳黑返回气化装置,将造成设备的堵塞、磨损,无法保证设备安稳长期运行.通过对碳黑水分离技术进行多方面的研究,寻找到适宜的工艺路线与解决方案.     

中央空调制冷机的化学清洗

阐述了中央空调制冷机结垢的类型及其产生的原因和危害,分析了中央空调制冷机的冷媒水系统、冷却水系统的化学清洗技术和操作方法.     

氧化铁覆膜滤沙对陶瓷化工厂废水中铅吸附性能的研究

用合成方法制备氧化铁覆膜滤沙。在动态条件下,研究了氧化铁覆膜滤沙对重金属离子Pb2 的吸附效果及吸附条件。含Pb2 的陶瓷化工厂废水经氧化铁覆膜滤沙吸附后,Pb2 离子含量显著低于国家排放标准。     

Modification of leather properties by grafting. I. Effect of monomer chain on the physico‐mechanical properties of grafted leather

Although leather has a number of desirable properties such as thermal stability and fire retardancey, in addition to high toughness, it has a few drawbacks such as weight, high water absorption, poor soil and rot resistance, and nonuniformity. If these defects are overcome, leather's usefulness would be further enhanced and its competitive position with respect to synthetics would increase. This study reports the physical and mechanical properties of buffalo leather after chemical graft copolymerization with ethyl acrylate, butyl acrylate, and 2‐ethyl hexyl acrylate using benzoyl peroxide as an initiator. The optimum conditions for grafting (e.g., monomer and initiator concentrations, temperature and time of grafting, and solvent leather ratio) were extensively investigated. The study achieved outstanding properties for buffalo leather in reduction of water uptake after grafting, especially on using 2‐ethyl hexyl acrylate and butyl acrylate monomers. FT‐IR and solid ¹³C‐NMR for leather before and after grafting confirmed the grafting process.© 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1478–1483, 2003     

Novel thermosetting resins for SMC applications from linseed oil: Synthesis,characterization, and properties

New thermosetting resins for applications of sheet‐molding compounds (SMCs) were successfully synthesized from linseed oil, which is the most molecularly unsaturated of all plant oils. The carbon–carbon double bonds were opened by epoxidation, followed by acrylation, and then maleinization, which provided more crosslink sites and added acid functionality on the triglyceride molecules to develop thickening. Dynamic mechanical analysis showed that the storage modulus of these new polymers was approximately 2.5 GPa at 30°C, and the glass‐transition temperature was above 100°C. During maturation the resins reached a molding viscosity quickly and stayed stable. Mechanical tests showed a flexural strength of 100 MPa and a flexural modulus of 2.8 GPa. Thermogravimetric analysis showed a single degradation ranging from 300°C–480°C, which was a result of the carbonization of the crosslinked network. These bio‐based resins are promising as replacements of some petroleum‐based resins in the SMC industry. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006     

β-环糊精-氧化石墨烯超分子杂化体的构筑及应用进展

β-环糊精是由7个D-吡喃葡萄糖单元通过α-1,4-糖苷键键连成环的超分子主体分子，“内疏水、外亲水”的独特结构赋予了其优异的分子识别能力；氧化石墨烯类材料凭借其优良特性成为近几年的研究热点。由β-环糊精和氧化石墨烯构筑的超分子杂化体在兼具二者特有性能的基础上又有新功能的引入。本文综述了β-环糊精-氧化石墨烯超分子杂化体的构筑方式，按二者间的连接方式，分别为共价键和非共价键两种连接方式，其中通过共价键连接是目前最主要的构筑方式；此外对β-环糊精-氧化石墨烯超分子杂化体的特征和表征进行了简述。同时对β-环糊精-氧化石墨烯超分子杂化体在水污染处理、电化学检测、药物控释和催化等领域的应用进展进行了综述。最后对该超分子杂化体在构筑和应用上的发展趋势进行了展望。     

氨合成塔触媒升温还原中水汽浓度分析方法改进

采用电石转化氢焰色谱法,用TDX-01固定相为分离柱,分析氨合成塔触媒升温还原中水汽浓度。