全文获取类型
收费全文 | 127260篇 |
免费 | 10512篇 |
国内免费 | 5398篇 |
专业分类
电工技术 | 9788篇 |
技术理论 | 15篇 |
综合类 | 10848篇 |
化学工业 | 18039篇 |
金属工艺 | 2139篇 |
机械仪表 | 3861篇 |
建筑科学 | 19243篇 |
矿业工程 | 7890篇 |
能源动力 | 6795篇 |
轻工业 | 9328篇 |
水利工程 | 20947篇 |
石油天然气 | 9162篇 |
武器工业 | 636篇 |
无线电 | 3828篇 |
一般工业技术 | 7842篇 |
冶金工业 | 4513篇 |
原子能技术 | 2188篇 |
自动化技术 | 6108篇 |
出版年
2024年 | 368篇 |
2023年 | 1411篇 |
2022年 | 2883篇 |
2021年 | 3630篇 |
2020年 | 3978篇 |
2019年 | 3084篇 |
2018年 | 3010篇 |
2017年 | 3673篇 |
2016年 | 4276篇 |
2015年 | 4309篇 |
2014年 | 8643篇 |
2013年 | 8216篇 |
2012年 | 10183篇 |
2011年 | 9768篇 |
2010年 | 7318篇 |
2009年 | 7431篇 |
2008年 | 6705篇 |
2007年 | 8693篇 |
2006年 | 8038篇 |
2005年 | 7049篇 |
2004年 | 5617篇 |
2003年 | 5023篇 |
2002年 | 4169篇 |
2001年 | 3326篇 |
2000年 | 2767篇 |
1999年 | 2070篇 |
1998年 | 1485篇 |
1997年 | 1221篇 |
1996年 | 926篇 |
1995年 | 850篇 |
1994年 | 628篇 |
1993年 | 484篇 |
1992年 | 376篇 |
1991年 | 293篇 |
1990年 | 210篇 |
1989年 | 220篇 |
1988年 | 155篇 |
1987年 | 141篇 |
1986年 | 106篇 |
1985年 | 119篇 |
1984年 | 104篇 |
1983年 | 70篇 |
1982年 | 35篇 |
1981年 | 12篇 |
1980年 | 20篇 |
1979年 | 21篇 |
1977年 | 9篇 |
1976年 | 6篇 |
1959年 | 8篇 |
1951年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
21.
《International Journal of Hydrogen Energy》2022,47(66):28475-28485
Constructing efficient and stable bifunctional electrocatalysts for overall water splitting remains a challenge because of the sluggish reaction kinetics. Herein, the core-shell hybrids composed of Co(PO3)2 nanorod core and NiFe alloy shell in situ grown on nickel foam (NiFe/Co(PO3)2@NF) are synthesized. Owing to the hierarchical palm-leaf-like structures and strong adhesion between NiFe alloys, Co(PO3)2 and substrates, the catalyst provides a large surface area and rapid charge transfer, which facilitates active sites exposure and conductivity enhancement. The interfacial effect in the NiFe/Co(PO3)2 core-shell structure modulates the electronic structure of the active sites around the boundary, thereby boosting the intrinsic activity. Benefiting from the stable structure, the durability of the catalyst is not impaired by the inevitable surface reconfiguration. The NiFe/Co(PO3)2@NF electrode presents a low cell voltage of 1.63 V to achieve 10 mA cm?2 and manifests durability for up to 36 h at different current densities. 相似文献
22.
The slight-alkalization of generator internal cooling water (GICW) is widely used to inhibit the corrosion of hollow copper conductor and thereby ensure the safe operation of the generator. CO2 inleakage is increasingly identified as a potential security risk for GICW system. In this paper, the influence of CO2 inleakage on the slight-alkalization of GICW was theoretically discussed. Based on the equilibriums of the CO2-NaOH-H2O system, CO2 inleakage saturation was derived to quantify the amount of the dissolved CO2 in GICW. This parameter can be directly calculated with the measured conductivity and the [Na+] of GICW. The influence of CO2 inleakage on the slight-alkalization conditioning of GICW and the measurement of its water quality parameters were then analyzed. The more severe the inleakage, the narrower the water quality operation ranges of GICW, resulting in the more difficult the slight-alkalization conditioning of GICW. The temperature calibrations of the conductivity and the pH value of GICW show non-linear correlations with the amount of CO2 inleakage and the NaOH dosage. This study provides insights into the influence of CO2 inleakage on the slight-alkalization of GICW, which can serve as the theoretical basis for the actual slight-alkalization when CO2 inleakage occurs. 相似文献
23.
《International Journal of Hydrogen Energy》2022,47(49):21033-21043
Magnetron sputtered low-loading iridium-ruthenium thin films are investigated as catalysts for the Oxygen Evolution Reaction at the anode of the Proton Exchange Membrane Water Electrolyzer. Electrochemical performance of 50 nm thin catalysts (Ir pure, Ir–Ru 1:1, Ir–Ru 1:3, Ru pure) is tested in a Rotating Disk Electrode. Corresponding Tafel slopes are measured before and after the CV-based procedure to compare the activity and stability of prepared compounds. Calculated activities prior to the procedure confirm higher activity of ruthenium-containing catalysts (Ru pure > Ir–Ru 1:3 > Ir–Ru 1:1 > Ir pure). However, after the procedure a higher activity and less degradation of Ir–Ru 1:3 is observed, compared to Ir–Ru 1:1, i.e. the sample with a higher amount of unstable ruthenium performs better. This contradicts the expected behavior of the catalyst. The comprehensive chemical and structural analysis unravels that the stability of Ir–Ru 1:3 sample is connected to RuO2 chemical state and hcp structure. Obtained results are confirmed by measuring current densities in a single cell. 相似文献
24.
The proliferating need for sustainability intervention in food grain transportation planning is anchoring the attention of researchers in the interests of stakeholders and environment at large. Uncertainty associated with food grain supply further intensifies the problem steering the need for designing robust, cost-efficient and sustainable models. In line with this, this paper aims to develop a robust and sustainable intermodal transportation model to facilitate single type of food grain commodity shipments while considering procurement uncertainty, greenhouse gas emissions, and intentional hub disruption. The problem is designed as a mixed integer non-linear robust optimisation model on a hub and spoke network for evaluating near optimal shipment quantity, route selection and hub location decisions. The robust optimisation approach considers minimisation of total relative regret associated with total cost subject to several real-time constraints. A version of Particle Swarm Optimisation with Differential Evolution is proposed to tackle the resulting NP-hard problem. The model is tested with two other state-of the art meta-heuristics for small, medium, and large datasets subject to different procurement scenarios inspired from real time food grain operations in Indian context. Finally, the solution is evaluated with respect to total cost, model and solution robustness for all instances. 相似文献
25.
Gerd J. Hahn 《国际生产研究杂志》2020,58(5):1425-1441
The Fourth Industrial Revolution – also known as Industry 4.0 (i4.0) – comprises the digitalisation of the industrial sector. This paper uses the theoretical lens of supply chain innovation (SCI) to investigate the implications of i4.0 on supply chain management. For these purposes, the method of structured content analysis is applied to more than 200 use cases of i4.0-enabled SCI introduced by both established and startup companies. i4.0-enabled SCI manifests along three dimensions: process, technology, and business architecture. The key findings of this study can be summarised as follows: first, i4.0-enabled SCI extends the initial focus on productivity improvements in SC processes towards scalability and flexibility. Second, extant i4.0 solutions rely mostly on analytics and smart things while omitting smart people technology and the human-centric approach associated with the i4.0 paradigm. Third, established companies adopt i4.0 merely to sustain their existing business architectures while startup companies radically change their operating models, relying heavily on data analytics and the platform economy. Consequently, established companies pursue a problem-driven, engineering-based approach to SCI while startup companies follow an ‘asset-light’, business-driven approach. Lastly, there are two distinct approaches to digitalising operational SC processes: platform-based crowdsourcing of standard processes and on-demand provision of customised services. 相似文献
26.
27.
SPEEK/cSMM membrane for simultaneous electricity generation and wastewater treatment in microbial fuel cell
下载免费PDF全文
![点击此处可从《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
28.
A strategic planning optimization model is proposed for a network of natural gas to liquids (GTL) systems, and it is solved using a rolling horizon strategy. The model formulation determines the strategic and tactical decisions of the GTL supply chain over a long time horizon. The decisions to build new GTL refineries may be made over the span of 30 years and their operations cover the span of 60 years. Multiple capacities of GTL refineries (i.e., 1, 5, 10, 50, and 200 thousand barrels per day) that produce gasoline, diesel, and kerosene commensurate to the United States demand ratio may exist in the network. The parameter inputs include the locations, availabilities, and prices of natural gas in the United States discretized by county, the delivery locations of fuel products, and the transportation costs of every input and output of the refinery, defined for each time period. Formulated as a large-scale mixed-integer linear optimization (MILP) model, the problem is solved using a rolling horizon strategy for tractability. Case studies on the state of Pennsylvania are presented for different planning schemes and their impact on the economic performance of the GTL network is discussed. 相似文献
29.
Qingna Gong Songtao Cao Yu Zhou Ruixin Wang Weizhou Jiao 《International Journal of Hydrogen Energy》2021,46(41):21442-21453
Ni2P nanoparticles and CdS nanorods were grew together on a mesoporous g-C3N4 through a facile in-situ solvothermal approach. Under visible light (λ > 400 nm), the as-prepared ternary PCN–CdS-5% Ni2P composite displays a high H2 evolution rate with 2905.86 μmol g?1 h?1, which is about 14, 18 and 279 times that of PCN–CdS, PCN–Ni2P and PCN, respectively. The enhanced photocatalytic activity is mainly attributed to the improved separation efficiency of the photocarriers by the type II PCN–CdS heterojunction and the effective extraction of photogenerated electrons by Ni2P. Meanwhile, Ni2P acts as co-catalyst to provide the photocatalytic active site for hydrogen reduction. In addition, PCN–CdS-5% Ni2P composite exerts good stability in 12-h cycles. 相似文献
30.
With the emergence of distributed ledger technology (DLT), numerous practitioners and researchers have proclaimed its beneficial impact on supply chain transactions in the future. However, the vast majority of DLT initiatives are discontinued after a short period. With the full potential of DLT laying far down the road, especially managers in supply chain management (SCM) seek for short-term cost-saving effects of DLT in order to achieve long-term benefits of DLT in the future. However, the extant research has bypassed grounding long-term as well as short-term effects of DLT on supply chain transaction with empirical data. We address this shortcoming, following an abductive research approach and combining empirical data from a multiple case study design with the corresponding literature. Our study reveals that the effects of DLT on supply chain transactions are two-sided. We found six effects of DLT solutions that have a cost-reducing or cost avoidance impact on supply chain transactions. In addition, we found two effects that change the power distribution between buyers and suppliers in transactions and a single effect that reduces the dependency of supply chain transactions on third parties. While cost-reducing and avoidance as well as dependency-reducing effects are positive effects, the change in power distribution might come with disadvantages. With these findings, the paper provides the first empirical evidence of the impact of DLT on supply chain transactions, which will enable managers to improve their assessment of DLT usage in supply chains. 相似文献