Characterization and wear behavior of WC-0.8Co coating on cast steel rolls by electro-spark deposition

To prepare high wear resistance and high hardness coatings, electro-spark deposition was adopted for depositing an elec trode of a mixture of 92wt%WC+8wt%Co on a cast steel roll substrate. The coating was characterized by classical X-ray diffracto meter (XRD) and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX). The results indicate that the coating shows nanosized particulate structure and dendritic structure including columnar structure and equiaxed structure. The pri mary phases of the coating contain Fe_3W_3C, Co_3W_3C, Fe_2C and Si_2W. The coating has a low friction coefficient of 0.13, its average wear-resistance is 3.3 times that of the cast steel roll substrate and the main mechanism is abrasive wear. The maximum microhard ness value of the coating is about 1573.9 Hv_(0.3) The study reveals that the electro-spark deposition process has the characteristic of better coating quality and the coating has higher wear resistance and hardness.     

Processing and properties of 2D SiC/SiC composites by precursor infiltration and pyrolysis

Two-dimensional plain-weave silicon carbide fiber fabric reinforced silicon carbide (2D-SiC/SiC) composites were molded by stacking method and densified through precursor infiltration and pyrolysis (PIP) process. SiC coating was deposited as the fiber/matrix interphase layer by chemical vapor deposition (CVD) technique. Fiber/matrix debonding and relatively long fiber pullouts were observed on the fracture surfaces. Additionally, the flexural strength and elastic modulus of the composites with and without fiber/matrix interphase layer were investigated using three-point bending test and single-edge notched beam test. The results show that the fiber fraction and the porosity of 2D-SiC/SiC composites with and without coating are 27.2% (volume fraction) and 11.1%, and 40.7% (volume fraction) and 7.5%, respectively. And the flexural strength and elastic modulus of 2D-SiC/SiC composites with and without coating are 363.3 MPa and 127.8 GPa, and 180.2 MPa and 97.2 GPa, respectively. With a proper thickness, the coating can effectively adjust the fiber/matrix interface, thus causing a dramatic increase in the mechanical properties of the composites. Foundation item: Project(NCET-07-0228) support by the New Century Excellent Talents in University     

复合掺杂Nd（III）和Zn（II）非晶态Ni（OH）2电极活性材料的制备及其表征

以NiSO4、ZnSO4和Nd（NO3）3为原料,采用共沉淀快速冷冻法制备出了复合掺杂稀土Nd（III）和Zn（II）的非晶态氢氧化镍粉体材料。测试发现：样品材料微结构无序性强,结晶水含量较高。将样品材料制备成镍电极并组装成MH—Ni电池,在80mA／g恒电流充电5．5h、40mA／g恒电流放电、终止电压为1．0V的充放电制度下,复合掺杂6％Nd（III）和6％Zn（II）样品材料电池的放电平台为1．2624V,放电比容量为343．12mAh／g,远高于目前应用的B-Ni（OH）2电极活性材料的放电比容量。     

高含硫气藏中元素硫沉积形态和微观分布研究

元素硫沉积是高含硫气藏开采过程中存在而又必须解决的难题之一.随着高含硫气藏储层压力不断下降,元素硫溶解度也不断下降,一旦元素硫溶解度低于元素硫含量,元素硫就会从地层中沉积下来.沉积的元素硫会堵塞地层孔隙,降低渗透率,严重影响气井产能.为了研究元素硫在地层中的沉积形态和沉积特征,利用自主设计的实验流程和实验方法,使TD5-1井高含硫气体通过岩芯,并降低压力让元素硫在岩芯中沉积下来,然后对沉积了元素硫的岩芯进行电镜扫描和能谱分析,首次得到了元素硫在岩芯中的沉积形态,即元素硫主要以膜状形式分布在岩芯孔隙壁面上.该研究结果为深入认识、掌握元素硫沉积规律以及指导高含硫气藏合理开发奠定了基础.     

电泳-电沉积法制备Ni-Fe2O3复合镀层 及其氧化性能研究

先采用电泳沉积工艺在Ni基体上均匀沉积Fe2O3膜,然后采用电镀技术在Fe2O3膜中沉积金属Ni,得到含Fe2O3质量分数较高的Ni-Fe2O3复合镀层。分析了沉积电压对电泳沉积Fe2O3膜厚度的影响,研究了镀层的高温氧化性能,并对其氧化机理进行了探讨。使用傅里叶红外光谱、扫描电镜、能谱仪、X射线衍射仪对镀层的截面形貌、成分等进行了研究。结果表明:通过改变阴阳两极之间的电场强度或调整两极之间的距离,电泳沉积Fe2O3的厚度会发生很大的变化;经过一定温度热处理后,电泳沉积层中的有机物去除干净;使用电泳-电沉积法制备的Ni-Fe2O3镀层与基体之间的结合界面紧密、完整;复合沉积层在1 000℃高温条件下氧化后可以得到镍铁尖晶石结构的物质。     

水热温度对玻璃纤维增强HAp-CS涂层的影响

为了制备出结合强度较好的生物涂层,采用水热电泳法在碳/碳复合材料表面成功制备了玻璃微纤维增强的羟基磷灰石——壳聚糖(g(f)/HAp-CS)复合涂层,用x-射线衍射仪、透射电子显微镜、扫描电子显微镜、能谱分析仪、红外傅里叶变换分析仪等测试手段对涂层进行了测试和表征,主要研究了水热沉积温度对复合涂层中HAp晶相和涂层显微结构的影响以及HAp涂层的沉积动力学.结果表明:采用玻璃微纤维增强的HAp-CS涂层,致密性和均匀性有了很大提高,显著减少了复合涂层表面的裂纹;随着水热温度的升高,涂层中HAp的衍射峰逐渐增强,表面形貌得到了有效改善,涂层的致密性和均匀性显著提高;涂层的沉积速率随水热温度的升高而加快,其沉积活化能为14.63kJ/mol.     

氮化铝体单晶生长技术研究进展(英文)

评述氮化铝体单晶生长技术中常用的金属铝直接氮化法、溶解生长法、氢化物气相外延法和物理气相传输法.指出氢化物气相外延法和物理气相传输法是前景看好的生长氮化铝体单晶方法.介绍本课题组对物理气相传输法的一些改进.认为生长大尺寸氮化铝单晶体的研究将集中在精确控制生长条件、选择合适的坩埚材料、优化制备工艺和制备优质氮化铝籽晶等方面.     

Investigations of ZnO thin films deposited by a reactive pulsed laser ablation

Highly transparent ZnO thin films were deposited at different substrate temperatures by pulsed laser deposition in an oxygen atmosphere. The thin films were characterized by various techniques including X-ray diffraction, scanning electron microscopy, optical absorption, and photoluminescence. We demonstrated that oriented wurtzite ZnO thin films could be deposited at room temperature using a high purity zinc target. Variable temperature photoluminescence revealed new characteristics in the band edge emission. The underlying mechanism for the observed phenomena was also discussed.     

Effect of acetic acid on electrochemical deposition of carbon-nitride thin film

Electrochemical deposition method was employed to prepare CNx thin film from methanol-urea solution,and it was shown that adding a little acetic acid in the solution significantly affected the deposition process.After optimizing the experiment conditions,we obtained polycrystalline grains with sizes of about 3―7μm on the faces of single crystal silicon.X-ray diffraction spectrua indicate that the grains are mainly composed of cubic phase mixed with a small amount of β and α phases.     

Electrophoretic deposition of ZnCo2O4 spinel and its electrocatalytic properties for oxygen evolution reaction

In this paper, ZnCo₂O₄ was deposited on nickel substrate by electrophoretic deposition (EPD) method as electrocatalyst for the oxygen evolution reaction. The effect of electrophoresis variables including the deposition time, the applied voltages was discussed. XRD, SEM, and electrochemical measurement techniques were used to characterize the deposit and ZnCo₂O₄/Ni electrode. Compared with the ZnCo₂O₄ electrode prepared by nitrate decomposition method, the electrophoretic ZnCo₂O₄ electrodes exhibit better electrocatalytic properties and higher mechanical stability. And the electrode prepared at 10 V for 5 min has the best electrocatalytic properties with the overpotential of only 0.203 V at current density of 100 mA cm⁻².