Preparation of micro-arc oxidation coatings on magnesium alloy and its thermal shock resistance property

1. Introduction Due to their high specific strength, good electro-magnetic shielding characteristics, high damping characteristics, good cast ability, and excellent pol-ishing capability, magnesium alloys are extensively used in aeronautical, automobile, and electro- communication industries [1-3]. But magnesium has some disadvantages, such as low chemical stability, high negative electric potential, and low hardness, so it is necessary to use surface disposal to accommo-date the demand for re…     

Electrochemical investigation of the iron-containing and no iron-containing AB5-type negative electrodes

The electrochemical behaviour of LaNi_3.55Mn_0.4Al_0.3Co_0.75−xFe_x (x = 0, 0.15, 0.55, 0.75) intermetallic compounds has been studied and presented [C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, Int. J. Hydrogen Energy 29 (2004) 307–311; C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, J. Alloys Compd. 360 (2003) 266–271; C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, J. Alloys Compd. 384 (2004) 249–253]. It has been deduced that the LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compound has interesting electrochemical properties. In this paper we present the electrochemical study of LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compound properties compared with the parent LaNi_3.55Mn_0.4Al_0.3Co_0.75 compound. Several techniques, such as, the chronopotentiometry, the constant potential discharge (CPD), the cyclic voltammetry (CV) and the linear polarization (LP) were applied to characterize these electrochemical properties. The electrochemical discharge capacity of the LaNi_3.55Mn_0.4Al_0.3Co_0.75 alloy increases to reach 294 mAh g⁻¹ after few cycles only (five cycles). However, the activation of the LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 alloy takes more than 20 cycles to be achieved and the obtained maximum discharge capacity is 194 mAh g⁻¹. The hydrogen diffusion coefficient D_H was determined by constant potential discharge and cyclic voltammetry techniques. The obtained values of the LaNi_3.55Mn_0.4Al_0.3Co_0.75 and LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compounds are 6.29 × 10⁻¹¹ and 7.62 × 10⁻¹¹, and 2 × 10⁻⁸ and 7.5 × 10⁻⁸ cm² s⁻¹ by CPD and CV techniques, respectively. The exchange current density values, determined by a linear polarization technique, are 44 and 27 mA g⁻¹, respectively, for LaNi_3.55Mn_0.4Al_0.3Co_0.75 and LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 alloys.     

超声波检测混凝土结构抗冻性的方法研究

依据固体结构动弹模与表面波速度的关系，采用超声波检测混凝土冻融试件的动弹模，并与共振法测出的动弹模进行对比，总结出其内在相关规律，建立起预报混凝土动弹模的回归主程，由测得的波速计算出相应的动弹模，再利用动弹模之比评估出混凝土结构的抗冻性。初步试验和研究表明，此方法研究思路切实可行，符合混凝土冻融特性的基本变化规律，能够实现从度件测试向结构检测的发展，可供混凝土耐久性检测工程参考。     

Stannate and permanganate conversion coatings on AZ31 magnesium alloy

The formation of stannate and permanganate–phosphate conversion coatings on AZ31 magnesium alloy was investigated in situ by EIS measurements and their protective performances were studied by different electrochemical techniques in diluted (0.05 M) sodium sulphate solution.The influence that short or long treatment times exert on the performances of such conversion coatings is discussed. While permanganate–phosphate baths always built layers characterized by penetrating cracks, long stannate baths produced layers without interconnected porosity, but were defective. This accounted for the initial greater protectiveness achieved with the stannate treatment; nevertheless, the easy penetration of the electrolytic solution through such a layer quickly decreased its corrosion resistance.     

混凝土抗硫酸盐侵蚀试验的一种新方法

提出了一个测定混凝土抗硫酸盐侵蚀能力的新方法。采用这种方法对超高强混凝土的抗化学腐蚀性能进行了试验，并和普通混凝土进行了对比。发现用一般硅酸盐水泥配制的超高强混凝土虽然在抵抗化学侵蚀能力方面比普通混凝土有所提高，但由于化学组成上的原因，它对高浓度的(NH4)2SO4等化学介质也难以抵抗。     

钼变形抗力的研究

在Gleeble-1500热模拟试验机上，分析钼的高温变形特征，其变形温度为1100～1400℃，变形速率为1-50s^-1，变形程度为0-0．6，并对钼板进行塑性变形抗力的研究，采用非线性回归方法建立钼板的变形抗力模型。获得了钼板的变形抗力曲线图，对不同的数学模型结构进行回归比较，提出拟合精度高的变形抗力的数学模型，该模型具有较高的精度及良好的数值稳定性。     

离子氮化对镀铬层组织与性能的影响

研究了镀铬层经离子氮化后的组织和性能。分别用SEM、电子探针和X光衍射仪观察和分析了复合处理层剖面的组织、结构和成分,试验结果表明:离子氮化能使镀铬层的网状裂纹弥合,可明显提高了镀层表面硬度、结合力和耐蚀性。     

环境温度对风压传感器精确度的影响探讨

对风压传感器的硅橡胶膜片弹性形变进行了理论分析,推测风压传感器的精确度可能受到温度的影响。通过工业压力校准器对传感器进行了压力校验。结果表明,风压传感器的精确度受温度与气压差的影响。该研究结果可用于指导风压传感器进行温度与气压差补偿设计。     

基于CVaR的风电机组日前申报出力优化模型研究

在我国,风电机组需提前一天提交次日24小时的申报出力信息,由于来风具有明显的不确定性和随机性特征,风电机组次日实际出力与日前申报出力会存在一定的偏差。为解决以上问题,首先采用K-means聚类法对风电机组实际出力数据进行聚类,并生成样本集;其次,基于风电不确定性样本集构建风险中性风电机组日前申报出力决策优化模型;再次,构建基于条件风险值（CVaR）的日前申报出力优化模型;最后,基于实际数据进行了算例分析。算例分析结果表明,基于CVaR的日前申报出力决策优化模型能有效减少风电机组日前申报出力与次日实际出力的偏差,且使风电机组获得风险价值更好的申报出力,从而实现申报利润的风险可控性。     

基于CPSO-BP神经网络的风电并网暂态电压稳定评估

针对目前传统方法难以快速、准确判断风电并网后系统暂态电压稳定性的问题,提出了一种基于CPSO-BP组合的风电并网暂态电压稳定评估方法。首先采用混沌理论对粒子群算法的不足进行改善,应用改进后的算法对神经网络的初始权值和阈值进行优化,然后利用系统故障前后采集的传统物理量和风电场相关的物理量作为BP神经网络输入特征量进行监督学习,最后将训练得到的模型应用于风电并网系统的暂态电压稳定评估中。利用英格兰10机39节点系统标准算例进行风电并网仿真分析,结果证明了所提方法的有效性。