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101.
102.
A statistical study of the particle shape and size of pure V2O5 and TiO2, and samples of coprecipitated V2O5---TiO2 catalysts with different V/Ti ratios, has been performed. They were also characterized by XRD, EDAX, SEM and XPS. The results showed that pure vanadium pentoxide is compose by large square or needle-shaped particles, while pure titanium dioxide has small and rounded ones. VTiO samples presented an area and shape, depending on the V/Ti ratio.
These results and the spectroscopical characterization conducted to a particle model of the catalysts. Those VOTi samples with high V/Ti ratio would have large V2O5 crystals acting as support of a V/TiO2 solid solution. In contrast, those samples with a low V/Ti ratio, would have the solid solution supporting vanadium pentoxide crystals. 相似文献
103.
ZSM-5型沸石催化剂的结焦与失活 总被引:14,自引:0,他引:14
本文对ZSM-5型沸石催化剂结焦与失活的关系进行了系统的评述.探讨了ZSM-5沸石的酸度和微孔结构对结焦过程的影响. 相似文献
104.
A new synthesis procedure for titanium-containing aluminosilicate zeolites has been obtained using a clear colloidal dispersion (sol) which was prepared with titanium isopropoxide, water, hydrochloric acid and colloidal silica, Ludox. When NaY, KL, offretite, mordenite and ZSM-5 zeolites were crystallized from the sol following conventional hydrothermal crystallization procedures, all the aluminosilicate zeolites showed the same X-ray absorption fine structure at the Ti K edge indicating framework Ti. The zeolites showed remarkable catalytic activity for the partial oxidation of cyclohexene using H2O2 as an oxidant and the photocatalytic decomposition of trichloroethene using water. 相似文献
105.
106.
Zakaria Chajar Michel Primet Hélène Praliaud Michèle Chevrier Catherine Gauthier Frédéric Mathis 《Catalysis Letters》1994,28(1):33-40
The role of nitrogen dioxide in the selective reduction of NO by propane over a Cu-MFI zeolite is investigated. NO2 and NO reductions were carried out under similar conditions of reaction. In the presence of oxygen, the reduction of NO by C3H8 does not differ significantly from that of NO2. In the absence of oxygen, the reduction of NO2 by propane occurs with a partial decomposition of the nitric dioxide molecule. Such a decomposition leads to the formation of oxygen, which is responsible for the increase in catalytic activity by comparison with the same reaction performed with NO. NO2 formed and released in the gas phase during the reduction of NO by propane in the presence of oxygen does not play a predominant role in the catalytic process. 相似文献
107.
探讨了裂解C_5馏分就近集中分离综合利用和分散直接利用,以及建设单独分离双环戊二烯装置发展下游精细化工产品的综合利用策略。 相似文献
108.
Heat-shock induction of heat-shock protein genes is due to a specific promoter element (the heat-shock element, HSE). This study used lacZ under HSE control (HSE-lacZ) to characterize HSE activity in Saccharomyces cerevisiae cells of different physiological states and differing genetic backgrounds. In batch fermentations HSE-lacZ induction by heat shock was maximal in exponential growth, and showed marked decline with the approach to stationary phase. Expression in the absence of heat shock was unaffected by growth phase, indicating that the growth-dependent expression of many yeast heat-shock genes uses promoter elements in addition to the HSE. Heat-induced expression was strongly influenced by the temperature at which cultures were grown. While basal, uninduced expression was constant during growth at different temperatures to 30 degrees C, induction by transfer to 39 degrees C was reduced by increases in growth temperature as low as 18-24 degrees C. Maximal HSE-lacZ induction (30- to 50-fold) was in cultures grown at low temperatures (18-24 degrees C), then heat shocked at 39 degrees C. Ethanol was a poor inducer. Mutations having little effect on HSE-lacZ expression included a respiratory petite; ubi4 (which inactivates the poly-ubiquitin gene); also ubc4 and ubc5 (which each inactivate one of the ubiquitin ligases involved in degradation of aberrant protein). pep4-3 increased both basal and induced beta-galactosidase about two-fold, probably because of slower turnover of this enzyme in pep4-3 strains. 相似文献
109.
110.
离子液体催化C_5馏分中二烯烃的聚合反应 总被引:1,自引:0,他引:1
合成了多种基于1-丁基-3-甲基咪唑阳离子的离子液体,并作为裂解C5馏分中混合二烯烃聚合反应的介质。考察了离子液体种类、反应温度、反应时间和添加Lew is酸对混合二烯烃聚合反应的影响。实验结果表明,以硝酸根为阴离子的离子液体对混合二烯烃的聚合反应具有一定的阻聚作用;以六氟磷酸根为阴离子的离子液体能明显促进混合二烯烃的聚合反应,提高二聚物的含量;添加Lew is酸(质量分数为1%的ZnCl2)的离子液体对混合二烯烃的聚合反应具有更明显的促进作用,其效果仅次于酸性氯铝酸类离子液体,反应温度以30℃以下为宜,温度过高将促使二聚物进一步聚合,形成三聚物乃至多聚物,降低二聚物的含量。 相似文献