NO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> emission from incineration of organic liquid waste in a circulating fluidized bed

An incineration test of a toxic chemical organic waste liquid was conducted on a circulating fluidized bed (CFB) incinerator. The flue gas was measured online with the advanced SAE-19 flue gas analyzer. The effects of several factors, in terms of flow rate of waste liquid, ratio of waste liquid injected into dense bed of the CFB, excess air coefficient, the secondary air fraction and bed temperature on NO _x emissions, were verified. The experimental results show that NO emissions in flue gas increase with increase in the flow rate of the waste liquid injected into the bed or the excess air coefficient or the bed temperature and those decrease with increase in the ratio of waste liquid injected into the dense bed of the CFB or the secondary air fraction. During the test runs, NO _x concentration in flue gas met the national regulation on NO _x emissions due to suppressive effect of low temperature and staged combustion in CFB on NO _x formation. This paper was presented at the 6 ^th Korea-China Workshop on Clean Energy Technology held at Busan, Korea, July 4–7, 2006.     

STRUCTURE OPTIMIZATION OF A CIRCULATING MOVING BED REACTOR

A stress distribution model for a liquid-solid circulating moving bed reactor that consists of a bottom reaction chamber, a top regeneration chamber, a coupling standpipe, a particle transportation system, and a bottom standpipe is established based on the equations of continuity and momentum balance. Simulations show that the stress concentration regions are at the bottom of the regeneration chamber and the coupling standpipe. To reduce the maximal stress and increase the operation flexibility in a reactor for the 2000-ton-per-year production of linear alkylbenzene, the regeneration chamber should have a low height-to-radius ratio (about 9), a suitable half-conical angle between 28° and 35°, and standpipe radius of about 0.05 m.     

A transient method for characterizing flow regimes in a circulating fluid bed

In recent years, although an increasing number of literature have been devoted to circulating fluidized bed (CFB), the prediction of velocities over which different fluidization regimes exist is still difficult. In this study, a transient method was applied which readily allows one to identify operational features and critical transitions. The method is based on stopping the solids flow rate into the riser when riser is operating in fully dense transport regime. The analysis of transient pressure drop data across the riser during a solids flow cut-off experiment against its time derivative demonstrate the three distinct operating regimes that exist as the gas deplete the solid out of the riser. The transient was compared to data taken under steady state operations using statistically designed experiments. Results indicated that although there were significant differences when comparing operations in dilute conditions, there were no significant differences between the two methods in the fast fluidized and dense transport regimes. The transient method was capable of reproducing the solids circulation dependence on riser solids holdup and on the axial pressure profile. This transient method offers an accurate, easy, rapid, and reproducible means of characterizing CFB operations over a wide range of flow conditions. The lack of accuracy in the dilute regime is conjectured to be due to the wide particle size distribution that resulted in segregation during the transient testing.     

7.63m焦炉循环氨水系统运行特点及检修技术

介绍了7.63m焦炉循环氨水系统的设计参数、应急系统设计、氨水工艺流程、主要设备和生产运行中出现的问题,论述了循环氨水系统检修方案的制定实施、焦炉生产作业调整、冷却水量平衡保供及生产、环保风险的防控等实践活动。     

YL-1OO型自动加药装置在乙烯循环水场的应用

介绍了国产YL-100型自动加药装置功能及其在中国石化茂名石化乙烯工业公司乙烯循环水场的应用情况,结果表明其运行平稳,总磷测试数据可靠,可达到循环水自动加药控制的目的。     

Particle residence time distributions in circulating fluidised beds

This paper gives experimental measurements of the particle residence time distribution (RTD) made in the riser of a square cross section, cold model, circulating fluidised bed, using the fast response particle RTD technique developed by Harris et al. (Chem. Eng. J. 89 (2002a) 127). This technique depends upon all particles having phosphorescent properties. A small proportion of the particles become tracers when activated by a flash of light at the riser entry; the concentration of these phosphorescent particles can subsequently be detected by a photomultiplier. The influence of the solids circulation rate and superficial gas velocity on the RTD were investigated. The results presented are novel because (i) the experiments were performed in a system with closed boundaries and hence give the true residence time distribution in the riser and (ii) the measurement of the tracer concentration is exceedingly fast. The majority of previous studies have measured the RTD in risers with open boundaries, giving an erroneous measure of the RTD.Analysis of the results suggests that using pressure measurements in a riser to infer the solids inventory leads to erroneous estimates of the mean residence time. In particular, the results cast doubt on the assumption that friction and acceleration effects can be neglected when inferring the axial solids concentration profile from riser pressure measurements.An assessment of particle RTD models is also given. A stochastic particle RTD model was coupled to a riser hydrodynamic model incorporating the four main hydrodynamic regions observed in a fast-fluidised bed riser namely (i) the entrance region, (ii) a transition region, (iii) a core-annulus region and (iv) an exit region. This model successfully predicts the experimental residence time distributions.     

Low-temperature methanol synthesis in a circulating slurry bubble reactor

A circulating slurry bubble reactor was developed to synthesise methanol via methyl formate from the gas mixture of carbon monoxide and hydrogen at low temperature. The strategy for designing and scaling up the bubble reactor involved a preliminary understanding of fluid dynamics in a cold model, continuous operations under industrial conditions and a parallel experiment in an autoclave. Per-pass syngas conversion was investigated during 100-h operations. The axial profile of solid catalyst concentration was measured just before the shutdown and the composition of liquid product was analysed after the shutdown. These results show that the circulating slurry bubble column will become a potential reactor for the commercial process of low-temperature methanol synthesis after the catalyst system has been improved.     

新型气升式环流反应器流场数值模拟

利用CFD软件ANSYS 14.0及欧拉-欧拉多相流模型,模拟了一种采用微孔曝气器的新型气升式环流反应器的气液两相流动,得到反应器内气含率和循环液速等参数的详细分布。模拟结果表明：新型气升式环流反应器的平均气含率与气量成正比关系;气量为2.5 m3/h时具有更高的循环液速。     

Impac塔填料在冷却塔中的应用

在对比国内外冷却塔填料现场应用情况的基础上，总结了Impac塔填料及喷嘴应用的优势及存在的问题，说明了Impac塔填料热力性能传质传热效果及Lantc喷头的布水情况，通过经济效益对比分析表明，该填料及喷头具有良好的应用前景；同时，该填料具有施工安装方便等特点，对解决冷却塔冬季结冰也有好处，为冷却塔改造填料喷嘴的选型提供了新途径。     

Biomass pyrolysis in a circulating fluid bed reactor for the production of fuels and chemicals

An approach for biomass flash pyrolysis in a circulating fluid bed (CFB) reactor with continuous solids regeneration is described in this study. The unit is capable of performing conventional and catalytic biomass pyrolysis with the proper solid selection. The production of improved quality liquid products in a direct step through catalytic pyrolysis is investigated in this work. Both conventional and catalytic biomass pyrolysis can be effectively performed in this CFB unit. Flash pyrolysis conditions were achieved and liquid product yields of ∼70 wt% (on biomass feed) were obtained. The effect of specific operating variables including the type of inorganic solid material and the solid/biomass ratio was established on the final liquid product quality and yield. Solid materials considered included silica sand, a commercial fluid catalytic cracking catalyst and a ZSM-5 additive. Catalytic biomass pyrolysis generally leads to the production of additional water, coke and gases compared to conventional pyrolysis. However, the obtained liquid product quality and composition is improved.