RFG—DMR降烯烃催化剂在重油催化裂化装置上的工业应用

介绍了东明石化集团Ⅱ套重油催化裂化装置使用RFG—DMR降烯烃催化剂的情况。该催化剂占系统藏量83％时进行的标定结果表明：该剂降低汽油烯烃含量效果比较明显。汽油烯烃体积分数由48．56％降到39．72％．下降了8．84％。汽油辛烷值没有降低。产品分布得到改善。重油裂化能力强。于气和焦炭选择性好。轻质油收率增加了1．07％，总液体收率增加了1．56％。     

生焦FCC催化剂反应性能研究

介绍了近年来国内外开发的几种与生焦催化剂反应性能有关的催化裂化新工艺及生焦催化剂在这些工艺过程中所发挥的主要作用。讨论了有关生焦FCC催化剂物化性能、反应性能以及焦炭沉积规律和焦炭结构组成等方面的研究进展,重点介绍了中国石化石油化工科学研究院在本领域的最新研究工作。     

FCC汽油后加工技术滞后与MTG的发展机遇

针对我国FCC汽油高硫、高烯烃、低芳烃和高辛烷值组分不足,现阶段后加工技术研究与应用相对滞后,甲醇产能严重过剩以及甲醇制汽油优于煤液化的实际,提出推广和发展MTG项目的建议.     

丙烯生产技术的研究进展

综述了丙烯的主要生产技术及其进展,详细介绍了烯烃的蒸汽裂解、催化裂化优化增产丙烯、丙烷脱氢和甲醇转化成烯烃等制取丙烯技术。丙烯生产工艺的发展方向是提高裂解的选择性,进一步提高催化裂化的裂解深度并加大重质原料的加工力度,以及寻找生产丙烯的新原料。     

LDO-75重油催化裂化催化剂的工业应用

介绍了LDO-75重油裂化催化剂在中国石油大连石化公司年产3.5 Mt重油催化裂化装置的工业应用.结果表明,LDO-75催化剂达到系统总藏量50%后,装置催化剂单耗由1.34kg·t-1降至1.04 kg·t-1,干气和油浆收率分别降低0.03%和1.36%,液化气收率增加1.19%,总液收提高1.42%.     

Estimation of the number of trays for natural gas triethylene glycol dehydration column

The paper deals with the tray-to-tray method for determining the required number of trays in columns with intensive entrainment of liquid when the operating line of the “dry working regime” is not straight and with a small concentration of diffusing component in gas. Presented calculations show that the number of transfer units for gas and liquid should be calculated using the AIChE method accompanied with longitudinal mixing according to Gilbert properly transformed for case of diffusion through stagnant film. The suggested method can be applied for TEG dehydration absorbers-columns for dehydration of natural gas using triethylene glycol with system factor SF = 0.5.     

原油储运库的全能流模型

将过程系统分析理论应用于原油储运库的用能分析,提出原油储运库全能流模型概念.按照分解-综合-分解的模式,将系统分解为最基本的单元设备,分析用能实质、划分用能过程,建立单元模型;以原油、能量在系统中的转移为线索,结合工艺流程将单元设备综合为系统结构模型;最终给出系统计算框图,结合实际运行数据,确定系统各个节点的水力、热力...     

流化催化裂化原料加氢预处理技术综述

综述了流化催化裂化（FCC）原料加氢处理的目的、反应机理、催化剂和工艺流程选择以及操作模式。     

国产汽油进气阀沉积物的生成特性研究

对国产催化裂化汽油形成进气阀沉积物(IVD)的机理进行了研究,明确了烯烃、芳烃及非烃组分的沉积物生成特性,并对汽油馏分、胶质含量和发动机工作温度等影响因素进行了系统的分析考察,为改善国产汽油的清净性能、研发与国产汽油相适应的高效清净剂提供了理论基础.     

Gas and solid behaviours during defluidisation of Geldart-A particles

Bed collapsing experiments were carried out in a cold-air transparent column 192 mm in diameter and 2 m high. Typical Fluid Catalytic Cracking (FCC) catalyst with a mean particle size of 76 μm and a density of 1400 kg/m³ was used. Both single and double-drainage protocols were tested. The local pressure drop and bed surface collapse height were acquired throughout the bed settling.Typical results were found regarding dense phase voidage of a fluidised bed and the bed surface collapse velocity. In addition, bubble fraction was calculated based on the collapse curve.Experimental results showed that windbox effect is significantly reduced compared to previous works since the volume of air within the windbox was reduced. The comparison of single/double-drainage protocols revealed a new period in the defluidisation of Geldart-A particles concerning gas compressibility. Through the temporal analysis of local pressure drop, the progress of the solid sedimentation front from bottom to top was determined, analysed and modelled.