炭分子筛概述

阐述了炭分子筛分离的原理，并分别从其制备原料、制备方法、产品用途等方面综述了近年来炭分子筛的新进展。     

自控系统在加氢反应工艺中的应用

通过对化工生产中加氢反应的危险性简要介绍,并以某药厂对加氢反应工艺自控系统改造时从自控方案选择到自控参量、主要自控设施确定及安装、校验和系统调试等主要过程实施为例,说明此种危险可行性,为药厂类加氢工艺自控系统的技术改造提供相应的参考。     

低熔点合金填充聚合物材料断口形貌研究

研究了合金元素、加工温度、金属含量、第三组分对低熔点金属填充聚合物材料断口形貌的影响。实验结果表明:不同的合金对体系的影响很大,低分子量、低结晶性聚合物,高的成型加工温度可提高材料的相容性。     

新型高压密封装置的优化设计

以最低制造成本为优化目标，建立了新型高压密封装置优化设计的数学模型，并给出设计实例。结果表明，采用优化设计可降低制造成本１４．７％。     

Using electric actuation and detection of oscillations in microcantilevers for pressure measurements

Response characteristics of a microcantilever, such as resonant frequency, amplitude, phase and quality factor, can be used for absolute pressure measurements in the range of 10⁻⁴ to 10³ Torr. To this end, it would be very convenient to have the resonance of the microcantilever actuated and detected electrostatically. Herein, we report the nonlinear dynamics of microcantilevers under varying pressure and different gases using the harmonic detection of resonance (HDR) technique [J. Gaillard, M.J. Skove, R. Ciocan, A.M. Rao, Electrical detection of oscillations in 340 microcantilevers and nanocantilevers, Rev. Sci. Instrum. 77 (2006) 073907]. The HDR technique exploits nonlinearities in the cantilever-counter electrode system to allow electrostatic actuation and detection of the responses of the microcantilever to the pressure and gas composition. In particular, the 2nd and 3rd harmonics of the measured charge on the cantilever are investigated. The microcantilever demonstrates a quality factor of 10,000 at 10⁻³ Torr, and a usable response in the range from 10⁻³ to 10³ Torr. The use of different harmonics can enable us to adjust the range of pressures over which the sensor has an efficacious response, enhancing its sensitivity to a particular environment. The experimental results are in reasonable agreement with theoretical calculations, despite the nonlinearities involved.     

回转体头部压力分布规律及其对转捩点的影响

以圆头回转体为研究对象,头部线型采用双参数椭圆曲线,利用面元法求解绕流势流流场,利用F.W.Scholkemeier的积分方法,确定该压力分布下的层流边界层,利用P.S.Granville方法求解边界层转捩点.通过变换头部线型参数,以最小压力系数绝对值的下降方向为搜索方向,研究不同头型压力分布的变化规律及其对转捩点的影响.结果表明:最小压力系数绝对值越小的头型其最小压力点离头部驻点的距离越近;不同头型的转捩点不光与其压力分布有关,而且还与其头部长径比有关.     

Crack propagation of pipeline steel exposed to a near-neutral pH environment under variable pressure fluctuations

This investigation attempts to understand the corrosion fatigue crack propagation behavior of pipeline steels exposed to near-neutral pH environments. The fatigue loading was designed to simulate the underload-type variable amplitude pressure fluctuations found during pipeline operation. The effects of amplitudes (R ratios) of underload and minor cycles were investigated. It has been found from this investigation that the crack growth rate is enhanced significantly through load interaction of the variable amplitude fatigue. The acceleration factor is found to be up to 2.7 and 5.3 for tests in air and in the near-neutral pH solution, respectively. The crack growth rate decreases with R ratios of underload and minor cycles for tests both in air and in near-neutral pH environments. The latter could enhance crack propagation by a factor of up to 11, as compared with the crack growth rate in air. The critical R ratio of minor cycles at which the minor cycles do not contribute to crack propagation through load interaction was determined to be as high as 0.982, which is much lower than the threshold determined by constant amplitude fatigue. This critical R ratio could be utilized to demarcate stress corrosion cracking and corrosion fatigue, and should be incorporated as one of the design principles for components/structures subjected to variable amplitude cyclic loading.     

水分对分子筛结构及吸附性能的影响

分子筛是变压吸附制氧过程中最重要的组分,使用中该组分常出现吸水失效问题,极大地影响了氧产量及浓度.针对此问题,本文以HD-1型和PU-8型分子筛为原料,通过在不同温度(100、200、300、400℃)下活化得到不同含水量的分子筛,并通过对不同材料的结构形貌、热性能及吸附性能的表征分析了水分对分子筛结构及吸附性能的影响.研究结果表明:水分不会破坏分子筛的骨架结构,但会增大晶胞参数,并导致HD-1型分子筛中阳离子迁移;分子筛中的物理吸附水和化学结晶水会影响其吸附性能,其中物理吸附水的影响最大;活化有效提高了分子筛的吸附性能,且温度越高,含水量越少,吸附性能越好;在150~180℃下活化,将物理吸附水脱附后,分子筛的吸附能力可恢复70%,可在此温度下进行吸附器内低温活化;在400℃下活化,脱除化学结晶水,分子筛吸附性能可100%恢复,400℃为两种分子筛的最佳活化温度.