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11.
The reactivity of O-, T- and R-phases of the high pressure-high temperature (HPHT) polymerized C60 towards gaseous fluorine in the temperature range of 50-250 °C was investigated. The reaction products were characterized by FTIR, powder X-ray diffraction, SEM, EDX, and VTP-EIMS to determine the bulk stoichiometries, bonding patterns, phase compositions, crystalline structures and thermal decomposition behavior of the fluorinated polymers. At 1 h isothermal treatment duration, fluorinated products with various bulk stoichiometries were obtained from different polymer phases with the R-phase showing the highest fluorine uptake. At 250 °C, all C60 polymers showed partial decomposition to unfluorinated C60 monomer under fluorine atmosphere. At 200 °C, the fluorination of R-phase yielded a pure fluoropolymer most likely having a {C60Fx}n (x = 36-44) composition. The same fluoropolymer was presumably obtained from O- and T-phases in lower yields. The linear chain structure was suggested for this new fluorocarbon polymer in agreement with the molecular mechanics modeling calculations. 相似文献
12.
[60]Fullerene (C60) was mono-substituted with well-defined poly(methyl methacrylate) (PMMA-b-C60) using the atom transfer radical polymerization (ATRP) technique. The self-assembly behaviors of PMMA-b-C60 in ethyl acetate (EA) and decalin mixtures were studied using laser light scattering (LLS) and transmission electron microscopy (TEM). Homogeneous solutions of PMMA-b-C60 can be obtained in the solvent mixtures containing more than 40 wt% EA, where the molar ratio of decalin to EA is close to 1. For each solvent mixture, unimers coexist with micelles and large aggregates. The sizes of PMMA-b-C60 micelles and aggregates are independent of polymer concentration, confirming that they are produced via the closed association mechanism. For the various solvent mixtures, the weight-averaged molecular weights, Mw of the PMMA-b-C60 aggregates range from 4.1×107 to 12.5×107 g/mol. The hydrodynamic radii of the large aggregate, Rh, vary from 90 to 136 nm, while the z-averaged radii of gyration, Rg, range from 210 to 311 nm. The Rg/Rh value for each solvent mixture is ∼2.3, which is independent of decalin contents in the mixed solvents. The morphological study using the transmission electron microscope suggests that the large aggregates are composed of porous large compound micelles (LCM) in solution. 相似文献
13.
Endohedral metallofullerenes M@C2n (M=La, Y) were synthesized by the arc-discharge method using optimum electric arc parameters. It was also shown that an organic solvent (N,N-dimethylformamide) is successfully used in selective extraction of M@C2n. We identified the resulting products by mass spectrometry, electron spectrophotometry, EPR and X-ray fluorescence spectroscopy. The resulting N,N-dimethylformamide extracts of La@C2n and Y@C2n are shown to be free of empty fullerenes and appear as a mixture of endometallofullerenes M@C2n whose main ingredient is M@C82 (∼80 wt%). Transport properties of the extracts of La@C82 and Y@C82 were studied using pressed pellets. It was found that oxygen and heat treatment affect conductivity of endometallofullerenes. Heat treatment results in a three-order increase of conductivity from 10−5 upto 10−2 Ohm−1 cm−1 相似文献
14.
Zahra YarahmadiAli Reza Ashrafi 《Computers & Mathematics with Applications》2011,62(1):319-325
The bipartite edge frustration of a graph G, denoted by φ(G), is the smallest number of edges that have to be deleted from G to obtain a bipartite spanning subgraph of G. This topological index is related to the well-known Max-cut problem, and has important applications in computing stability of fullerenes. In this paper, the bipartite edge frustration of an infinite family of fullerenes is computed. Moreover, this quantity for four classes of graphs arising from a given graph under different types of edge subdivisions is investigated. 相似文献
15.
基于改进型Elman神经网络,建立了电站锅炉受热面污染在线监测软测量模型,为锅炉吹灰优化策略提供了理论依据。将软测量模型与传统吹灰程控系统融合所形成的智能吹灰程控系统采用模块化方法构建,集灰污在线监测、数据分析、信息管理和优化指导、控制功能一体化。该系统有助于加强吹灰管理,指导运行人员及时、合理吹灰、优化吹灰,达到提高机组安全性和经济性的目的。 相似文献
16.
介绍了C60结构、制备以及物理化学性质,并初步探索它在固体推进剂中的应用可能性。指出球烯及衍生物对固体推进剂燃烧性能的改进将会提供广阔的前景。 相似文献
17.
Franco Cataldo 《Fullerenes, Nanotubes and Carbon Nanostructures》2005,13(3):239-257
A series of selected halomethanes were treated with the submerged carbon arc using graphite electrodes at 10A. CCl4 and CHCl3 produce abundant soot which is double in comparison to the soot produced by arcing CH2Cl2 and is one order of magnitude higher than the amount of soot produced by arcing hydrocarbons such as n-hexane or decalin and two orders of magnitudes higher in comparison to the amounts of soot produced by arcing alcohols. It was found a anticorrelation between the amount of polyynes present in the solution of the arced solvent and the amount of soot produced by arcing. In the case of CCl4 and CHCl3 no polyynes were detected by liquid chromatographic analysis (HPLC-DAD), while polyynes were detected in CH2Cl2 and are present in higher concentration in arced hydrocarbon solutions. The soot produced from halomethanes was analyzed by FT-IR spectroscopy in comparison to the soot produced by arcing hydrocarbons and alcohols. Furthermore, the soot from halomethanes was analyzed by HPLC-DAD after extraction with acetonitrile and found to contain a mixture of halogenated polycyclic aromatic hydrocarbons (PAHs). Also CHClBr and CH2I2 were arced between graphite electrodes. The former compound produces free bromine and soot; bromine causes halogenation of the polyynes. In the case of the latter compound, free iodine is released from the arc and the amount of soot produced is comparable to that obtained by arcing CH2Cl2. 相似文献
18.
N-type organic thin film transistors (OTFT) containing modified gold electrodes have been fabricated to investigate the influence of the self assembled monolayer on the transistor characteristics. We report on the effect of drain/source modification by thiol derivatives on the performances, electrical parameters uniformity and electrical stability of C60 transistors. In the literature, electrical instability is often attributed to organic semiconductor (OSC), OSC-insulator interface and insulator. We found here that OSC-metal interfaces affect dramatically the operational stability for bottom gate/bottom contact structure. These effects have been attributed to morphological evolution at the interface metal-OSC induced by the self-assembled monolayers. 相似文献
19.
《Fullerenes, Nanotubes and Carbon Nanostructures》2013,21(3):245-255
Abstract Several dimers: C120, C140, C130 and their oxygen‐containing derivatives as well as some oligomers or polymers of the well known spherical fullerenes have been synthesized so far. Some of the formulas attributed to such compounds represent the first steps in a more complex fate leading to trivalent capped tubulenes. Such a way could even be followed by functionalized fullerenes. A detailed network transformation is given for C60 and its mono‐ and di‐epoxy derivatives. Semiempirical calculations support the presented findings. 相似文献
20.
In this work, the fullerene C60 nano-oil is proposed as a promising lubricant to enhance the performance of domestic refrigerator compressors. The stability of fullerene C60 nanoparticles dispersed in a mineral oil and the lubrication properties of the nano-oil were investigated experimentally. It was confirmed that the nanoparticles steadily suspend in the mineral oil at stationary conditions for a long period of time. The friction coefficients of the nano-oil significantly decrease with increasing the concentration of nanoparticles in the mineral oil, especially at the lower applied loads. The friction coefficients of the nano-oil with the concentration of 1–3 g L−1 are 12.9–19.6% lower than that of pure mineral oil. The applications of the nano-oil with the specific concentration of 3 g L−1 to two domestic refrigerator compressors were examined by compressor calorimeter experiments. The results shows the COPs of two compressors were improved by 5.6% and 5.3%, respectively, when the nano-oil was used instead of pure mineral oil. 相似文献