THE OLIGOCENE–MIOCENE MENILITE FORMATION IN THE UKRAINIAN CARPATHIANS: A WORLD‐CLASS SOURCE ROCK

This study investigates the hydrocarbon potential of Oligocene–Miocene shales in the Menilite Formation, the main source rock in the Ukrainian Carpathians. The study is based on the analysis of 233 samples collected from outcrops along the Chechva River in western Ukraine in order to analyse bulk parameters (TOC, Rock‐Eval), biomarkers and maceral composition. In Ukraine, the Menilite Formation is conventionally divided into Lower (Lower Oligocene), Middle (Upper Oligocene) and Upper (Lower Miocene) Members. The Early Oligocene and Early Miocene ages of the lower and upper members are confirmed by new nannoplankton data. The Lower Menilite Member is approximately 330 m thick in the study area and contains numerous chert beds and turbidite sandstones in its lower part together with organic‐rich black shales. The shales have a high content of silica which was probably derived from siliceous micro‐organisms. The TOC content of the shales frequently exceeds 20 wt.% and averages 9.76 wt.%. HI values range between 600 and 300 mgHC/gTOC (max. 800 mgHC/gTOC). The Middle Member contains thin black shale intervals but was not studied in detail. The Upper Member is about 1300 m thick in the study area and is composed mainly of organic‐rich shales. Chert layers are present near the base of the Member, and a prominent tuff horizon in the upper part represents a volcanic phase during shale deposition. The member grades into overlying molasse sediments. The average TOC content of the Upper Menilite succession is 5.17 wt.% but exceeds 20 wt.% near its base. Low T_max and vitrinite reflectance measurements for the Lower (419°C and 0.24–0.34 %R_r, respectively) and Upper (425°C and 0.26–0.32 %R_r, respectively) Menilite Member successions indicate thermal immaturity. Biomarker and maceral data suggest a dominantly marine (Type II) organic matter input mixed with varying amounts of land‐plant derived material, and indicate varying redox and salinity conditions during deposition. Determination of the Source Potential Index (SPI) shows that the Menilite Formation in the study area has the potential to generate up to 74.5 tons of hydrocarbons per m². The Chechva River outcrops therefore appear to have a significantly higher generation potential than other source rocks in the Paratethys realm. These very high SPI values for the Menilite Formation may explain why a relatively small area in Ukraine hosts about 70% of the known hydrocarbon reserves in the northern and eastern Carpathian fold‐thrust belt.     

Geochemistry of upper Permian siliceous rocks from the Lower Yangtze region, southeastern China: implications for the origin of chert and Permian ocean chemistry

The Permian Chert Event is of great significance to understanding the geological evolution of the entire Permian; however, the origin of widespread chert formation is debated. We report new geochemical data from deep-marine siliceous rocks of the upper Permian Da-long Formation, Lower Yangtze region, southeastern China. Their geochemical results show that these thin-bedded siliceous rocks have a clear biologic origin, with rare to no evidence of hydrothermal influence. The values of Al/(Al + Fe + Mn) and Eu/Eu* are 0.60–0.84 (mean = 0.72) and 0.45–1.08 (mean = 0.77), respectively, and Mn/Ti ratios are relatively low (mean = 0.72). The correlations of La_N/ CeN, La_N/ Yb_N, and Fe₂O₃/ TiO₂ with Al₂O₃/(Al₂O₃ + Fe₂O₃), along with the Ce anomaly, indicate that the Da-long siliceous rocks were deposited at a transitional zone between a continental margin and the open ocean; i.e., relatively close to terrestrial sediment input and far from hydrothermal activity. The accumulation of chert is related to its unique paleogeographic location in an equatorial setting with many submarine paleo-highlands. Intense upwelling and frequent local volcanism are the main factors that promoted the development of siliceous rocks in the studied area. Ocean acidification triggered by large-scale volcanism (Large Igneous Province) during the late Permian led to extensive silica precipitation and preservation.     

Geochemical characteristics of the Permian marine mudstone and constraints on its provenance and paleoenvironment in the Fenghai area, Fujian Province, southeastern China

Permian marine strata have gradually become a research focus in the world. The marine strata of the Late Permian Dalong Formation (P₃d) in the Fenghai area, Fujian Province, have become more and more important as their geochemical characteristics record important geological information and are a good indicator for recovering and reconstructing the paleosedimentary environments and tectonic attributes. The major elements, trace elements and rare earth elements were analyzed by XRF and ICP-MS, respectively. Based on the results of detailed field geological surveys, profile measurements as well as typical sample collection, the tectonic setting and provenance of Permian marine mudstone were comprehensively discussed. The results showed that the Dalong Formation (P₃d) was deposited in an active continental margin tectonic environment as revealed by the relation between Fe₂O₃ + MgO and TiO₂ and Al₂O₃/SiO₂. The fingerprint characteristics of Mn, Fe, Co, Ni and REE and the ratio of U/Th, V/Cr, Sr/Ba, (La/Yb)_N and V/(V + Ni) indicated that the sedimentary provenance was mainly derived from potassium feldspar, followed by muscovite. Sedimentary water bodies showed a gradually decreasing depositional rate trend, water depth gradually shallowing and paleo-salinity and productivity gradually increasing. Moreover, since transient delamination occurred during sedimentary processes, sedimentary water bodies showed obvious neritic characteristics. It was consistent with the results revealed by lithological and geochemical characteristics. Calcareous mudstone and siltstone transitioned into fine sandstone from bottom to top, indicating paleo-water bodies became shallow. The research results provided good reference and guidance for understanding Permian paleo-sedimentary environments and tectonic attributes of the Yong’an area, Fujian Province, southeastern China.     

超大规模集成电路快速热处理技术

本文介绍了快速热处理技术的研究成果.包括:RHT设备,高剂量注入硅的RTA机理与最佳RTA条件选择,以及浅PN结制造,硅化物形成,BPSG回流和薄氧化层的快速氮化等RTP技术.     

石英光纤中受激喇曼散射光谱形成及其能量转换

将泵浦光产生的受激喇曼散射（ Ｓ Ｒ Ｓ） 光谱看作新的独立的单色光源,在光纤内传播的过程中,每个光源按喇曼增益曲线各自独立地激发新的斯托克光谱, 因此 Ｓ Ｒ Ｓ 光谱曲线是光谱内无数个单色光源之间相互吸收相互放大的结果。据此,建立耦合波方程,利用 Ｒｕｎｇｅ － － Ｋｕｔｔａ方法可以计算 Ｓ Ｒ Ｓ 光谱。文中讨论了一阶斯托克光谱的形成,同阶斯托克光谱内的能量红移现象,高阶斯托克光之间以频移４４０ ｃｍ － １ 传递能量以及频带展宽等问题     

元器件纯锡镀层表面晶须风险评估与对策

讨论了各种锡晶须的形态以及其长度的具体测量方法,并在试验研究的基础上进一步分析抑制非光滑(哑光)纯锡镀层上锡晶须生长的对策.研究结果表明,增加锡镀层厚度(＞7 μm),或通过使用添加剂来产生更加粗糙的表面以适当增大晶粒尺寸,电镀完成后及时进行退火程序是进一步减轻雾锡镀层上锡晶须困扰的有效手段.如果引入Ni作为中间镀层,则需要达到一定的厚度(估计＞0.7 μm),方可达到预期的效果.     

编队卫星SAR系统的模糊函数分析

从编队卫星SAR的特点出发,定义了编队卫星SAR的模糊函数,推导出了模糊函数的数学表达式,并进行了计算机仿真。仿真结果充分验证了本函数的有效性。通过分析模糊函数可以直观地看出编队卫星构型对系统分辨率的影响,这为卫星构型的选择提供了依据。     

Hydrothermal synthesis of SnO2 nanocorals,nanofragments and nanograss and their formaldehyde gas-sensing properties

Morphology plays an important role in the properties of nanomaterials. We successfully synthesized three new SnO₂ morphologies, nanocorals, nanofragments and nanograss, via a simple hydrothermal method with surfactant additives. The final products were characterized by field-emission scanning electron microscopy and X-ray diffraction. We found that the surfactants played a critical role in the synthesis of different SnO₂ nanostructures. In particular, when poly(ethylene glycol) was added as a surfactant, a unique grass-like structure was obtained. The mechanism of formation for this novel structure is discussed. The gas-sensing performance of all the products was investigated. The results show that the nanograss morphology had a superior gas response to formaldehyde than the other morphologies.     

准噶尔盆地车2井区储层建模

准噶尔盆地车2井区齐古组主要为辫状河流相沉积,对该储层建立沉积岩性、岩相或储层结构模型,根据不同沉积相的储层参数定量分布规律,分相进行井间插值或随机模拟,提高了储层描述的水平和速度,准确地反映出油藏的构造、沉积、物性与含油性等方面特征,为该地区以后的数值模拟打下了坚实基础。