药用中间体苯丙酮含量的气相色谱/质谱分析

苯丙酮是合成利胆药苯丙醇的重要中间体。本文建立了用气相色谱 /质谱法 (GC/MS)测定苯丙酮含量的方法。组分的定性依靠GC/MS联用技术和NIST谱库标准质谱图对照分析。以苯乙酮为内标 ,苯丙酮含量在 1.0× 10 -5～ 2 .0× 10 -4g/mL范围内呈线性 ,线性相关系数r =0 .994 9,苯丙酮最低检测浓度为 1.0× 10 -8g/mL。该法操作简便、快速 ,结果准确可靠 ,且具有很好的实用价值     

LOCAL EQUILIBRIUM THEORY FOR THE DYNAMICS OF NONISOTHERMAL MIXED GAS ADSORPTION OF HIGH-CONCENTRATION COMPONENTS

A local equilibrium theory for nonisothermal gas adsorption is developed which accounts for variations in interstitial gas velocity induced by adsorption. Also presented are expressions describing the entropy admissibility criterion. A solution is developed for a Riemann's problem involving adiabatic gas-phase adsorption where there is no inert diluent and where Langmuir isotherms apply.     

A reverse osmosis desalting plant operated by gas turbines

Power plants in Kuwait use gas turbines (GT) only for a few hours to produce power at peak load times. Peak loadoccurs in the summer due to the air-conditioning load. As an example, the average number of operating hours for six gas turbines in the Doha East power plant was 16 in the summer of 2001. There is little concern about efficiency of these GT since they work for a very short time during the year. However, a recent increase in desalted seawater demand suggests the use of these GT to operate reverse osmosis (RO) desalting systems all year around. The summer outside design temperature in Kuwait for air-conditioning calculations is 48°C dry bulb temperature (DBT), and 28°C wet bulb temperature (WBT); but the ambient temperature can easily reach 60°C. Gas turbine power output and efficiency are drastically reduced by the increase in temperature of intake air to the gas turbine's compressor, especially during harsh Kuwaiti summer conditions. Thus, it is essential to investigate cooling of air intake to the GT compressor. The performance of a typical GT unit and its ability to produce desalted waterby a RO desalting system at different ambient temperatures are presented. Calculation of needed capacities for the cooling of intake air to the GT compressor was performed for evaporative cooling, single and multiple mechanical vapor compression cycles, and combined indirect evaporation cooling with the refrigeration system. The improvements of power output and efficiency due to the cooling of air intake of the GT and the resulting increase in desalted water are also presented.     

Calculation of single adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms on activated carbon at high pressures

A method is developed for the calculation of single-component adsorption isotherms from gravimetrically measured binary gas mixture adsorption isotherms at high pressures, at two temperatures and for different mole fractions of the gas phase. The adsorption of nitrogen/methane on active carbon Norit R1 is taken as an experimental example.     

Deformation transition of intact coal induced by gas injection

Gas migration in coal bed is a multiple-physical process, of which not only includes gas desorption/diffusion through coal matrix and gas Darcy flow through the cleat system, but also results in deform...     

铁路选线环境影响量化分析计算方法及应用研究

根据防护费用法、影子工程法等折算办法对环境破坏导致的经济损失等价为具体货币值,并将这些环境影响量化分析计算方法应用于西宝客运专线建设的环境评价问题中.结果表明:提出的算法对铁路选线多目标决策方案比选有应用价值.     

抽真空截止点的位置对压铸件气孔的影响

在真空压铸中 ,抽真空截止点的确定对压铸件的品质影响很大 ,过早和过迟将影响压铸的连续生产和不利于减少铸件的气孔。抽真空截止点应设在冲头快压射前 15～ 2 0mm处 ,真空压铸可以提高铸件的密度 1%以上。     

一种新型气硬冷芯盒树脂砂工艺试验及其在生产中的应用

原砂加入2．5％水溶性酚醛树脂，固化剂为甲酸甲脂，加入量占树脂的30％～40％。先把甲酸甲脂在气体发生器中气化，然后再与40％的压缩空气混合，吹气硬化制芯，最高抗拉强度1．2MPa，抗压强度0．32MPa，发气量12mL／g。生产浇注试验表明：砂芯表面光洁，轮廓清晰，尺寸精确，铸件缺陷少，无毒或低毒，和一般冷硬树脂砂比较，成本降低30％。     

天然气长输管道燃驱机组控制系统优化技术

燃气轮机驱动的压缩机组被广泛地应用在天然气长输管道,其控制系统优化技术的大范围深度应用在管道行业尚数首次,及时消除生产瓶颈的同时,也为涉及燃机的控制专业同行提供了技术借鉴,更重要的是为管道行业燃机运行提供了安全保障。     

高压切割喷嘴冲击磨损的数值分析

以复用矿井含煤颗粒的水对高压切割喷嘴的磨损物理问题为研究对象,采用计算流体力学理论进行数值计算,分析讨论了质量浓度为10、15、20、25、30、40 mg/L条件下速度、剪应力、磨损的分布以及变化关系。计算、分析结果表明:磨损主要发生在出口部位和锥体的后半部份,入口部份和锥体前半部份磨损较小;入口部位、锥体部位磨损量、剪应力随质量浓度增加变化较小;出口部位磨损量在质量浓度为10～20 mg/L减小较快,超过20 mg/L后变化不大;出口部位流体速度、磨损量、剪应力与质量浓度间存在对应关系。煤粒入口速度与混合物速度相同、锥体部位煤粒流体速度低于锥体部位混合物速度(平均值)约79.4%;煤粒出口部位速度随质量浓度的增大而呈现先增加后减小的趋势,速度最大值发生在浓度20 mg/L。