［Bmim］BF4-H2O-Na2CO3离子液体双水相体系液液相平衡数据的测定与关联

用浊点法测定了四氟硼酸1-丁基-3-甲基咪唑—水—碳酸钠体系在常压30℃下的溶解度曲线及密度曲线，并用经验方程进行了关联。用浊点—密度法测定了该体系的液液相平衡数据，绘制了相应的相图。结果表明：双水相体系一相以离子液体和水为主，碳酸钠的含量很少，另一相以碳酸钠和水为主，离子液体的含量很少。该体系既可作为萃取分离体系，也可作为从水溶液中分离回收离子液体的初步体系。用Othmer-Tobias+Bancroft经验方程对相平衡数据进行关联，最大相对误差为94.99%， 最大平均相对误差为15.69%，关联结果不理想。提出用Othmer-Tobias经验方程+溶解度方程对其进行关联，最大相对误差为4.52%，最大平均相对误差为2.77%，关联精度较高，该方法可适用于有一组分含量较低的体系的液液相平衡的关联计算。     

CONDENSING HEAT TRANSFER IN AN ADVANCED TWO-PHASE CLOSED THERMOSYPHON

1 INTRODUCTIONClosed thermosyphon has been developed to enhance heat transfer and recover wasteheat in various process industries [1,2].Stimulated by this success,a new type oftwo-phase closed thermosyphon was designed by inserting respectively two inner tubesinto the thermosyphon,one in the boiling section and the other in the condensing sec-tion.The two-phase flow boiling heat transfer coefficient was calculated successfully onthe basis of Chen's dual-mechanism [3].A boiling heat transfer model for thetwo-phase closed thermosyphon with an inner tube in the boiling section was pro-     

旋风分离器两相流研究综述

综述了旋风分离器内部流场、颗粒运动和数值计算模型的理论研究发展历程。     

A Numerical Sirnulation of Gas-Particle Two-Phase Flow in a Suspension Bed Using DifFusion Flux Model

A mathematical modei of two-dimensional turbulent gas-particle twophase flow based on the modified diffusion flux modei (DFM) and a numerical simulation method to analyze the gas-particle flow structures are developed. The modified diffusion flux modei, in which the acceleration due to various forces is taken into account for the calculation of the diffusion velocity of particles, is applicable to the analysis of multi-dimensional gas-particle two-phase turbulent flow. In order to verify its accuracy and efficiency, the numerical simulation by DFM is compared with experimental studies and the prediction by k-ε-kp two-fluid modei, which shows a reasonable agreement. It is confirmed that the modified diffusion flux modei is suitable for simulating the multi-dimensional gas-particle two-phase flow.     

高矣物的特性对双水相相图和头孢氨苄及7-ADCA分配行为的影响

A series of ethylene oxide(EO)-propylene oxide (PO) random co-polymers (EOPO) were used to form aqueous two-phase systems (ATPS) with ammonium sulfate.Effects of EOPO′s properties on the phase separation behaviors and on the partition of cephalexin and 7-aminodesacetoxicephalosporanic acid(7-ADCA) in ATPS were investigated.Both the molar mass and molar ratio of EO to PO of EOPO could greatly influence partition behaviors of cephalexin and 7-ADCA as well as the binodal curve of ATPS. With the increase of molar mass of co-polymer or the decrease of molar ratio of EO to PO,the critical point of ATPS decreased,the binodal curve became more asymmetry,and both cephalexin and 7-ADCA followed the same tendency to partition into the polymer-poor bottom phase.The experimental results shows that it is feasible to partition cephalexin and 7-ADCA in either the polymer-rich top phase or the polymer-poor bottom phase by choosing a specific phase-forming EOPO.     

气体释放速率对浅层气藏中气水运移的影响

为了论证在防治浅层气地质工程灾害中预先采取的有控制性排气措施的合理性和必要性,借助非饱和水气两相渗流原理,研究浅层气藏在气体释放路径下的气水运移规律.采用数值方法描述排气井不同释放速率对地下浅层气藏中气水运移的影响.结果表明:气体释放速率对气藏中的气水运移和分布形态有显著影响,释放速率越快,"水锥"效应越明显;实际工程中需结合详勘数据,选取适宜的排气速率,实施控制性放气措施,避免过早发生淹井,导致气井快速失效;在气藏中的浅层气体释放完毕后,砂土中会残留部分以气泡形式存在的气体,施工过程中需引起重视.     

沸腾两相流动压力波动信号的特性

研究了竖直管内沸腾两相流动时压力波动信号的特性,对压力波动时间序列进行了标准偏差分析、功率谱密度函数分析、分维数分析、相关维分析及Kolmogorov熵分析,考察了热流密度对压力波动的影响规律.结果表明沸腾两相流动具有非线性混沌特性,且热流密度对各特征参数有不同影响.     

Computational fluid dynamics (CFD) modeling of spouted bed: Influence of frictional stress, maximum packing limit and coefficient of restitution of particles

Following the previous article [Du, W., Bao, X., Xu, J., Wei, W., 2006. Computational fluid dynamics (CFD) modeling of spouted bed: assessment of drag coefficient correlations. Chemical Engineering Science 61 (5), 1401-1420], this contribution describes the influences of the frictional stress, maximum packing limit and coefficient of restitution of particles on CFD simulation of spouted beds. Using the two-fluid method embedded in the commercial CFD simulation package Fluent 6.1, the spouting hydrodynamics of a cylindrical-conical spouted bed was simulated and verified with the experimental data of He et al. [He, Y.L., Lim, C.J., Grace, J.R., Zhu, J.X., Qin, S.Z., 1994a. Measurements of voidage profiles in spouted beds. Canadian Journal of Chemical Engineering 72 (4), 229-234; He, Y.L., Qin, S.Z., Lim, C.J., Grace, J.R., 1994b. Particle velocity profiles and solid flow patterns in spouted beds. Canadian Journal of Chemical Engineering 72(8), 561-568]. The results showed that, for coarse particles, the frictional stress is important only for the annulus computation and has no obvious effects on the hydrodynamics of the solids flow in the spout region. The specification of the maximum packing limit could significantly affect the properties of the pseudo-fluid phase of the particles by changing the radial distribution function. The strong dependence of the pseudo-fluid properties of the particle phase, such as pressure, bulk viscosity and shear viscosity, on the granular temperature accounts for the influence of the coefficient of restitution of particles on CFD modeling. The solids volume fraction at loose packing state is suitable for spouted bed simulations, and a pretest of the coefficient of restitution of particles must be conducted when no experimental datum is available.     

五相感应电机及其调速系统的仿真

多相电机作为电机大功率化的有效途径之一,受到广泛关注,本文介绍了在MATLAB中Simulink仿真平台上五相感应电机及其调速系统的建模方法.通过广义两相实变换得到便于计算的多相电机模型.调速系统采用基于矢量空间解耦的矢量控制策略,实现转矩与励磁的解耦控制,达到如直流电机般的控制效果.     

采用控轧控冷工艺生产车轮用双相钢

介绍了车轮用热轧双相钢板的控制轧制与控制冷却工艺、组织性能和冲压使用效果，该产品强度高、塑性好，屈强比为0．64～0．68。