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51.
The 4-alkoxybenzoic acids are well-known liquid crystals showing several mesophases(nematic,smectic C phase or both)depending on the alkoxy chain length and whereby the rigid core of the mesogen is formed by intermolecular hydrogen bonds.In this paper it is shown that the thermal behaviour of lanthanide salts of 4-hexyloxybenzoic acids depends on the lanthanide ion(Ln=La,Pr,Nd,Sm,Eu).The lanthanum(Ⅲ)and praseodymium(Ⅲ)4-hexyloxybenzoates exhibit a smectic A mesophase.No mesophase is found for the corresponding compounds of heavier lanthanides.The thermal properties of the lanthanide(Ⅲ)4-hexyloxybenzoates were investigated by differential scanning calorimetry(DSC),polarising thermo-optical microscopy and synchrotron X-ray radiation. 相似文献
52.
Motion picture films are susceptible to local degradations such as dust spots. Other deteriorations are global such as intensity
and spatial jitter. It is obvious that motion needs to be compensated for before the detection/correction of such local and
dynamic defects. Therefore, we propose a hierarchical motion estimation method ideally suited for high resolution film sequences.
This recursive block-based motion estimator relies on an adaptive search strategy and Radon projections to improve processing
speed. The localization of dust particles then becomes straightforward. Thus, it is achieved by simple inter-frame differences
between the current image and motion compensated successive and preceding frames. However, the detection of spatial and intensity
jitter requires a specific process taking advantage of the high temporal correlation in the image sequence. In this paper,
we present our motion compensation-based algorithms for removing dust spots, spatial and intensity jitter in degraded motion
pictures. Experimental results are presented showing the usefulness of our motion estimator for film restoration at reasonable
computational costs.
Received: 9 July 2000 / Accepted: 13 January 2002
Correspondence to:S. Boukir 相似文献
53.
Evaggelia D. Tzika Vassiliki Papadimitriou Theodore G. Sotiroudis Aristotelis Xenakis 《European Journal of Lipid Science and Technology》2008,110(2):149-157
The autoxidation at alkaline pH and enzymatic oxidation by mushroom tyrosinase of oleuropein, the dominant biophenol present in the fruits and leaves of Olea europea, was followed by both electron paramagnetic resonance (EPR) and absorption spectroscopy. For comparison, the same oxidation processes were applied to 4‐methylcatechol, a simple polyphenol present in olive mill wastewaters. EPR spectra of stable o‐semiquinone radicals produced during autoxidation at pH 12 and short‐lived o‐semiquinone free radicals produced during autoxidation at pH 9.0 or tyrosinase action and stabilized by chelation with a diamagnetic metal ion (Mg2+) were recorded for both polyphenols, and the corresponding hyperfine splitting constants were determined. The UV‐Vis spectral characteristics of the oxidation of polyphenols were highly dependent on the type of polyphenol, oxidant type and the pH of the reaction. The kinetic behavior of tyrosinase in the presence of oleuropein and 4‐methylcatechol was followed by recording spectral changes at 400 nm (absorption maximum) over time. The tysosinase activity with oleuropein showed a pronounced pH optimum at pH 6.5 and a minor one around pH 8. From the data analysis of the initial rate at pH 6.5, the kinetic parameters Km = 0.34 ± 0.03 mM and Vmax = 0.029 ± 0.002 ΔA400 min–1 were determined for oleuropein. 相似文献
54.
Mesoporous GaSBA-15 molecular sieves with different nSi/nGa ratios have been directly synthesized using Pluronic 123 triblock polymer as a structure-directing agent by pH-adjusting method. The mesoporous materials have been characterized using ICP-AES, XRD, N2 adsorption, 71Ga-MAS NMR, SEM and TEM. ICP-AES studies show a high amount of gallium incorporation on the silica pore walls. The structural and textural properties of calcined GaSBA-15 are characterized by XRD and N2 adsorption. 71Ga MAS NMR results demonstrate that a high amount of tetrahedral-gallium could be substituted for Si in the framework of SBA-15. TEM and FE-SEM images show the uniform pore diameter and rope-like hexagonal mesoporous structure of GaSBA-15. These GaSBA-15 materials have been used as catalysts for vapour-phase t-butylation of 1,2-dihydroxybenzene (DHB) for selective synthesis of 4-t-butylcatechol (4-TBC) under different reaction conditions. GaSBA-15(10) gave the highest 93.2% conversion of DHB and 95.7% selectivity of 4-TBC as compared with other GaSBA-15 catalysts. 相似文献
55.
56.
报道以甲基丙烯酸羟乙酯与甲基丙烯酸甲酯的共聚物为载体膜材料,研制成非酶标记的T4免疫传感器,并对载体膜材料的共聚方法及共聚物共聚比与传感器灵敏度的关系进行了探讨。 相似文献
57.
通过小规模爆破试验,用线性回归方法对块煤进行筛分分析,指出影响炮采工作面块煤率的因素是炸药性能、装药结构、爆破参数、起爆顺序、时间间隔等。 相似文献
58.
Heat-shock induction of heat-shock protein genes is due to a specific promoter element (the heat-shock element, HSE). This study used lacZ under HSE control (HSE-lacZ) to characterize HSE activity in Saccharomyces cerevisiae cells of different physiological states and differing genetic backgrounds. In batch fermentations HSE-lacZ induction by heat shock was maximal in exponential growth, and showed marked decline with the approach to stationary phase. Expression in the absence of heat shock was unaffected by growth phase, indicating that the growth-dependent expression of many yeast heat-shock genes uses promoter elements in addition to the HSE. Heat-induced expression was strongly influenced by the temperature at which cultures were grown. While basal, uninduced expression was constant during growth at different temperatures to 30 degrees C, induction by transfer to 39 degrees C was reduced by increases in growth temperature as low as 18-24 degrees C. Maximal HSE-lacZ induction (30- to 50-fold) was in cultures grown at low temperatures (18-24 degrees C), then heat shocked at 39 degrees C. Ethanol was a poor inducer. Mutations having little effect on HSE-lacZ expression included a respiratory petite; ubi4 (which inactivates the poly-ubiquitin gene); also ubc4 and ubc5 (which each inactivate one of the ubiquitin ligases involved in degradation of aberrant protein). pep4-3 increased both basal and induced beta-galactosidase about two-fold, probably because of slower turnover of this enzyme in pep4-3 strains. 相似文献
59.
双噁唑啉化合物对PBT的增粘作用 总被引:1,自引:0,他引:1
以2.2'-双(2-唑啉)和双(2-唑啉基)苯作扩链剂,用焙融挤出的方法,对聚对苯二甲酸丁二酯(PBT)进行扩链,考察扩链剂的用量、反应时间和反应温度对PBT的特性粘度及端羧基含量(CV)的影响。结果表明,当用2,2'-双(2-唑啉)作扩链剂时,PBT的特性粘度[η]从0.799提高到0.926dL/g,CV降至5eq/10 ̄6g以下;当用双(2- 唑啉基)苯作扩链剂,[η]从0.763增至0.925dL/g,CV降至10eq/10 ̄6g以下,达到了较满意的扩链效果。 相似文献
60.
In 2006, an involutional block cipher using cellular automata was proposed. A self-invertible CA-based structure allows for an efficient hardware implementation. This paper analyzes the insecurity of the cipher due to its conjugate property. The results of this study will make it possible to construct a decryption process without knowledge of the secret key. 相似文献