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排序方式: 共有377条查询结果,搜索用时 15 毫秒
11.
Ahmed Labena Ahmed Hamed Eman H. I. Ismael Samy M. Shaban 《Journal of surfactants and detergents》2020,23(5):991-1004
The Egyptian oil and gas industry is suffering from severe metal corrosion problems, particularly microbial-induced corrosion. There is limited knowledge on the corrosion inhibition of carbon steels in the presence of an acidophilic, iron-oxidizing bacterial species Acidithiobacillus ferrooxidans. Therefore, in this study, novel Gemini cationic surfactants, in three forms depending on variation in alkyl chains of 8, 12, and 16 carbon atoms named FHPAO, FHPAD, and FHPAH, respectively, were synthesized and characterized by Fourier transform infrared and nuclear magnetic resonance spectroscopy. The surface parameters and the thermodynamic of the synthesized surfactants were evaluated at three different temperatures, 20, 40, and 60 °C. The synthesized Gemini cationic surfactants were tested as broad-spectrum antimicrobial, antibacterial and anticandida agents. They evaluated as biocides and corrosion inhibitors against Acidithiobacillus ferrooxidans. FHPAD showed higher adsorption ability at the solution interface and higher affinity to construct micelles than FHPAO and FHPAH. Both adsorption and micellization processes were hydrophobic and temperature dependent. FHPAO, FHPAD and FHPAH exhibited wide-spectrum antimicrobial activities, and the highest activity and the lowest minimum bactericidal/fungicidal inhibitory concentrations were attributed to FHPAD. Furthermore, synthesized FHPAD demonstrated the highest metal corrosion inhibition efficiency of 95.5% at 5 mM in comparison to 87.5% and 81.7% for FHPAO and FHPAH, respectively. In conclusion, this study provides novel synthesized cationic surfactants with many applications in the oil and gas industry, such as broad-spectrum antimicrobial, biocides, and corrosion inhibitors for acidophilic, iron-oxidizing bacterial species Acidithiobacillus ferrooxidans. 相似文献
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Sana Raouche Miguel Mauricio-Iglesias Stéphane Peyron Valérie Guillard Nathalie Gontard 《Innovative Food Science and Emerging Technologies》2011,12(4):426-434
Antimicrobial bio-sourced films based on poly(lactic acid) containing either carvacrol or allyl isothiocyanate (AITC) were prepared and their antimicrobial properties were assessed on Botrytis cinerea during storage and after a high pressure (HP) “pasteurisation-like” treatment (up to 800 MPa at ambient temperature). A dry process (extrusion + thermomoulding) was used to shape the material. The high temperature encountered during film processing dramatically decreased the carvacrol and AITC content in the film, leading to a less efficient antimicrobial activity. The use of β-cyclodextrin (β-CD) to encapsulate the active compounds before film processing proved to be efficient to protect the AITC against thermal degradation and to control its release from the films during its use. PLA-based films containing either AITC or β-CD encapsulated AITC showed a significant activity against B. cinerea. An effective combination between the antimicrobial activity of AITC-based films and the high pressure treatment was observed on a model food system (PDA) inoculated with N × 104 (N ~ 1–9) conidia of B. cinerea. An HP treatment of only 300 MPa associated with an antimicrobial PLA/β-CD system providing an initial quantity of active agents equivalent to 4 mg of AITC/L of air (i.e. almost 2 folds lower than the minimal inhibition concentration of the active packaging used alone, which was determined to be equal to 10 mg/L of air in the same conditions) was found more efficient (total inhibition of B. cinerea growth during 10 days) than an 800 MPa HP treatment used alone (increase of the lag phase growth of 3.3 days).
Industrial relevance
The consumer demand for “fresh like” product containing reduced amount of preservatives without compromising human and environmental safety needs the development of new preservation strategies. As a consequence, the concept of “hurdle technologies” has risen up. The combined effect of HP treatment and volatile antimicrobial packaging allowed the use of lower individual treatment intensities to inhibit B. cinerea growth. Combining such “hurdles” is of relevance in the context of development of low-cost and eco-friendly food technologies. 相似文献14.
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目的:测定常用食品防腐剂对西式火腿主要腐败菌的抑制作用。方法:采用微量稀释法测定不同防腐剂对木糖葡萄球菌、地衣芽孢杆菌和雷氏普罗威登菌的最小抑菌浓度(MIC)。结果:对于木糖葡萄球菌(G+),抑菌效果最好的是Nisin和ε-聚赖氨酸,MIC均为12.5μg/mL;对于地衣芽孢杆菌(G+),抑菌效果最好的是D-异抗坏血酸钠、丙酸钙、柠檬酸和柠檬醛,MIC均为12.5μg/mL;对于雷氏普罗威登菌(G-),抑菌效果最好的是过氧化氢和柠檬酸,MIC均为25μg/mL。结论:不同防腐剂对西式火腿肠主要腐败菌的抑制效果有所差异,应复配使用。 相似文献
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Jinpeng Shen Zhiqiang Qiao Jun Wang Kaili Zhang Rui Li Fude Nie Guangcheng Yang 《Combustion and Flame》2014
This study investigates pressure loss and compensation in the combustion process of Al–CuO metastable intermolecular composite (MIC) on a microheater chip. A ball cell model of pressure change in the combustion process is proposed to show the effects of pressure loss on the reaction rate and efficiency of energy output at microscale. An effective compensation method for pressure loss is then developed by integrating Al–CuO MIC with CL-20 (2,4,6,8,10,12-hexanitrohexaazaisowurtzitane) onto a SiO2/Cr/Pt/Au microheater chip. The combustion processes of Al–CuO MIC with different weight percentages of fine CL-20 particles on the microheater chips are observed by high-speed video recording. Results indicate that the reaction of Al–CuO MIC is a slow combustion process that turns into intense deflagration after adding fine CL-20 particles to Al–CuO MIC. The pressure–time characteristics indicate higher maximum pressure and pressurization rate for Al–CuO/CL-20 because the pressure loss at microscale is well compensated by the addition of fine CL-20. This study proves the importance of pressure loss in the combustion process of MIC at microscale and provides an efficient compensation strategy for pressure loss to improve the reaction rate and efficiency of energy output at microscale environment. 相似文献
18.
Polymer brush coatings for combating marine biofouling 总被引:4,自引:0,他引:4
Wen Jing Yang Koon-Gee Neoh En-Tang Kang Serena Lay-Ming Teo Daniel Rittschof 《Progress in Polymer Science》2014
A variety of functional polymer brushes and coatings have been developed for combating marine biofouling and biocorrosion with much less environmental impact than traditional biocides. This review summarizes recent developments in marine antifouling polymer brushes and coatings that are tethered to material surfaces and do not actively release biocides. Polymer brush coatings have been designed to inhibit molecular fouling, microfouling and macrofouling through incorporation or inclusion of multiple functionalities. Hydrophilic polymers, such as poly(ethylene glycol), hydrogels, zwitterionic polymers and polysaccharides, resist attachment of marine organisms effectively due to extensive hydration. Fouling release polymer coatings, based on fluoropolymers and poly(dimethylsiloxane) elastomers, minimize adhesion between marine organisms and material surfaces, leading to easy removal of biofoulants. Polycationic coatings are effective in reducing marine biofouling partly because of their good bactericidal properties. Recent advances in controlled radical polymerization and click chemistry have also allowed better molecular design and engineering of multifunctional brush coatings for improved antifouling efficacies. 相似文献
19.
在工程实践中,国家重要的海洋工程设施(如海底输油管线和船舶燃料系统等)发生的腐蚀破坏案例常常涉及到油水环境,并与微生物腐蚀作用密切相关,而了解海洋含油环境中石油烃类的生物转换机制是了解微生物腐蚀的关键。阐述了海洋环境中降解石油烃类的主要微生物及其降解机制,其在有氧和无氧条件下呈现不同的特点。微生物降解石油烃类过程中非常重要的一步即为接受电子,该过程将生物无法直接利用的化学能转换成可直接利用的能量形式,即腺苷三磷酸(ATP)。有氧条件下的烃类降解以氧气作为最终电子受体,而在缺氧条件下可利用硝酸盐、铁离子、硫酸盐等作为电子受体。海洋环境中的石油烃类会促进腐蚀性硫化物的生成,因此油水环境下的微生物腐蚀机理以硫化物的腐蚀破坏为主。此外,烃类降解过程产生的琥珀酸等酸性中间代谢物也会加剧腐蚀的发生。但目前关于海洋油水环境中微生物群落作为一个整体展现出的功能性及其对钢铁设施的破坏机理,仍然缺乏系统性的研究,而基于高通量测序的微生物组学研究技术将成为有效解决这些问题的手段之一。 相似文献
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