Extracellular polymeric substances (EPS) were studied with regard to their potential application as inhibitors of biocorrosion. EPS that have been isolated from biofilms of sulphate‐reducing bacteria (SRB) were adsorbed on samples of high alloyed steel (type 1.4301) at different temperatures. The samples were exposed to SRB containing solution and afterwards analysed by fluorescence microscopy (FM). The results show that the EPS form an incomplete layer and lead to a smaller amount of cell adhesion when compared to pure surfaces. The results are discussed with regard to the application of EPS for the prevention of biofilm formation. 相似文献
By covering amorphous silicon (a-Si) with a thin metal film, it is possible to lower the crystallization temperature of the a-Si (typically around 800 °C when using ramp anneals) to levels which can be used in a manufacturing process. This phenomenon of Metal Induced Crystallization (MIC) has been reported previously for Ni, Au and Al. In this work, in-situ X-ray Diffraction was used to study the MIC process for 20 different metals (Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Al). The 7 metals which lower the crystallization temperature the most are Ni, Pt, Pd, Cu, Au, Al and Ag. The crystallization kinetics were studied in detail for these 7 materials. In order to explain the MIC process, two models where used depending on the interaction of the metal with Si (eutectic or compound forming). 相似文献
The present study demonstrates different approaches towards MIC identification in three real cases of technological equipment failures.
In the first case the failure of carbon steel heat exchanger as a result of tubes, lids, tube sheets, and connection pipes clogging was investigated. Chemical analysis of cooling water and precipitates, as well laboratory screening of deposits for bacteria, revealed that activity of iron-oxidizing bacteria present in cooling water led to heat exchanger blockage.
The second case is related to MIC detection on floating roofs made of magnesium–aluminum alloy following a 3-weeks hydro-test. Corrosion tests carried out on the original and sterilized water used in hydro-test confirmed MIC process.
In the third case the potential of MIC occurrence in engine cooling system made of cast aluminum alloy and filled with 20% ethylene glycol coolant solution was evaluated. The simulation tests allowed determining the real causes of the severe corrosion attack of examined system, including MIC high probability. 相似文献
Bacterial influenced corrosion of AISI 316 stainless steels (SS) and ASTM A36 carbon steel by two strains of sulfate reducing bacteria (SRB) were analyzed. Thermophilic and mesophilic bacteria were isolated from the condensate fluid of “Los Azufres”, a geothermal electric field located in the State of Michoacan at Central Mexico. Anaerobic corrosion tests were carried out for 15, 30 and 60 days in lactate‐containing media at 50 °C and 40 °C. Scanning electron microscopy (SEM) was used to determine corrosion morphology. Pitting density was determined with an optical microscope. Corrosion potential, anodic potentiodynamic polarization curves and pH values were measured under anaerobic conditions. Results show that the microbial activity influenced the overall corrosion process, whereas, pitting corrosion and localized attack corrosion (LAC) were found. The anodic polarization curves show that passivation and activation processes should take place on the steel surface of the sample and pH decreases as the exposure time increases. 相似文献
The purpose of this study was to investigate the presence of β-lactam-resistant bacteria in six different types of Portuguese cheese. The numbers of ampicillin resistant (AMPr) bacteria varied from 4.7 × 102 to 1.5 × 107 CFU/g. Within 172 randomly selected β-lactam-resistant bacteria, 44 resistant phenotypes were found and 31.4% were multidrug resistant. The majority (85%) of the isolates identified belonged to the Enterobacteriaceae family. The presence of the blaTEM gene was detected in 80.9% of the tested isolates. The results suggest that without thermal processing of the milk and good hygienic practices, cheese may act as a vehicle of transfer of β-lactam-resistant bacteria to the gastrointestinal tract of consumers. 相似文献