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41.
The conversion of heavy paraffin and aromatics into a high-quality diesel fraction was performed in a microplant using a WNiPd/CeY-alumina catalyst. The effects of aromatics and naphtheno-aromatics on mild hydrocracking of hexadecane were studied at different concentrations. Two catalysts, with and without Pd and thermal treatment, were characterized by FTIR, XPS, and TPD of ammonia and ammonia plus naphthalene to complement previous study about the surface composition. The hydrocracking activity and selectivity were tested using different amounts and types of aromatics. This study demonstrated the presence of two acid strengths that contribute in different ways to paraffin and aromatics isomerization, ring opening, and cracking reactions. The product distribution obtained by mild hydrocracking of n-C16 is between amorphous (SiO2Al2O3) and Y-zeolite type of support. The aromatic adsorption on acid sites reduces the cracking rate and improves the survival of di- and tri-branched paraffin. A model for the path of reaction is discussed to explain the results. 相似文献
42.
制造业国有企业在我国国民经济中具有非常重要的地位,其发展状况因所处地区、行业的不同而存在很大差别。从总体上看,制造业国有企业在投入产出能力、企业运营能力、盈利能力和偿债能力等方面都有待于提高。制造业中大型国有企业保持了良好增长态势。国家重点企业通过增加研究与开发投入,发展后劲显著增强。制造业中国有企业的数量在大幅度减少,其所占的比重持续下降,在制造业的不少小行业中,非国有企业已经取代了国有企业,成为行业中的主要力量。 相似文献
43.
Dr. C. R. Nagarajah W. Thompson 《The International Journal of Advanced Manufacturing Technology》1994,9(5):333-342
There are two aspects to cell formation in flexible manufacturing systems, cell sizing or deciding on the optimum number of machines to be allocated to each cell, and then allocation of specific machines to each cell. Although the latter problem has been investigated extensively there is a paucity of published work on the former. This paper discusses the effects of cell sizing on operational flexibility.Operational flexibility is that aspect of flexibility that enables manufacturing systems to respond with speed and efficiency to changes in the manufacturing environment while maintaining an effective level of control. 相似文献
44.
This paper presents the development of an event-driven control architecture and its implementation in a physical simulator of a computerized manufacturing system using object-oriented techniques. The architecture was developed to improve the efficiency of handling concurrent control events in the DOS environment. In the implementation, the control system of the physical simulator consists of four distinct layers of control devices: a PC/386 computer, a microcontroller, I/O modules and the system's control devices such as motors, solenoids and sensors. A control program residing in the PC/386 coordinates system-level tasks such as event scheduling, while a BASIC program running on the microcontroller handles all low-level control tasks such as sensor monitoring and motion control. The concepts and developments presented in this paper should help in implementing an efficient control system for both CIM systems and their physical simulators. 相似文献
45.
An ordering of magnesium is observed in the as-synthesized MAPO-36 molecular sieve. Upon calcination, part of the magnesium is removed from the sample and part occupies extraframework positions thus rendering a random distribution of magnesium in the lattice. The shoulder observed in the31P spectrum of the calcined sample is assigned to P(3Al, 1Mg) sites in conflict with the earlier assignment to P-OH groups. The bridging hydroxyl groups located at these sites are detected in the1H MAS spectrum at 3.6 ppm. Further, MAPO-36 catalyzed acetone conversion to mesityloxide that cracked at elevated temperature to yield acetic acid and aliphatics. 相似文献
46.
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48.
More than one hundred samples of European beers have been investigated by the new SNIF-NMR method which is based on 2H NMR at the natural abundance level and enables site-specific natural isotope fractionation factors in ethanol to be determined. The relative (R) and absolute (D/H)i, parameters are shown to be characteristic of the country where the beers are brewed and the observed variations are explained in terms of cereal composition, water resource, and manufacturing processing (fermentation, yeast, temperature cycle). These new parameters find analytical and mechanistic applications in the identification of a beer and in the investigation of a fermentation process. 相似文献
49.
50.
A polyhedron P is castable if its boundary can be partitioned by a plane into two polyhedral terrains. Castable polyhedra can be manufactured
easily using two cast parts, where each cast part can be removed from the object without breaking the cast part or the object.
If we assume that the cast parts are each removed by a single translation, it is shown that for a simple polyhedron with n vertices, castability can be decided in time and linear space using a simple algorithm. A more complicated algorithm solves the problem in time and space, for any fixed ε > 0. In the case where the cast parts are to be removed in opposite directions, a simple O(n
2
)-time algorithm is presented. Finally, if the object is a convex polyhedron and the cast parts are to be removed in opposite
directions, a simple algorithm is presented.
Received June 1, 1994; revised May 25, 1995. 相似文献