基于耦合去噪算法的航空发动机中Si3N4圆柱滚子表面缺陷的检测方法

为解决基于机器视觉的传统单一图像去噪算法对混合噪声信号处理效果不佳,导致不能有效地检测识别航空发动机中应用的Si3 N4圆柱滚子表面缺陷问题,提出一种基于改进的耦合去噪算法与多尺度阈值分割算法相结合的视觉检测方法.通过优化的小波阈值去噪算法与改进的中值滤波算法相耦合方法对Si3 N4圆柱滚子的表面缺陷图像进行去噪处理,...     

Reversible Formation of g‐C3N4 3D Hydrogels through Ionic Liquid Activation: Gelation Behavior and Room‐Temperature Gas‐Sensing Properties

Many unique properties arise when the 3D stacking of layered materials is disrupted, originating nanostructures. Stabilization, and further reorganization of these individual layers into complex 3D structures, can be essential to allow these properties to persist in macroscopic systems. It is demonstrated that a simple hydrothermal process, assisted by ionic liquids (ILs), can convert bulk g‐C₃N₄ into a stable hydrogel. The gelation occurs through delamination of the layered structure, driven by particular interactions between the IL and the carbon nitride sheets, forming an amphiphilic foam‐like network. This study employs spectroscopic and computational tools to unravel the gelation mechanism, and provides a rational approach toward the stabilization of 2D materials in hydrogels. The solution‐processable hydrogels can also be used as building blocks of complex devices. Chemiresistive gas sensors employing g‐C₃N₄ 3D hydrogels exhibit superior response at room temperature, enabling effective gas sensing under low power conditions.     

Gold Nanoparticles and g‐C3N4‐Intercalated Graphene Oxide Membrane for Recyclable Surface Enhanced Raman Scattering

Toxic organic pollutants in the aquatic environment cause severe threats to both humans and the global environment. Thus, the development of robust strategies for detection and removal of these organic pollutants is essential. For this purpose, a multifunctional and recyclable membrane by intercalating gold nanoparticles and graphitic carbon nitride into graphene oxide (GNPs/g‐C₃N₄/GO) is fabricated. The membranes exhibit not only superior surface enhanced Raman scattering (SERS) activity attributed to high preconcentration ability to analytes through π–π and electrostatic interactions, but also excellent catalytic activity due to the enhanced electron–hole separation efficiency. These outstanding properties allow the membrane to be used for highly sensitive detection of rhodamine 6G with a limit of detection of 5.0 × 10^?14m and self‐cleaning by photocatalytic degradation of the adsorbed analytes into inorganic small molecules, thus achieving recyclable SERS application. Furthermore, the excellent SERS activity of the membrane is demonstrated by detection of 4‐chlorophenol at less than nanomolar level and no significant SERS or catalytic activity loss was observed when reusability is tested. These results suggest that the GNPs/g‐C₃N₄/GO membrane provides a new strategy for eliminating traditional, single‐use SERS substrates, and expands practical SERS application to simultaneous detection and removal of environmental pollutants.     

Fast,Scalable Synthesis of Micronized Ge3N4@C with a High Tap Density for Excellent Lithium Storage

Nanostructuring has significantly contributed to alleviating the huge volume expansion problem of the Ge anodes. However, the practical use of nanostructured Ge anodes has been hindered due to several problems including a low tap density, poor scalability, and severe side reactions. Therefore, micrometer-sized Ge is desirable for practical use of Ge-based anode materials. Here, micronized Ge₃N₄ with a high tap density of 1.1 mg cm⁻² has been successfully developed via a scalable wet oxidation and a subsequent nitridation process of commercially available micrometer-sized Ge as the starting material. The micronized Ge₃N₄ shows much-suppressed volume expansion compared to micrometer-sized Ge. After the carbon coating process, a thin carbon layer (≈3 nm) is uniformly coated on the micronized Ge₃N₄, which significantly improves electrical conductivity. As a result, micronized Ge₃N₄@C shows high reversible capacity of 924 mAh g⁻¹ (2.1 mAh cm⁻²) with high mass loading of 3.5 mg cm⁻² and retains 91% of initial capacity after 300 cycles at a rate of 0.5 C. Additionally, the effectiveness of Ge₃N₄@C as practical anodes is comprehensively demonstrated for the full cell, showing stable cycle retention and especially excellent rate capability, retaining 47% of its initial capacity at 0.2 C for 12 min discharge/charge condition.     

凹栅槽AlGaN/GaN HEMTs器件退火处理效应

研究了如何减小等离子体干法刻蚀导致的大肖特基漏电. 用X射线光电能谱（XPS）分析刻蚀前后的AlGaN表面,发现刻蚀后AlGaN表面出现了N空位,导致肖特基栅电流偏离热电子散射模型,N空位做为一种缺陷使得肖特基结的隧穿几率增大,反向漏电增大,肖特基势垒降低. 介绍了一种AlGaN/GaN HEMTs器件退火处理方法,优化退火条件为400℃, N2氛围退火10min. 退火后,栅金属中的Ni与Ga原子反应从而减少N空穴造成的缺陷,器件肖特基反向漏电减小三个量级,正向开启电压升高,理想因子从3.07降低到了2.08.     

适用于MMIC的功率合成器设计

设计了一种适用于对MMIC功率放大器进行合成的新型功率合成器。采用多端口网络理论对功率合成结构进行分析, 结合MMIC功放单片的工作特点总结出该功率合成器最重要的设计指标, 设计出工作在5GHz~6GHz的16路辐射线型功率合成器。通过测试发现该功率合成器的驻波〈1.5dB, 各端口幅度不平衡度〈±0.4dB, 相位不平衡度〈±2°, 并具有较好的隔离度, 整个功率合成器的直径小于56mm, 非常适合用于C波段大功率的合成。最终采用该功率合成器在5GHz~6GHz的工作频率内成功获得160W的合成功率。     

Photothermally Sensitive Poly(N‐isopropylacrylamide)/Graphene Oxide Nanocomposite Hydrogels as Remote Light‐Controlled Liquid Microvalves

A photothermally sensitive poly(N‐isopropylacrylamide)/graphene oxide (PNIPAM/GO) nanocomposite hydrogel can be synthesized by in situ γ‐irradiation‐assisted polymerization of an aqueous solution of N‐isopropylacrylamide monomer in the presence of graphene oxide (GO). The colors and phase‐transition temperatures of the PNIPAM/GO hydrogels change with different GO doping levels. Due to the high optical absorbance of the GO, the nanocomposite hydrogel shows excellent photothermal properties, where its phase transitions can be controlled remotely by near‐infrared (NIR) laser irradiation, and it is completely reversible via laser exposure or non‐exposure. With a higher GO loading, the NIR‐induced temperature of the nanocomposite hydrogel increases more quickly than with a lower doping level and the temperature can be tuned effectively by the irradiation time. The nanocomposite hydrogel with its excellent photothermal properties will have great applications in the biomedical field, especially as microfluidic devices; this has been demonstrated in our experiments by way of remote microvalves to control fluidic flow. Such an “easy” and “clean” synthetic procedure initiated by γ‐irradiation can be extended for the efficient synthesis of other nanocomposite materials.     

智能车内环境自调节系统（泊车用）的设计与规划

针对目前汽车产业内泊车时的车内环境调节技术的发展滞后,致使很多车主夏季不得不使用凉椅、遮阳挡,冬季面对发动机点火难的尴尬,以及车载空调耗油、噪声大的缺点。利用珀尔帖效应原理,根据实际需求制作规格合适的半导体制冷模块,并利用L298N芯片控制,结合单片机最小系统、数字温度传感器DS18B20、LED显示电路、按键等功能,检测、控制,执行。并通过相关实验,最终实现了系统整体要求也同时贴补了这一领域的研究空白。     

P-type ZnO thin films prepared by in situ oxidation of DC sputtered Zn3N2:Ga

The feasibility of a new fabrication route for N and Ga codoped p-type ZnO thin films on glass substrates, consisting of DC sputtering deposition of Zn3N2:Ga precursors followed by in situ oxidation in high purity oxygen, has been studied. The effects of oxidation temperature on the structural, optical and electrical properties of the samples were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), optical transmittance and Hall effect measurements. The results were compared to a control film without Ga. XRD analyses revealed that the Zn3N2 films entirely transformed into ZnO films after annealing Zn3N2 films in oxygen over 500 ℃ for 2 h. Hall effect measurements confirmed p-type conduction in N and Ga codoped ZnO films with a low resistivity of 19.8 Ω·cm, a high hole concentration of 4.6 × 1018 cm-3 and a Hall mobility of 0.7 cm2/(V·s). These results demonstrate a promising approach to fabricate low resistivity p-type ZnO with high hole concentration.