Passivation effects of deuterium exposure on boron-doped CVD homoepitaxial diamond

The deuterium (hydrogen) passivation effect on acceptors in boron-doped CVD homoepitaxial diamond was studied by electrical (Hall-effect) and secondary ion mass spectroscopy (SIMS) measurements. Deuterium was incorporated into the samples using microwave (MW) deuterium plasma at 673 K for 2–24 h. We observed the progress of acceptor passivation with p-type conduction, which finally resulted in a highly resistive state.     

三峡库区湖北四县水土资源综合开发利用与水土流失防治对策研究

三峡库区湖北宜昌、秭归、兴山、巴东四县幅员面积１１５８９．３平方公里，总人口数１６６．０２万人，三峡水库形成后，淹没土面积７４．４７平方公里，涉及８．９４万人，规划农业生产安置２．８万人。本文以四县土地资源利用现状主和环境容量的分析为基础，进行三峡库区移民安置对水土流失的影响评价，论证综合开发利用水土资源，水土保持与开发性移民相结合，是扩大库区人口环境容量的必由之路，研究制订出移民安置与水土资源的     

Surface electronic structure of detonation nanodiamonds after oxidative treatment

X-ray absorption spectroscopy has been used for comparative study of electronic structure of detonation nanodiamonds (ND) purified using different oxidative treatments. The treatment of detonation soot with a mixture of nitric and sulphuric acids followed by ion exchange and ultrafiltration of hydrosol obtained was found to result in developing of ND surface coverage consisting of oxidized carbon species, which electronic state is close to that of strongly oxidized graphite. The deeper purification of ND was demonstrated to allow cleaning of ND particles from most of the oxidized carbon contaminations.     

刚性棒状全芳香液晶聚酯的合成及性质的研究

以溴和苯基取代的对苯二甲酰氯及2，2′-二甲基联苯-4，4′-二甲酰氯作为单体，分别与甲基、叔丁基、苯基取代的对苯二酚经熔融缩聚反应，合成一类具有刚性棒状结构的全芳香液晶聚酯。聚酯的热性质以TGA、DSC，热台偏光显微镜研究。所有的聚酯均为热致性液晶，它们具有相对较低的转变温度，在普通的有机溶剂中具有较好的溶解性质。     

官厅水库水质趋势分析及对策研究

官厅水库水质污染曾经比较严重，于1997年退出了北京市饮用水水源体系。经过9年的综合治理．官厅水库水质有明显改善。通过采用PWQTrend水质污染趋势模型分析软件．对官厅水库库区近9年来的水质监测资料进行模拟计算，并对水质趋势进行分析研究，发现官厅水库库区有一部分项目明显好转．还有一部分项目有污染加重的趋势，进而提出官厅水库水污染控制及治理的对策和建议。     

微型构造表征技术在八面河油田的应用

通过对八面河油田井网密集区及井网稀疏的欠开发区的微构造研究,探讨了微构造表征技术。首先在储层多层次逐级对比的基础上,建立主力油层对比关系;密集井网条件下,则利用钻井资料编制油层顶底微型构造图;对于欠开发地区,通过人机联作自动追踪成图技术,输出2m等值线间隔构造图,建立微构造模型。以微构造模型为基础进行潜力评价,部署关键井寻找优质储量或进行开发动态调整。应用该项技术在八面河油田滚动发现了角15块等断鼻翼部局部高点,增加石油地质储量488×10~4t。     

三维地质模型在濮城油田的应用

以濮城油田东区沙二下油藏为研究对象，在储层流动单元细分、微构造、沉积微相、测井曲线二次处理、储层非均质研究、储层动态解释等研究基础上，以数据库为支撑，应用三维可视化技术，建立了研究区油藏三维可视化地质模型。其成果应用于油藏的调整井位设计，并且实现了油藏精细描述—油藏精细数值模拟一体化，效果良好。     

常门铺水库溢洪道设计方案比较

在常门铺水库溢洪道改造中，通过不工模型试验，对其数据成果进行分析并进行方案比较，最终采用即经济又合理的方案二，为国家节省投资50.8万元。     

Eu(DMBM)_2(2,2′-bipy)NO_3的合成与荧光光谱

本工作首次合成了Eu(DMBM)_2(2,2′-bipy)NO_3(DMBM=二对甲氧基苯甲酰甲烷,2,2′-bipy-2,2′-联吡啶)。通过元素分析、热谱、电导率、红外和拉曼光谱、质子核磁共振谱对所合成化合物进行了表征。在77K测定了固体配合物的激发光谱和发光光谱。光谱数据说明配合物含有两种Eu(Ⅲ)格位。配合物中三种配体在Eu(Ⅲ)周围的分布情况略有不同,显示出不同的晶体场效应。光谱数据表明,配合物中Eu(Ⅲ)格位属于非中心对称的点群C_1或C_3或C_2。     

Phase equilibria of crude oils using the continuous thermodynamics approach

This paper deals with the application of continuous thermodynamics to light and heavy oil systems using the Peng- Robinson equation of state. The composition of the high molar mass components in a reservoir oil is described by a continuous distribution function of some characterizing quantity, e.g. molar mass or boiling temperature. Numerical Gaussian quadrature methods are used to generate pseudo-components and their mole fractions from distribution data. Several examples are presented for phase equilibria of solvent/crude oil systems. The results showed that semi-infinite distribution functions, such as the Γ function, cannot be applied to all cases, e.g. dew point calculations. The Gauss- Legendre quadrature method coupled with spline fitting worked best for heavy oil systems.