类金刚石薄膜的Raman光谱分析及红外光谱特性

用酒精和氢气的混合气体为工作气体 ,在不同的酒精浓度下 (1 0 % ,1 5% ,2 0 % )下利用微波等离子体化学气相沉积法在较低温度下 (450～ 50 0℃ )以单晶硅为衬底制备出类金刚石薄膜样品。 Raman光谱分析了酒精浓度对薄膜中金刚石成份的含量的影响。红外光谱分析表明薄膜的红外光透过率与薄膜的表面形貌、薄膜结构有关。酒精浓度为 1 0 %时得到的金刚石薄膜的红外光透过率最高 ,达到 62～ 72 % ,同时透过率曲线因薄膜干涉而引起的振荡也最为显著。     

Relationship between microscopic and macroscopic structures of organic thin films for SHG

The experiments described in this paper were undertaken in order to obtain information about the relationship between the structure and non-linear optical properties (second-harmonic generation) of organic thin films. For this purpose, two closely related dyes, diones and tetrones, were compared, both of which are shown to have large hyperpolarisabilities. Their microscopic properties are investigated by conformational analysis and electron diffraction. It could be shown that detailed knowledge about the structure and the adjacent neighbour packing can be obtained from conformational analysis and electron diffraction in order to understand the non-linear optical properties of the two dyes.     

组合式熔凝石英微透镜阵列-线列Yba_2Cu_3O_(7-δ)高温超导薄膜红外探测器的研究

采用准分子激光扫描消融法淀积YB32C23O7-δ高温超导薄膜,利用常规光刻工艺制备线列高温超导薄膜器件,采用离子束刻蚀制备与高温超导薄膜器件匹配的熔凝石英微透镜阵列,测试了微透镜／高温超导薄膜器件所构成的混合结构在1～5μm红外波段的几项重要的光响应特性．     

新型聚多巴胺纳米颗粒光热蒸发性能评价

聚多巴胺具有与黑色素相似的吸光性能,是一种被广泛关注的高分子近红外吸收材料,在光热转化方面有良好前景。但由于其本身聚合机理多样,内部结构复杂,目前对聚多巴胺功能性设计的研究较少。本文通过设计Fe³⁺和硅烷偶联剂与多巴胺反应,提高了聚多巴胺的吸光特性和亲水性;通过X射线光电子能谱(XPS)、傅里叶变换红外光谱(FTIR)等表征证明,成功合成了高吸光度亲水聚多巴胺纳米颗粒,吸光度达到90%。同时将合成的纳米颗粒真空抽滤,堆叠构建亲水输运通道。实验表明：在太阳光蒸发环境,一个太阳光强下,使用本文设计的光热膜进行纯水蒸发实验,纯水蒸发速率可以达到1.1 kg/(m²·h),光热转化效率为80%,比普通聚多巴胺提高15%,证明该材料有很好的光热转化性能,在海水淡化领域有着良好的应用前景。     

高导电性ZAO陶瓷靶材及薄膜的制备

用热等静压法烧结制备了高导电性ZAO(铝掺杂氧化锌)陶瓷靶材,并用直流磁控溅射法制备出ZAO透明导电薄膜。靶材的致密度达98.7%,电阻率为2.2?03·cm;制得薄膜的最低电阻率为9.3?04·cm,可见光平均透射率大于85%。浅析了靶材的组织结构及靶材的电学、力学性能和薄膜制备的主要实验参数对其光、电性能的影响。     

喷射成形Al-Zn-Mg-Cu系超高强度铝合金热处理制度的实验研究

研究了喷射成形Al-Zn-Mg-Cu系超高强度铝合金的沉积态和挤压态的组织,对挤压态合金进行了固溶处理和时效处理,得到了时效硬度曲线,并进行了力学性能测试.结果显示:沉积态合金孔隙较多;挤压态合金内存在大量的颗粒,经能谱分析为富铜相;固溶温度达到490℃时,晶界出现熔化现象.时效硬度曲线表明:采用120℃时效,在15~25h之间达到硬度峰值;采用135℃时效,达到硬度峰值的时间与合金的成分有关,随着Zn含量的增加,达到硬度峰值的时间变短,而抗拉强度基本稳定在700MPa左右.     

等离子体处理对氧化铟锡(ITO)润湿性及性能参数的影响

在预处理室中对ITO薄膜进行等离子体处理,研究分别在氧气、氮气、氩气及空气四种工作气体下,等离子体处理压强和处理时间对薄膜的润湿性及性能参数的影响。接触角测试仪表征表明,等离子体处理时间越长、处理压强越大,静态H₂O接触角越小,其润湿性越高。分光光度计测试结果表明,经等离子体处理,ITO薄膜透过率较未处理均有所下降。四种工作气体下,等离子体处理压强越大对透过率的影响越小,但随着处理时间的增长影响会增大;相较其他工作气体,氧气等离子体处理整体变化最小。四点探针表征表明,处理后的ITO薄膜方块电阻无明显变化,这是由于等离子体处理只对ITO薄膜表面进行改性,没有改变内部性质。利用霍尔效应测量载流子浓度,没有发现明显变化,与方块电阻不变结论一致。     

MoS_2-LaF_3共溅膜潮湿贮存后的摩擦学性能

本文考察了 MoS_2-LaF_3共溅膜在潮湿空气中贮存后结构及摩擦学性能的变化。结果表明,少量稀土化合物使共溅膜组织更加致密,防止了底材腐蚀,稳定了薄膜结构,MoS_2-LaF_3共溅膜经潮湿贮存后仍具有长的耐磨寿命和稳定的摩擦系数。     

Flexible electronics: Prediction of substrate deformation during different steps of the lithography process

A numerical model was developed to simulate the micro-deformations of a polymeric substrate due to lithographic processing of different layers of a transistor-like structure. The results of the model were validated with the results from experiments. The model, a mechanical-thermal-hygroscopic model, takes into account the dimensional effects of temperature, moisture and stresses. It also includes the temperature dependent visco-elastic behaviour of the polymer substrate. The model can be used to predict overlay accuracies between different functional layers introduced by the lithographic process. It can also be used to understand the underlying processes such that it provides a tool to improve the overlay accuracy during actual processing.     

Age differences in psychosocial predictors of positive and negative affect: A longitudinal investigation of young, midlife, and older adults: Correction to Windsor and Anstey (2010).

Reports an error in Age differences in psychosocial predictors of positive and negative affect: A longitudinal investigation of young, midlife, and older adults by Tim D. Windsor and Kaarin J. Anstey (Psychology and Aging, 2010[Sep], Vol 25[3], 641-652). Contains an error in Figure 3, on page 649. The correction discusses where to find the correct data. (The following abstract of the original article appeared in record 2010-18944-009.) Research has consistently shown that despite aging-related losses, older adults have high levels of emotional well-being relative to those in young and midlife adults. We aimed to contribute to knowledge around the factors that predict emotional well-being over the life course by examining age group differences in associations of positive and negative social exchanges and mastery beliefs with positive and negative affect in a sample of 7,472 young, midlife, and older adults assessed on 2 measurement occasions, 4 years apart. Results from structural equation models indicated lower levels of negative affect with advancing age. Mastery was consistently related to higher well-being, with the strongest associations evident for young adults. Older adults reported the most frequent positive and least frequent negative social exchanges; however, associations of social relations with affect tended to be stronger among young and midlife adults relative to older adults. Results are discussed in the context of life course perspectives on goal orientations and self-regulatory processes. (PsycINFO Database Record (c) 2011 APA, all rights reserved)