电子辐射对渗透和非渗透性客体上指纹信息记录的影响

由于恐怖分子利用邮政系统投寄携带炭疽病毒的邮件,传播病毒,已引起美国政府在邮政系统,选择地利用电子辐射杀死病毒。然而,这种病毒袭击并没有得到有效控制,却使信封内的邮件由于高温辐射,受到损坏。有报道说,由于电子辐射使纸张、珠宝、信用卡、软盘和光盘及其它电子材料受到损害。某些研究已在法庭科学中得到验证。本文介绍辐射过程在渗透和非渗透性客体上,对化学试剂、生物酶记录指纹信息的影响。     

Rheological properties and foam processibility of precured EPDM

EPDM foam was prepared by dynamically vulcanizing EPDM compound in a HAAKE rheometer firstly, then mixing the partially precured EPDM compound with a blowing agent and a sulfur vulcanizing system on a two roll mill. The compound was extruded through a cold feed extruder, and the extrudate was foamed in a circulating hot air oven. EPDM compound was vulcanized partly in the HAAKE rheometer, the final torque increases with increasing sulfur content. Rheological measurement shows the dynamic storage modulus, the loss modulus, and the complex viscosity of precured EPDM compound increase with increasing sulfur content. Then the partially precured EPDM compound was compounded with a blowing agent and a sulfur vulcanizing systems, Rheometric measurement shows that the rate of vulcanization of partially precured EPDM compound is not affected by the precure. The blowing results show that the foam processibility could be improved and the expansion ratio increases in the same processing condition for optimum partially precured EPDM compound, which indicates the optimum crosslink density for EPDM could enhance the efficiency of blowing agent AC. SEM shows that the foam articles have a closed‐cell structure with few open cells, and the large cells inlay among the small cells. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3387–3394, 2006     

新型聚氨酯防水涂料性能的研究

本以聚醚多元醇和过量多异氰酸酯合成聚氨酯预聚体，以水为固化剂制备一种新型聚氨酯防水涂料，讨论了两种聚醚多元醇(N220／N3050)质量比、NCO质量分数、固化剂含量、甲乙两组分质量比对聚氨酯防水涂料力学性能的影响。     

JX系列高温脱氯剂的开发

通过脱氯剂穿透氯容随实验条件变化规律的研究，讨论高温脱氯剂的脱氯反应模型。基于对脱氯机理的认识，通过对活性组份筛选和制备方法研究，成功研制出以JX-5A脱氯剂为代表的JX系列高温脱氯剂，穿透氯容达到50％以上。     

Effects of perfluoroether concentration and curing protocol on morphology and mechanical properties of toughened TGDDM/MNA resin systems

Previous published work has shown that hydroxyl terminated perfluoroether oligomers can be suitably modified and functionalised to make them miscible with epoxy resins in the uncured state. The reaction conditions can adjusted to induce phase separation either through spinodal decomposition to produce an IPN type morphology, or by nucleation and growth if a dispersed-particle microstructure is required.In the present work we examine the relative toughening enhancement efficiency of the two possible heterophase morphologies. Both systems show a sigmoidal increase in fracture toughness, with increasing concentration of the perfluoroether modifier. However, this takes place at much lower modifier concentrations for the systems with a particulate morphology (about 3.5% w/w) than for IPN systems (about 7.5% w/w). The maximum fracture toughness achievable for the two systems, on the other hand, is very similar and coincides with the concentration at which co-continuous phases are formed.These differences in morphology, however, are not reflected in the variation of modulus and compressive yield strength with increasing concentration of perfluoroether modifier, in so far as both systems exhibit a gradual and small reduction in property with increasing concentration. Furthermore, the dynamic mechanical spectra of the two systems are very different, but the changes resulting from increasing the concentration of toughening agent are relatively small in either case.Nanoindentation tests indicate that it is the local plasticity, brought about by the presence of the softer perfluoroether phase, which is responsible for the enhancement of fracture toughness. This is corroborated by AFM examinations, which reveal local plastic deformations in the regions surrounding the softer particles.     

基于知识情感等级BDI主体的决策行为模型研究

为了将知识、信念、愿望和意图以及害怕、焦虑和自信对决策行为的影响的强烈程度进行形式化,把无穷值的卢卡斯维茨逻辑的真值取值范围从[0,1]扩展到[-1,1]。知识情感等级BDI主体的决策行为通过添加了具体条件的不同背景的不同测度来决定;知识情感等级BDI主体模型清晰地表示了主体的知识状态、心智状态和情感状态的不确定性;此模型可以轻易地向其他类型的主体进行推广。在给出了知识情感等级BDI模型的语言、语义以及此模型的不同背景之间的相互关系之后,对知识情感等级BDI主体的军事决策行为进行了实例分析。此研究旨在为分布式人工智能和军事仿真提供形式支持。     

选择性螯合滴定法测定电镀液中的锡铜铅

提出了测定电镀液中锡铜铅的一个简易快速螯合滴定法.用EDTA螯合锡(Ⅳ)、铜(Ⅱ)、铅(Ⅱ)和其它金属离子,然后分别用三羟基苯甲酸、巯基丁二酸和氨荒丙酸解蔽.释放出的EDTA,用锌标准溶液反滴定(XO-CPB为混合指示剂).终点变化相当敏锐.研究了测定锡、铜、铅时一般共存离子的干扰.此法已被成功地用于测定锡-铜-铅合金电镀液和镀层锡铜铅合金中的锡、铜和铅.     

Natural fiber composites of high‐temperature thermoplastic polymers: Effects of coupling agents

Our earlier paper (Jana, S.C.; Prieto, A. J Appl Polym Sci 2002, 86, 2159) on the development of natural fiber composites of high‐performance thermoplastic polymers described a new methodology for the manufacturing of composite materials of a high‐temperature thermoplastic polymer, poly(phenylene ether) (PPE) and wood flour, a cellulosic natural filler. A thermosetting epoxy, used as a reactive solvent, reduced the processing temperature of PPE/epoxy blends to well below the decomposition temperature of natural fillers. In addition, the epoxy component, upon polymerization, formed coating layers around the filler particles to provide resistance against moisture diffusion and attacks by acids and alkali. This article describes the results of an investigation on two outstanding issues: (1) the influence of cellulosic wood particles and coupling agents on the speed of epoxy curing and reaction‐induced phase separation and (2) the effects of coupling agents on the morphology of crosslinked epoxy at the surfaces of natural fillers and mechanical properties of the composites. It was found that wood particles expedited epoxy curing in the composites; the extent of epoxy curing, however, was reduced in the presence of coupling agents. Also, the coupling agents promoted complete coverage of wood flour particles by polymerized epoxy, although the mechanical properties deteriorated over systems without coupling agents. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2168–2173, 2002     

Fundamental foaming mechanisms governing the volume expansion of extruded polypropylene foams

This article describes the fundamental foaming mechanisms that governed the volume expansion behavior of extruded polypropylene (PP) foams. A careful analysis of extended experimental results indicated that the final volume expansion ratio of the extruded PP foams blown with butane was governed by either the loss of the blowing agent or the crystallization of the polymer matrix. A charge coupling device (CCD) camera was installed at the die exit to carefully monitor the shape of the extruded PP foams. The CCD images were analyzed to illustrate both mechanisms, gas loss and crystallization, during foaming at various temperatures, and the maximum expansion ratio was achieved when the governing mechanism was changed from one to the other. In general, the gas loss mode was dominant at high temperatures and the crystallization mode was dominant at low temperatures. When the gas loss mode was dominant, the volume expansion ratio increased with decreasing temperature because of the reduced amount of gas lost. By contrast, when the crystallization mode was dominant, the expansion ratio increased with increasing temperature because of the delayed solidification of the polymer. The processing window variation with the butane concentration, the change in the temperature ranges for the two governing modes, and the sensitivity of melt temperature variations to the volume expansion ratio are discussed in detail on the basis of the obtained experimental results for both branched and linear PP materials. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2661–2668, 2004     

形核剂成分对高碳钢凝固过程的影响

高碳钢连铸坯存在的最大质量问题是中心缩松、中心偏析严重.解决这一问题的关键是扩大铸坯等轴晶区比例,细化晶粒.本文以Fe-C合金作为形核剂,研究了形核剂含碳量对高碳钢凝固过程的影响机理.研究结果表明,向钢液中加入形核剂可有效地扩大等轴晶区.对高碳钢,中碳铁合金形核剂既可扩大等轴晶区,又可细化晶粒;而低碳形核剂可以扩大等轴晶区,但细化晶粒效果差.为有效地发挥形核剂的作用,对不同钢种要合理地选择形核剂含碳量.