砷酸根及铬酸根在低聚合羟基铁-蒙脱石复合体表面的竞争吸附

在模拟氧化及酸性土壤条件下,用制备的低聚合羟基铁-蒙脱石复合体进行了砷酸根、铬酸根离子的竞争吸附实验,研究了砷酸根离子和铬酸根离子不同用量及不同添加顺序对竞争吸附的影响,并与蒙脱石和含水氧化铁进行了对比。结果表明,低聚合羟基铁-蒙脱石复合体对砷酸根及铬酸根离子有不同的吸附能力,但在实验条件下砷酸根及铬酸根离子在低聚合羟基铁-蒙脱石复合体表面不发生竞争吸附。砷酸根和铬酸根的吸附顺序对其吸附量有一定的影响。竞争吸附实验的砷酸根、铬酸根吸附量均高于对其单阴离子的吸附量,此现象在复合体表面最为明显,说明复合体具有独特的阴离子吸附性能。

     

Application of strength reduction method to dynamic anti-sliding stability analysis of high gravity dam with complex dam foundation

Considering that there are some limitations in analyzing the anti-sliding seismic stability of dam-foundation systems with the traditional pseudo-static method and response spectrum method,the dynamic strength reduction method was used to study the deep anti-sliding stability of a high gravity dam with a complex dam foundation in response to strong earthquake-induced ground action.Based on static anti-sliding stability analysis of the dam foundation undertaken by decreasing the shear strength parameters of ...     

Facile solvothermal synthesis and photoconductivity of one-dimensional organic Cd(Ⅱ)-Schiff-base nanoribbons

One-dimensional (1D) organic nanoribbons built on N-p-nitrophenylsalicylaldimine cadmium complex were synthesized via a facile solvothermal route. Scanning electron microscope images revealed that the as-synthesized products were ribbon like with widths of 500 nm,thicknesses of about 50nm, and lengthes up to several hundred micrometers. Fourier transform infrared spectrum was employed to characterize the structure. The conductivity of a bundle of nanoribbons was also measured,which showed that Schiff base cadmium nanoribbons had good photoconductive property. This work might enrich organic photoconductive materials and be applicable in nano photoswitch devices in the future.     

Nuclear magnetic resonance analysis of protein–DNA interactions

Recent methodological and instrumental advances in solution-state nuclear magnetic resonance have opened up the way to investigating challenging problems in structural biology such as large macromolecular complexes. This review focuses on the experimental strategies currently employed to solve structures of protein–DNA complexes and to analyse their dynamics. It highlights how these approaches can help in understanding detailed molecular mechanisms of target recognition.     

Rare earth organic complexes as down-shifters to improve Si-based solar cell efficiency

This work reports on the optical and electrical characterization of crystalline silicon based solar modules encapsulated with ethylene-vinyl-acetate layers (that is the encapsulating matrix used nowadays by the photovoltaic industry) doped with a single europium complex whose sensitized region is broadened due to the presence of a co-ligand. Such europium doped EVA layers are able to realize down-shifting of photons with wavelength lower than 460 nm without introducing modifications of the industrial process leading to the fabrication of the photovoltaic modules. This effect has been proven under Air Mass 1.5 conditions (simulating terrestrial applications), where a 2.9% relative increase of the total power delivered by the encapsulated modules has been observed, allowing a reduction in the watt-peak price.     

New optical material europium EDTA complex in polyvinyl pyrrolidone films with fluorescence enhanced by silver plasmons

In our search for efficient Luminescent Solar Concentrators (LSC) we have prepared polyvinyl pyrrolidone (PVP) films incorporated by ethylenediamine tetraacetic acid (EDTA) complex of europium and co-doped with silver nanoparticles (NPs). Steady state fluorescence was studied under weak and strong excitation. Dynamical study was performed by second harmonic of Nd laser. Under weak excitation the fluorescence of europium co-doped with silver plasmons increased by a factor of three and excited by continuous laser by a factor of 50. The lifetimes of films doped by the complex were 755 μs and co-doped with silver nanoparticles 946 μs. This is the first finding that the photon density accumulates the number of plasmons interacting with electronic states of europium increasing its transition probability resulting in the strong intensification of fluorescence. In dynamical measurements of lifetimes a single pulse does not provide enough energy to create such number of plasmons.     

Choice of a pertinent color space for color texture characterization using parametric spectral analysis

This article presents a comparison of different color spaces including RGB, IHLS and L?a*b* for color texture characterization. This comparison is based on the fusion of the independent spatial structure and color feature cues. In IHLS and L*a*b*, two channel complex color images are created from the luminance and the chrominance values. For such images, two dimensional complex multichannel linear prediction models are used to perform parametric power spectrum estimation and the structure feature cues are computed from this estimated power spectrum. Quantitative comparison of auto spectra of luminance and combined chrominance channels for different color spaces is done. This comparison is based on the degree of decorrelation between luminance and chrominance information provided by different color space transformations. Three dimensional histograms are used as color feature cues. Then, to classify color textures, Kullback-Leibler divergence based symmetric distance measures are calculated for pure color, luminance structure and chrominance structure feature cues. Individual as well as combined effect of information from all feature cues on classification results is then compared for different color spaces and different color texture data sets. The proposed color texture classification method performs better than the state of the art methods in certain cases. The L*a*b* color space gives us a better characterization of the chrominance spatial structure as well as the overall spatial structure for all of the chosen data sets. Experimental results on pixel classification of color textures are also presented and discussed.     

High frequency complex permeability of flake-shaped Fe_(74)Cr_2Mo_2Sn_2P_(10)Si_4B_4C_2 particle composite material

A composite consisting of flake-shaped Fe74Cr2Mo2Sn2P10Si4B4C2 particles was prepared.The flake-shaped particles included in the composite were prepared by planetary ball milling.The complex permeability of the composite material was measured at frequency range from 10 MHz to 8.5 GHz.The permeability of the composite containing flake-shaped particles was much higher than that of the spherical particles.The permeability of particles was improved by means of heat-treatment.In contrast to the random-spatial-di...     

Molecular recognition of DNA–protein complexes: A straightforward method combining scanning force and fluorescence microscopy

Combining scanning force and fluorescent microscopy allows simultaneous identification of labeled biomolecules and analysis of their nanometer level architectural arrangement. Fluorescent polystyrene nano-spheres were used as reliable objects for alignment of optical and topographic images. This allowed the precise localization of different fluorescence particles within complex molecular assemblies whose structure was mapped in nanometer detail topography. Our experiments reveal the versatility of this method for analysis of proteins and protein–DNA complexes.     

夹芯复合墙板在水平荷载作用下变形的有限元分析

利用有限元程序对夹芯复合墙板在水平荷载作用下的变形进行分析,探讨墙板结构层厚度、水平桁架、纵向桁架、钢筋网作为主要参数变化时对墙板变形的影响。分析得出:影响墙板刚度的主要因素是结构层厚度,其次是水平桁架,其他因素影响较小。该结论为新型复合墙板的研发提供了理论依据。