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21.
The compositions (1 −x)Ag2SO4−(x)BaSO4, wherex=0·01 to 0·6, were prepared by slow cooling of the melt. The extent of the solid solubility of Ba2+ in Ag2SO4 was determined by X-ray powder diffraction and scanning electron microscopy. The bulk conductivity of each sample was obtained
using a detailed impedance analysis. The partial substitution of Ba2+ results in the enhancement of conductivity in compliance with the classical aliovalent doping theory. A simplistic model
based on lattice distortion (expansion) due to partial substitution of Ag+ by the bigger Ba2+ has been considered to explain enhanced conductivity. Beyond solid-solubility limit (5·27 mole%) the BaSO4-dispersed Ag2SO4 conductivity follows the usual trend seen in binary systems. An increase in conductivity in this case is discussed in the
light of interfacial reactions and surface defect chemistry. The maximum conductivity in 20 mole% BaSO4 dispersed Ag2SO4 is due to percolation threshold. 相似文献
22.
Allen Daniel N.; Strauss Gregory P.; Kemtes Karen A.; Goldstein Gerald 《Canadian Metallurgical Quarterly》2007,21(6):713
Hemispheric involvement in reasoning abilities has been debated for some time, and it remains unclear whether the right hemisphere's involvement in problem solving is modality specific or dependent on the type of spatial reasoning required. In the current study, 2 types of nonverbal reasoning abilities were examined, spatial reasoning and proportional reasoning, in 109 patients with cerebrovascular disease that was confined to either the right or the left hemisphere or was diffuse in nature. Results indicated that no lateralizing effects were present based on type of spatial reasoning. Findings are consistent with the suggestion that higher order cognitive processes involved in nonverbal abstraction and problem solving are not strongly lateralized to the right hemisphere but rather are more generally distributed throughout the cortex. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
23.
包行方 《石油化工设备技术》1996,17(1):5-8
充分利用了带主焊缝的役后试板,在国内首次开展回火脆化、氢介质下断裂韧性与疲劳扩展的研究,结果表明,加氢反应器焊缝有明显的脆化表现。同时,核查了反应器开停车升温速度和降温速度规定,以及确定了裂纹允许尺寸的参考数据,为今后安全运行提供了充分的依据。 相似文献
24.
This paper focuses on the microscopic damage and progressive failure of a composite reinforced by plain-weave glass cloth under tensile fatigue loading. The fatigue process was divided into three stages like that of multi-directional laminates. It was found that the internal damage at each stage (matrix cracks, debonds in the weft, successive debonds in the warp and ‘metadelaminations’ between warps and wefts) occurred near the cross-over point of the fabric. The modulus decay mechanism was explained by considering the progression of this internal damage. From the end of the first stage to the beginning of the middle stage, a characteristic damage state (CDS) (called a ‘meta-CDS’) was observed. It was found that woven composites have a unit area of damage accumulation (called a ‘unit cell’) and the damage of each unit cell and its distribution control the total fatigue damage of the material. 相似文献
25.
提出底敞口充气浮箱的结构和概念。经模型模拟试验研究分析,经典浮力定律可用于这种浮箱的浮力计算;其动充气状况还具有一定的允许伤损面积。它的研究将为水陆两用车辆增大浮力,缩小外形,提高水上自下而上能力和潜驶潜伏提供具有诱惑力的工程应用前景。 相似文献
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27.
高含酸性气碳酸盐岩气藏流体敏感性实验研究 总被引:2,自引:0,他引:2
对川东北雷口坡组、嘉陵江组、飞仙关组、长兴组高含H,S及032的碳酸盐岩储层流体敏感性进行了实验研究,结果表明岩样速敏损害弱~强,水敏和盐敏损害中偏弱~极强,碱敏损害严重。岩石学分析揭示,川东北高含酸性气碳酸盐岩储层发育伊利石、微晶石英、白云石、方解石、硫化钙等潜在损害物质。钻井完井液侵入会破坏储层各物质间的原始动态平衡,诱发储层损害。主要损害机理为:①储层流体pH增加引起黏土矿物以及微晶石英失稳;②碱液与微晶石英、长石、白云石反应生成硅酸盐、高岭石、水镁石等新矿相;③流体矿化度改变可降低伊利石微粒间的连接力;④硫化钙水解产生OH^-,过量的OH-与Ca^2+结合形成氢氧化钙沉淀;⑤储层含水饱和度和流体离子浓度改变,致使焦沥青脱附并在储层深部沉积;⑥硬石膏水化膨胀、分散运移。针对该气藏损害机理,可采用屏蔽暂堵技术以形成优质滤饼,有效降低储层流体敏感性损害。图5表2参10。 相似文献
28.
29.
中山包水电站钢岔管在天生桥二级水电站 6号压力钢管下平段分岔 ,岔管HD值达 15 40m2 ,结构体形复杂 ,采用NK HITEN780A Z35和NK HITEN6 90B高强度钢材制造安装 ,在国内水电工程中实际应用较少。文章着重介绍岔管的布置、结构分析和焊缝的无损检验要求。中山包水电站的正常发电运行 ,为 80kg/mm2 级高强钢在国内水电行业的应用提供了第 3个成功实例 相似文献
30.
The present paper will outline the main aspects of the design and construction of cooling towers in Germany in the last decade. As part of electricity generating power plants, cooling towers play a significant role for the availability of reliable energy supplies, in a manner compatible with environmental requirements. They definitely belong to the largest and thinnest concrete structures at present. Because of the combined action of wind, thermal and moisture effects, special care has to be taken with regard to fatigue, cracking and corrosion to ensure an adequate level of safety and durability. Such a design strategy has been employed for the world’s tallest cooling tower at the Niederaussem power plant in Germany, with an overall height of 200 m and thickness values of 22–24 cm. Special considerations included the realistic non-axisymmetric distribution of soil characteristics, wind action due to interference effects (as determined by wind-tunnel tests), optimisation of the shell shape to improve structural and dynamic behaviour, injection of the cleaned flue-gas into the cooling tower, and the use of high-performance concrete (85 MPa) to improve shell resistance against acid attack by the cleaned flue-gas. The paper will present some results of an actual research project on this problem, which was conducted at the University of Wuppertal, to explore the use of high-performance concrete on design, stability and durability of cooling tower shells. 相似文献