The Structure of the Irreversibly Bound Adhesion Promoter-Substrate Interfacial Layer of γ-Aminopropylsilanetriol on Crystalline Si, as Measured by XPS and FTIR

The irreversibly bound interfacial layer deposited by the γ-aminopropysilanetriol adhesion promoter onto a crystalline silicon substrate, which remains even after profuse washing, was found by XPS to have resulted from the fragmentation and rearrangement of the original γ-aminopropylsilanetriol molecule. A mechanism is proposed, involving the homolytic scission of the terminal N-C bond. One of the subsequent reactions is believed to involve hydrogen loss by abstraction and the formation of a terminal vinyl group, which bonds to the substrate. Support for this mechanism is found in IR spectroscopy of this layer.     

Boundary layer model for char combustion and gasification

A non-steady boundary layer model is developed for numerical simulation of combustion and gasification of a single shrinking char particle. The model considers mass and energy conservation coupled with heterogeneous char reactions producing CO and homogeneous oxidation of CO to CO₂ in the boundary layer surrounding the char particle. Mass conservation includes accumulation, molecular diffusion, Stefan flow and generation by chemical reaction. Energy conservation includes radiation transfer at the particle surface and heat accumulation within the particle. Simulation results predict experimentally measured conversion and temperature profiles of a burning Spherocarb particle in a laminar flow reactor. Effects of bulk oxygen concentration and particle size on the combustion process are addressed. Predicted particle temperature is significantly affected by boundary layer combustion of CO to CO₂. With increasing particle size, char gasification to char combustion ratio increases, resulting in decreasing particle temperature and increasing peak boundary layer temperature.     

K_2O－CaO－Al_2O_3－SiO_2系统自释釉瓷化学组成的研究

本文从酸度系数着手，证实了Ｋ２Ｏ－ＣａＯ－Ａｌ４Ｏ久－ＳｉＯ２系统中存在自释釉组成，限定了其组成范围，０．６７％＜Ｋ２Ｏ＜１．２８％，１０．６４％＜ＣａＯ＜１３．６２％，１１．５３％＜Ａｌ４Ｏ３＜１５．３２％，７２．７３％＜ＳｉＯ２＜７４．０４％，并讨论了自释釉瓷的性能。     

MATHEMATICAL MODELING OF THROUGH-HOLE-PLATING IN ELECTROCHEMICAL MICROFABRICATION II. AXISYMMETRIC TWO-DIMENSIONAL CONVECTIVE MASS TRANSFER

Axisymmetrical, two dimensional mass transfer in a tube and a through-hole was studied. The elliptic convective-diffusion equation was solved numerically by taking into account both the axial and radial diffusion in the entrance region of an infinite tube. The whole mass-transfer region in a tube of finite length was also studied by dividing the domain into several regions according to different mass-transfer mechanisms. A similar analysis is then conducted for a through-hole geometry by assuming a modified Hagen-Poiseuille fluid pattern. Results show that mass-transfer rate in a through-hole is larger than that in a tube by approximately 10%. This is due primarily to faster fluid flow within the concentration boundary layer in a through-hole.     

关于控制氯代烃的政策选择

本文分析了氯代烃的生产所引起的环境问题,并提出了减少氯代烃环境影响的政策选择的基本原则。     

深基坑工程安全评价的尖点突变模型

为评价深基坑工程失稳的突变特征,采用突变理论建立了深基坑工程尖点突变安全评价模型.根据工程安全监控理论,引入突变理论,以基坑水平变形为例,考虑深基坑土体的流变特性,建立了基于时效影响因子的深基坑工程尖点突变安全评价模型.实例分析表明,尖点突变安全评价模型克服了采用常规设置监控值评价时参数选择困难,并能反映基坑失稳突变性的特点,可以量化评价基坑安全程度,正确评价安全状态,具有适应性强、精度高的优点.     

Zonal disintegration phenomenon in enclosing rock mass surrounding deep tunnels -- Elasto-plastic analysis of stress field of enclosing rock mass

The zonal disintegration phenomenon (ZDP) is a typical phenomenon in deep block rock masses. In order to investigate the mechanism of ZDP, an improved non-linear Hock-Brown strength criterion and a bi-linear constitutive model of rock mass were used to analyze the elasto-plastic stress field of the enclosing rock mass around a deep round tunnel. The radius of the plastic region and stress of the enclosing rock mass were obtained by introducing dimensionless parameters of radial distance. The results show that tunneling in deep rock mass causes a maximum stress zone to appear in the vicinity of the boundary of the elastic and the plas-tic zone in the surrounding rock mass. Under the compression of a large tangential force and a small radial force, the rock mass in the maximum stress zone was in an approximate uniaxial loading state, which could lead to a split failure in the rock mass.     

朴素贝叶斯与全贝叶斯在DFI的应用比较研究

P2P应用软件检测技术主要是深度包检测法和深度流量检测法.深度包检测法不能检测出加密的和未知的对等网络流应用,深度流量检测方法可以克服深度包检测法这个缺点.将模糊识别领域里比较成熟的贝叶斯分类技术应用到对等网络深度流检测中.结合实际项目,对贝叶斯的两个分类器-朴素贝叶斯和全贝叶斯的算法、训练结果、运行结果进行研究,实验研究表明朴素贝叶斯和全贝叶斯分类器能够快速准确地找到P2P流应用,朴素贝叶斯分类器准确度占据优势,全贝叶斯运行时间占据优势.     

壁湍流周期性吹吸减阻的实验研究

为了研究局部周期性吹吸小扰动对湍流边界层的影响和湍流相干结构减阻控制机理,用实验方法研究了局部周期性吹吸小扰动与湍流边界层的相互作用.采用热线测速技术精细测量了施加吹扰动前后平板湍流边界层不同法向位置的流向、法向和展向速度分量的时间序列信号;通过测量扰动源下游近壁区域平均速度剖面的变化,发现在扰动下游一定空间范围内,粘性底层增厚和壁面减阻;通过对湍流度变化的分析,发现扰动影响猝发的发生;此外通过对展向平均涡量变化的分析发现,在扰动下游形成了2个定常的、强度相似的、大尺度的展向涡,它们起到流体滚动轴承的作用,减小了壁面摩擦阻力.     

坯料外形对镁合金矩形盒拉深成形的影响

用商业有限元软件模拟了在同一套模具和成形条件下不同毛坯外形的镁合金矩形盒拉深成形过程．依据数值模拟结果，分析了不同坯料外形对镁合金矩形盒拉深成形的影响。结果表明：使用矩形圆角坯料比其他坯料的成形性能好。