含氮、磷有机配体对(CdSe)_2量子点结构和电子性质的影响

使用密度泛函理论方法研究了量子点(CdSe)2与配体L(L=PH3、PH2Me、PHMe2、PMe3、NH3、NH2Me、NHMe2、NMe3)之间的相互作用及其产物的结构和性质。配体中的P或N原子与Cd原子上分别形成较强的Cd—P和Cd—N配位键,从而影响(CdSe)2的结构和电子性质。配体作用下,(CdSe)2的几何结构、电荷分布、轨道能级、吸收光谱等均发生变化,但2类配体的影响,尤其是甲基数目的影响,存在较大差异。     

嵌入式消毒柜门内衬板拉深模具设计

通过对嵌入式消毒柜门内衬板工艺分析，确定其模具加工方案，同时对试模过程中存在的问题作进一步的剖析。     

冰箱门面板冲压工艺分析及模具设计

分析冰箱门面板的冲压工艺,介绍模具设计中应注意的问题及滚压式结构的特点     

Defect structure and chemical diffusion in nickel sulfide β-Ni3S2

The chemical composition, defect structure, and diffusion in nickel sulfide -Ni₃S₂ have been investigated in H₂S-H₂ mixtures containing between 1 and 65% H₂S between 560 and 700°C. Gravimetric, density, and X-ray studies were carried out. In the thermodynamically stable compound the ratio of Ni/S varied between 1.3 and 1.75. The X-ray examination showed a step change in the lattice parameter at the Ni/S ratio 1.4. A linear dependence of the density values (between 5.5 and 6.2 g/cm³) on the composition was observed. On the basis of the chemical composition and density measurements the number of nickel and sulfur atoms in 1 cm³ were determined. It has been shown that the Ni₃S₂ phase is defected in both anion and cation sublattices and that its chemical formula may be described as follows: Ni_3±yS_2x, where y 2x. It has been found that in the mixture containing 10% H₂S the process of defect formation is determined by their diffusion in the sulfide. The temperature dependence of the diffusion coefficient is described by the equation D = 13.15 exp(-30,000/RT) cm²/sec. No dependence of D on the sulfur partial pressure was observed, but this may be due to the relatively large uncertainties in the measurement of the diffusion coefficients.     

坯料外形对镁合金矩形盒拉深成形的影响

用商业有限元软件模拟了在同一套模具和成形条件下不同毛坯外形的镁合金矩形盒拉深成形过程．依据数值模拟结果，分析了不同坯料外形对镁合金矩形盒拉深成形的影响。结果表明：使用矩形圆角坯料比其他坯料的成形性能好。     

ANALYSIS OF DISSIPATIVE STRUCTURE IN MATERIAL COMMINUTION

ＡＮＡＬＹＳＩＳＯＦＤＩＳＳＩＰＡＴＩＶＥＳＴＲＵＣＴＵＲＥＩＮＭＡＴＥＲＩＡＬ　ＣＯＭＭＩＮＵＴＩＯＮＺｈａｎｇ；Ｚｈｉｔｉｅ（ＤｅｐａｒｔｍｅｎｔｏｆＭｅｃｈａｎｉｃａｌＥｎｇｉｎｅｅｒｉｎｇ，ＣｅｎｔｒａｌＳｏｕｔｈＵｎｉｖｅｒｓｉｔｙｏｆＴｅ...     

Titanium in the rapidly cooled hypereutectic gray iron

The effect of titanium on the structure and properties of a rapidly cooled hypereutectic cast gray iron has been studied on the example of permanent mold (PM) casting. A microstructure study showed that titanium is a relatively strong element in controlling solidification structure by increasing undercooling and thus promoting type D graphite. The effectiveness of titanium additions depends on the base iron carbon equivalent (CE) with more pronounced changes in iron with a lower CE. The undercooling ability of the titanium decreases after exceeding a certain level. Increasing titanium from 0.09–0.12% slightly increases undercooling in iron with lower CE, but this effect was reduced in a more strongly hypereutectic iron. Alloying with titanium generally improves tensile strength, but the effectiveness of titanium additions also depends on the base iron CE range. Scanning electron microscope (SEM) studies revealed that most of the titanium-containing compounds were located in the metallic matrix: titanium carbides have been found in pearlite, while titanium nitrides and carbonitrides were located in ferrite. The presence of large amounts of extremely hard titanium-containing compounds, which often appear with steadite in a relatively high phosphorous content PM gray iron, amplifies the negative effect of titanium on machinability. This study suggests that for optimal combination of tensile strength/microstructure with good machinability, the titanium content in PM gray iron should not exceed 0.075%.     

系统失效的分支-界限分析法及其在桁架可靠性分析中的应用

本文首先介绍了系统失效的分支-界限分析法，然后以空间桁架系统为例用分支-界限分析法进行了可靠性分析。系统失效的分支-界限分析法直观、明了，适合对实际工程中的复杂系统进行可靠性分析。     

Ag-Cu-In-Sn合金的结构特性

借助金相、X光衍射及SEM方法研究Ag-Cu-In-Sn合金的结构特性及合金各组元在合金相中的分布规律,还讨论了某些相结构对合金力学性能的影响。四元合金的化学成分是(wt％)57～63Ag,17～23Cu,(20—x)In,xSn,其中:Ag+Cu=80wt％,In+Sn=20wt％,2≤x≤16。     

高线粗中轧机"浮动"检测结构设计及故障排除

为克服轧制中因机架锁紧功能降低而产生的机架沿轨座轴向移动的"浮动"现象,对其产生原因进行了分析,并通过改进锁紧装置结构及相关部件,使"浮动"故障得到预防和有效控制并及时排除。