智能打壳装置

在一台HAL 2 3 0电解槽上安装了 5个带有节能系统 (EnergySavingSystem)的汽缸和一个可用于快速测试寿命的“虚拟”ESS汽缸。测试的目的是使用ESS系统在正常操作中估计空气节省量和证明包括ESS系统在内的打壳装置的预期寿命周期能达到 8年。测试表明ESS系统的预期寿命超过 8年 ,与传统系统相比 ,可节省 5 9%的空气。如果全部使用该系统 ,可节省 65 %的能量。     

Ambient temperature cured TiB_2 cathode coating for aluminum electrolysis

1　INTRODUCTIONAluminumindustryhasbeendevelopingrapidlyinChinainrecentyears ,soderbergcellshavebeenre placedwithmodernprebakecellsinmanyaluminumsmelters,theaveragecelllifehowever ,forprebakecellsinourcountrywasonlyabout130 0d ,muchlowerthantheaveragecelllife ,i.e .above 2 5 0 0d ,forthecellsindevelopedcountries .TiB2 cathodecoating (TCC)couldbeoneofthesolutionstoreducegreatlytheopportunitytotheearlyfailureofcellsandextendthecelllifeofprebakecell[14 ] .Theconceptoftitaniumdiboride (TiB2 …     

碘仿电解合成的工艺研究

开发了一种以石墨为阳极、铅为阴极、采用旋转阳极和离子膜分隔电解槽的碘仿电解合成的先进工艺 ,经过 5因素 4水平的正交试验 ,发现影响电流效率的各工艺因素中 ,阳极电流密度的影响最大 ,其次分别为阳极液温度 ,阳极液 p H值 ,阳极液中碘化钾的浓度和阳极转速。优化得到碘仿电合成的最佳工艺条件为 :碘化钾浓度 2 0 0 g· L- 1 ,阳极电流密度 2 5 A· dm- 2 ,阳极液温度为 2 0℃ ,阳极液 p H值为 9.5,阳极转速为2 0 0 r· min- 1 ,在此最佳工艺条件下 ,电流效率可达 97.2 3%。     

四甲基氢氧化铵制备方法及应用

总结了几种制备四甲基氢氧化铵的方法,比较了各种方法的优缺点,介绍了其在不同领域的应用情况.认为离子膜电解法工艺设备简单、三废排放少,得到的产品纯度高,能够满足电子领域的需求,是较理想的制备方法,可取代氧化银法得到广泛的应用.     

隔膜电解制备Mn^3＋的研究

对电解媒质ＭｎＳＯ４在有隔膜条件下电解制备Ｍｎ３＋过程进行了研究。结果表明，无论均相还是非均相隔膜电解，在常温２０℃、４０％Ｈ２ＳＯ４介质中，当电流密度、ＭｎＳＯ４浓度、电解时间在很宽的范围变动时，电流效率保持很高，至少在８５％以上。     

油田废水电解杀菌研究

采用电解杀菌技术处理油田废水，研究了电解时间、电流强度、极板间距以及电极联结方式等因素对废水中硫酸盐还原菌杀灭效果的影响。结果表明，油田废水经3min电解杀菌，硫酸盐还原菌杀灭率高达99．90％。随着电解时间的增加，硫酸盐还原菌的杀菌率进一步提高；电流强度增加，硫酸盐还原菌的杀灭率升高。在电流强度保持不变的情况下，随着极板间距增加，极板之间电压升高，更有利于杀灭硫酸盐还原菌。在极板间电流强度相同的条件下，两种电极联结方式的杀菌率差别不大，杀菌率均在99．9％以上。     

Influence of anode material on the electrochemical oxidation of 2-naphthol: Part 2. Bulk electrolysis experiments

The electrochemical oxidation of 2-naphthol has been studied by galvanostatic electrolysis, using a range of electrode materials such as lead dioxide, boron-doped diamond (BDD) and Ti-Ru-Sn ternary oxide anodes. The influence of some operating parameters, such as current density, flow-rate and chloride concentration on naphthol oxidation has been investigated in order to find the optimum experimental conditions. Measurements of chemical oxygen demand, HPLC and total organic carbon have been used to follow the oxidation. The experimental data indicate that on PbO₂ and BDD, naphthol oxidation takes place by reaction with electrogenerated hydroxyl radicals and is favoured by low current density and high flow-rate. On the contrary, on a Ti-Ru-Sn ternary oxide the mineralisation of naphthol occurs only in the presence of chloride ions that act as redox mediators and COD removal is affected by chloride concentration and is not significantly influenced by the current density and mass-transfer coefficient. From a comparison of the results of the three electrodes it has been found that boron-doped diamond gives a faster oxidation rate and better current efficiency.     

我国金属阳极隔膜法烧碱发展现状与对策

详细介绍了我国氯碱工业采用金属阳极隔膜法制烧碱的现状及与世界先进水平的差距。提出了包括大力进行以节能为重点的技术改造；调整烧碱产品规格；彻底淘汰和转换石墨阳极隔膜法；推广先进的扩张金属阳极隔膜电解技术以及结合我国国情有计划地发展离子膜法制烧碱技术等改造措施及预期效果。     

无隔膜电解槽制备铁氰化钾的研究

在无隔膜电解槽中采用钛阳极、铜阴极电解制备铁氰化钾。本文探索了影响此过程电流效率及能耗的各种因素，分析确立了实际应用的电解条件     

A novel preparation method for NiCo2O4 electrodes stacked with hexagonal nanosheets for water electrolysis

In this paper, we describe the preparation of a porous nanosheet-stacked NiCo₂O₄ composite electrode using a novel electrophoretic deposition (EPD) calcination method. The effects of the deposition time and voltage, and of the calcination temperature have been investigated. The microstructure of the deposited films in the electrodes before and after calcination has also been investigated. The electrocatalytic properties of the electrodes have been investigated using cyclic voltammetry and polarization curves. The electrode films produced using this new technique have a porous structure composed of stacked hexagonal NiCo₂O₄ nanosheets. The resulting electrodes exhibit good electrocatalytic properties for water electrolysis.