Molten salts/ceramic-foam matrix composites by melt infiltration method as energy storage material

A new type of high temperature energy storage material was obtained through the melt infiltration method, using compounding SiC ceramic foam as matrix and Na₂SO₄ as phase change material. The resulting composite material was measured by XRD, SEM, TG-DSC methods. The experimental results indicate that the composite is composed of silicon carbide, sodium sulfate and square quartz, and no chemical reactions occurs between Na₂SO₄ and SiC matrix. Na₂SO₄ has a good bonding with the SiC ceramic foam matrix. As the composite material is characterized by high thermal energy storage density and high thermal conductivity, it is suit for energy storage under high temperature. Funded by the “863” Hi-Tech Research and Development Program of China (2008AA05Z418)     

碱体系中系列羟基苯基卟啉红外光谱和拉曼光谱性质研究

本文继续深入研究该体系中相关物质的红外光谱和拉曼光谱的性质.论文结果说明,在碱体系中,NaOH只与羟基苯基卟啉周边meso-位的羟基反应形成盐,这个性质与紫外可见光谱性质是一致的.同时这一结果也为研究卟啉与金属的相互作用提供了有益的理论支持.     

Characterization of self-assembled monolayers of iron and cobalt octaalkylthiosubstituted phthalocyanines and their use in nitrite electrocatalytic oxidation

Cobalt and iron phenylthiosubstituted phthalocyanines have been deposited on Au electrode surfaces through the self-assembled monolayer (SAM) technique. The so formed layers were studied using voltammetric and impedance techniques. These SAMs blocked a number of Faradic processes and electrocatalyzed the oxidation of nitrite. The electrocatalytic parameters of the cobalt and iron phenylthiosubstituted phthalocyanines deposited on Au electrodes in nitrite solution were studied. Nitrite overpotentials which are lower than ever reported were obtained in this work for the iron phenylthiosubstituted phthalocyanines with very high stability.     

Impedance spectroscopy study of hardened Portland cement paste

In this paper, the differential impedance analysis (DIA) has been applied to the study of the dielectric properties of hardened Portland cement paste. Two time constants are found in the impedance spectra obtained in the frequency region form 100 kHz to 15 MHz. One time constant has been attributed to the solid matrix and the other one to the liquid phase filling the pores. The effect of the cement paste-electrodes interface has been quantified using two different experimental set-ups. Measurements using direct contact between electrodes and cement paste have been compared with measurements using an air gap technique in which the specimen “floats” between the electrodes. The two referred time constants have been found in both types of measurements. The influence of drying on the dielectric parameters is also studied.     

Dynamic buffering performance of the honeycomb paperboard filled with polyurethane

A new kind of composite buffering material was made by filling the voids of honeycomb paperboard with polyurethane. Drop tests were performed to evaluate the dynamic energy absorption capacity of the material. Based on the tests results, we analyzed the mechanical behaviors of the material under different conditions and obtained the inherent influencing laws of some factors on the material＇s dynamic buffering performance. It was shown that the dynamic buffering performance varied directly with impact velocity, and inversely with the void diameter, thickness and buffeting area of the composite material.     

Specific energy optimization in sawing of rocks using Taguchi approah简

This work aims at selecting optimal operating variables to obtain the minimum specific energy （SE） in sawing of rocks. A particular granite was sampled and sawn by a fully automated circular diamond sawblades. The peripheral speed, the traverse speed, the cut depth and the flow rate of cooling fluid were selected as the operating variables. Taguchi approach was adopted as a statistical design of experimental technique for optimization studies. The results were evaluated based on the analysis of variance and signal-to-noise ratio （S/N ratio）. Statistically significant operating variables and their percentage contribution to the process were also determined. Additionally, a statistical model was developed to demonstrate the relationship between SE and operating variables using regression analysis and the model was then verified. It was found that the optimal combination of operating variables for minimum SE is the peripheral speed of 25 m/s, the traverse speed of 70 cm/min, the cut depth of 2 cm and the flow rate of cooling fluid of 100 mL/s. The cut depth and traverse speed were statistically determined as the significant operating variables affecting the SE, respectively. Furthermore, the regression model results reveal that the predictive model has a high applicability for practical applications.     

“双储”模式下的节能控制在小区供水系统中的应用

根据城市居民对供水的可靠性、稳定性、经济节能性的需求,课题组提出了一种基于"双储"模式的供水系统,并按照本市德胜住宅小区的供水要求,设计了一套由储水池、气压罐、变频器、多台水泵机组等主要设备构成的全自动变频恒压供水系统.经过近半年的运行测试,系统有效地解决了传统供水方式中存在的问题,增强了系统的总体性能,有明显的节能效果.     

INVESTIGATION ON CRYSTALLIZATION KINETICS OF Pd-Cu-Si GLASS

The crystallization kinetics of Pd-Cu-Si glass was studied by means of diferential scanningcalorimetry-Ⅱ.According to Kissinger peak shift meth(?)d and Arrhenius equation,theapparent activation energy was calculated.The crystallization kinetics follows Johnson-Mehl-Avrami equation with n=3.0 within 0.15相似文献   

基于高能效及公平性的移动设备定位算法

通过分析校园师生基于GPS的真实活动轨迹,以及何种算法才最适合具有自私性的移动用户展开合作,提出一种高能效及用户公平定位技术.通过采用代理设备合作思想,提出一种集中式最优算法,在保证固定精度界限和设备公平的基础上,实现移动设备GPS时间平均功率最小化.通过控制退避时间和GPS关闭时间,提出一种分布式准最优算法.最后,基于多种拓扑结构进行全面的仿真实验,验证了算法的高能效性和公平性.     

Floc architecture of bioflocculation sediment by ESEM and CLSM

Sediment flocculation is a critical component for the understanding of cohesive sediment dynamics. Traditionally, the referred study has largely been devoted to forming mechanism, influencing factors and physicochemical sediment conditions of all kinds of organic-flocculation and inorganic-flocculation. However, during the last decade, the bioflocculation of sediment by biological activity has been given increasing attention. But most studies have focused on the interrelations between biological and sedimentological variables. With the assistance of a newly developed field kit and correlative microscopy (which includes environmental scanning electron microscopy and confocal laser scanning microscopy), this article begins to bridge the resolution gap between sediment particles and biological activities as well as its metabolic products biofilm, in order to better understand the role of polymeric material biofilm in floc ultrastructure and outward floc behavior of bioflocculation sediment. Results have demonstrated that bioflocculation sediment was observed to be composed of complex networks of biofilm and appeared to be of complicated physical floc structures. The biofilm was found to embed particles and permeate the void space, representing the dominant physical bridging mechanism of the flocs and contributed to the extensive surface area, architecture characteristics, and mechanical properties of bioflocculation sediment.