熔融碳酸盐燃料电池阴极材料的导电性

通过交流阻抗方法研究了熔融碳酸盐燃料电池阴极材料锂镍氧化物、锂钴氧化物和锂铁氧化物的导电性能。结果表明:锂镍氧化物电极的导电性最好,锂钴氧化物电极的导电性次之,锂铁氧化物电极的导电性最差;它们的导电性都随着温度的升高而按指数规律增加;在合成锂钴氧化物(或锂铁氧化物)的过程中,使Li2CO3轻微过量,可以提高锂钴氧化物(或锂铁氧化物)电极的导电性,而且在同一温度下,随着nLi∶nCo(或nLi∶nFe,摩尔比)值的增大,锂钴氧化物(或锂铁氧化物)电极的导电性显著增加。     

恒定水深拖拉铺管管线的三维大挠度静态应力分析

海洋管线具有复杂的工程结构,在恶劣的海洋环境中,承受着比陆地管线更为复杂的载荷。为了保证管线安全工作,需对其进行准确的应力分析。本文应用有限元法对恒定水深拖拉铺管的管线内力、应力及位移进行了计算,并将结果与已有的计算结果进行对比,进一步分析了各种海洋环境因素对管线弯曲效应的影响,取得了有一定实用性的成果,可供海洋拖拉铺管施工时参考。     

Investigations of water inrushes from aquifers under coal seams

In many coal mines, limestone-confined aquifers underlie coal seams. During coal extraction from these mines, water inrushes occur frequently with disastrous consequences. This paper introduces the hydrogeological conditions of the coal mines and the potential water inrush disasters from aquifers under coal seams. It then presents the water inrush mechanism. The main factors which control water inrushes include strata pressure, mining size, geologic structures and the water pressure in the underlying aquifer. Analysis shows that reduction of confinement due to mining is the major cause of the water-conducting failure in the floor strata. The depth of the failure zone is strongly dependent on the mining width. This paper also presents field observation results of the water-conducting failure in the floor strata, and applies the finite element method coupled with stress-dependent permeability to analyze hydraulic conductivity enhancement due to coal extraction. Finally, theoretical and empirical methods to predict water inrushes are given, and technical measures for improving mine design and safety for coal extraction over aquifers are presented. These measures include fault and fracture grouting and mining method modification such as changing long-wall to short-wall mining.     

潜油电机碟形弹簧的动力学分析

为了降低潜油电泵机组的振动对止推轴承性能的影响,在潜油电机中节和下节的止推轴承静块底部安装了蝶形弹簧。用有限元方法进行模态分析,确定了蝶形弹簧的主振型和固有频率,然后进行瞬态动力学分析,求解蝶形弹簧在一定载荷下的应力和位移。依此设计的蝶形弹簧将进一步延长止推轴承的使用寿命。     

裂缝各向异性介质中P-SV转换波正演模拟

裂缝介质正演是研究裂缝性油藏的各向异性、裂缝检测方法、裂缝AVO反演等的前提。在裂缝方位各向异性(EDA)介质模型的基础上，重点研究了纵波震源激发的地震波所产生P-SV波的有限差分正演模拟方法。从各向异性单斜对称系统的刚性矩阵推导出的波动方程，可以满足EDA介质模型不同方位角入射的二维差分模拟要求。在有限差分模拟中，采用了普通的Kelly差分格式、二阶各向异性吸收边界条件和一般的纵波震源的解析形式，并应用修正的通量传输校(FCT)方法来消除频散。同时，对纵波震源的解析式进行了技术处理，取得了较好的效果。     

基于遗传算法的土钉支护结构优化设计研究

通过建立三维有限元模型,对土钉支护的变形和受力性能进行分析,得出土钉力的合理分布。在此基础上,考虑土钉支护的水平位移,采用遗传算法,对土钉支护的结构优化设计进行研究,建立了土钉支护结构的优化设计数学模型,并编制了相应的计算程序。通过算例分析,并与基于极限平衡分析的优化结果相比较,得出合理的土钉支护结构设计的参考结论。     

高压射流冲击破碎岩石的有限元计算

高压射流冲击破岩是一个复杂的非线性问题。通过MSC．Marc建立模型，分别使用动态接触作为非线性冲击载荷模拟高压水射流冲击岩石。通过动力计算分析，根据岩石内部应力的变化使用Hoffman失效准则研究了岩石的破碎过程。分析表明，增加射流冲击速度可以提高射流破碎岩石的效率，当射流速度迭到某一临界值时，射流水锤作用使得岩石发生大块破碎。     

常压渣油热反应过程中胶体的稳定性

利用质量分数电导率方法研究了中东和克拉玛依常压渣油在热反应过程中胶体的稳定性。结果表明，随着反应时间的增长，在热反应生焦诱导期内，渣油的胶体稳定性迅速下降；开始生焦后，胶体稳定性缓慢下降。从中东常压渣油的SARA四组分的数均相对分子质量、碳氢元素组成、平均芳碳率等方面探讨了中东常压渣油在热反应过程中胶体稳定性下降的原因。结果表明，在热反应中，由于裂解和缩聚反应的共同作用，使渣油的沥青质和饱和分含量上升，芳香分含量下降，胶质含量变化不大；随着热反应的进行，四组分的数均相对分子质量均呈下降趋势，导致了渣油胶体稳定性的下降并发生生焦反应。     

The Effect of Structural Defects on the Thermal Conductivity of ZnS, ZnSe, and CdTe Polycrystals

ZnS, ZnSe, and CdTe polycrystals are experimentally investigated. Mechanisms are treated which restrict the thermal conductivity in samples prepared by recrystallization pressing and by deposition from the vapor phase and subjected to additional strain. Anomalies are observed on the temperature dependences of the thermal resistance of investigated samples, which are due to the special features of their phonon spectra and to the variation of the contribution made by longitudinal and transverse phonon branches to the heat transfer in the Debye temperature region and higher.     

Bifurcation points and bifurcated branches by an asymptotic numerical method and Padé approximants

The aim of this work is to develop a reliable and fast algorithm to compute bifurcation points and bifurcated branches. It is based upon the asymptotic numerical method (ANM) and Padé approximants. The bifurcation point is detected by analysing the poles of Padé approximants or by evaluating, along the computed solution branch, a bifurcation indicator well adapted to ANM. Several examples are presented to assess the effectiveness of the proposed method, that emanate from buckling problems of thin elastic shells. Especially problems involving large rotations are discussed. Copyright © 2004 John Wiley & Sons, Ltd.