高抗冲聚苯乙烯的研制 Ⅰ.预聚合反应动力学及相转变过程的研究

对HIPS预聚合反应阶段的动力学及相转变行为进行了研究,发现基础胶的种类、用量、搅拌速率及阻聚剂含量对苯乙烯预聚合反应动力学和相转变过程均有不同程度的影响。     

A new characteristic of liquid-liquid systems—inversion holdup of intensely agitated dispersions

As the holdup of dispersed phase in an agitated liquid-liquid dispersion is increased at fixed agitation, a point is reached (called inversion holdup) when the dispersion inverts—the dispersed phase becomes continuous and vice versa. In this work, we present experimental data which suggest that the inversion holdup for sufficiently intense turbulence is independent of all the operational parameters associated with a stirred tank, e.g., stirrer speed, vessel volume, impeller size, and impeller type; it depends only on the properties of the liquid-liquid system. The inversion holdup was verified to remain unchanged even for inversion in turbulent flow field in the annular space between two coaxial cylinders. A hypothesis involving drops in near contact with each other at high holdups is used to explain the experimental data. The new finding may also provide a qualitative basis for selecting a liquid-liquid system with desired extent of mixing in the dispersed phase for carrying out transport and reactions in multiphase systems.     

掺钾的锰－铈氧化物催化剂结构和甲苯完全氧化反应性能

本文研究了负载的铈－锰氧化物上掺钾对甲苯完全氧化反应性能的影响．结果表明当铈锰原子比为２：１以及钾锰原子比为０．４：１时．催化剂活性最好．稳定性实验表明．在２５０ｈ的时间内活性基本稳定不变．ＸＲＤ和ＸＰＳ表征结果显示铈的加入促进了锰的高分散，加入的钾也显示高分散．表面上铈锰的比例与体相基本一致．铈和锰氧化物的Ｏｌｓ峰具有相同的结合能。     

福建水口全平衡垂直升船机调试技术研究与实践

全平衡垂直升船机是解决高坝通航问题的有效途径,而升船机在正式投入运行前必须通过严格的设备调试。介绍了福建水口全平衡垂直升船机在调试过程中所发现的一系列问题及解决方法:包括技术参数整定、优化逻辑闭锁条件、人机界面和数据库功能等。目前,水口电站升船机设备运行状态符合设计要求。根据水口升船机调试的实践经验,对钢丝绳卷扬提升式全平衡垂直升船机调试的关键技术进行了总结,以期对国内升船机建设提供一定的借鉴价值。     

SVD‐Based Accurate Identification and Compensation of the Coupling Hysteresis and Creep Dynamics in Piezoelectric Actuators

In this paper, the coupling hysteresis and creep in piezoelectric actuators are identified and compensated for accurate tracking. First, we present the coupling hysteresis and creep model in smart actuators. Next, a complete identification strategy is designed according to the properties of the Preisach model. Then, an approach for parameter updating of the coupling model is provided. With the identified hysteresis and creep, the model‐based inversion compensation is designed. Finally, we apply the model identification and compensation to a piezoelectric stage to demonstrate the effectiveness of the proposed approaches. Significant reduction of the tracking error is achieved with the model‐based inversion feedforward compensator in which the relative errors at 10 Hz and 50 Hz are reduced to 1.85% and 4.53%, respectively. In addition, the model‐based feedforward is augmented with an integral feedback controller. With the composite controller, the relative errors at 10 Hz and 50 Hz are reduced to 0.42% and 3.04%, respectively.     

刍议全寿命周期成本在配电网规划中的实践

目前,市场经济体制的确立和完善促使供电企业之间的竞争日趋激烈。在配电网规划中应用全寿命周期成本,可以提升企业的经济效益和综合竞争力,推动其更好、更快地发展。通过简要分析全寿命周期成本在配电网规划中的实践,提出了一些有价值的参考意见。     

一种用于目标跟踪的波形自适应选择算法

提出了一种用于雷达目标跟踪的自适应广义调频波形设计算法。该算法根据跟踪器的动态需求,以广义调频信号为样板波形自适应设计下一时刻的发射波形,其目的是最小化预测的目标跟踪均方误差,并假定高信噪比条件,且目标跟踪运动模型和观测模型均为线性,利用与某一波形相对应的克拉美--罗下限（CRLB）以及卡尔曼滤波器,通过最小化预测的跟踪均方误差来实现广义调频波形的自适应设计。仿真结果表明：在信噪比相同的情况下,与使用固定参数、自适应参数的线性调频波形设计算法相比,所提出的算法能够获得更低的目标跟踪均方误差。     

Conjugated effects of the compatibilization and the dynamic vulcanization on the phase inversion behavior in poly(butylene terephthalate)/epoxide-containing rubber reactive polymer blends

The conjugated effects of both reactive compatibilization and dynamic vulcanization on the phase inversion behavior of poly(butylene terephthalate) (PBT)/epoxide-containing rubber blends have been studied in detail. Pure ethylene-methyl acrylate random copolymer (E-MA) and ethylene-methyl acrylate-glycidyl methacrylate random terpolymer (E-MA-GMA) were used as non reactive or reactive rubber phase, respectively. Location of the phase inversion region was studied using several techniques, including transmission electron microscopy (TEM) and dynamical mechanical thermal analysis (DMTA). To evaluate the relative influence of the blend compatibilization and the dynamic vulcanization on the phase inversion behavior, the relative kinetics of the two reactions were modified using different PBT and E-MA-GMA grades. The obtained results show unambiguously that the position and the width of the phase inversion region is essentially governed by the kinetic of the dynamic vulcanization process. The effect of the blend compatibilization remains quite limited even in the case of fast interfacial reaction. The crosslinking of the rubber phase induces an important shift of the phase inversion composition to higher rubber content. For blends containing low molecular weight PBT, up to 60 wt% of rubber can be homogeneously dispersed in the PBT matrix at long mixing time. In this case, development of high performance PBT based thermoplastic vulcanisates can be envisioned.     

全参考图像质量评价综述

图像质量评价是图像处理领域内一项很有意义的研究课题。客观图像质量评价方法可分为全参考评价方法、半参考评价方法和无参考评价方法, 目前全参考评价方法较为成熟, 而半参考和无参考评价方法则处于初级阶段, 远远达不到参考评价方法所能达到的效果。对全参考评价方法进行综述。首先简要地介绍了各种类型的评价方法, 其次详细地介绍了PSNR、SSIM、MSSIM、IFC、VIF、FSIM等几种典型的全参考图像质量评价方法, 然后在LIVE和TID2008数据库上进行实验, 对这几种全参考方法进行对比、分析, 最后探讨图像质量评价研究的发展趋势。     

改进的局域均值分解在机械故障诊断中的应用

为了准确地提取出故障特征,把局域均值分解算法应用于机械故障振动信号的特征提取中.然而在对信号进行局域均值分解时,由于端点的趋势无法预知,在分解时会污染到整个信号序列,而且滑动平均造成了信号的过平滑处理,导致故障特征不能准确地提取.采用波形匹配解决端点处信号的走势,之后再利用线性插值求得信号的局域均值函数与包络函数,通过在Matlab环境下仿真调幅信号验证了该算法在端点处能很好的保持原有信号的特征;并采用实际的机械振动信号进行实验验证,引入端点效应评价指标,根据分解后的生产函数与原信号的相关系数验证了改进的局域均值分解更能准确地提取故障特征.