软段含羧基的水性聚氨酯贮存稳定性研究

合成了软段含羟基的水性聚氨酯（WPU），对影响其贮存稳定性的各种因素进行了研究，通过显微镜对PU进行了观察。结果表明：以甲苯二异氰酸酯（TDI）合成，在有性溶剂（如丁酮、丙酮）条件下用三乙胺中和，采用较小相地分子质量的聚酯有利于增强WPU的贮存稳定性，以TDI合成的PU-TDI体系的粒径较PU-IPDI体系的小，稳定性高；以丁酮、丙酮为溶剂的PU-IPDI体系相反转完全。     

Rheological evaluation of the influence of polymer concentration and molar mass distribution on the formation and performance of asymmetric gas separation membranes prepared by dry phase inversion

Asymmetric gas separation membranes were prepared by the dry-casting technique from PEEKWC, a modified amorphous glassy poly(ether ether ketone). The phase inversion process and membrane performance were correlated to the properties of the polymer and the casting solution (molar mass, polymer concentration, solution rheology and thermodynamics). It was found that a broad molar mass distribution of the polymer in the casting solution is most favourable for the formation of a highly selective membrane with a dense skin and a porous sub-layer. Thus, membranes with an effective skin thickness of less than 1 μm were obtained, exhibiting a maximum O₂/N₂ selectivity of 7.2 and a CO₂/CH₄ selectivity of 39, both significantly higher than in a corresponding thick dense PEEKWC membrane and also comparable to or higher than that of the most commonly used polymers for gas separation membranes. The CO₂ and O₂ permeance were up to 9.5×10⁻³ and 1.8×10⁻³ m³/(m² h bar) (3.5 and 0.67 GPU), respectively.     

Speaker adaptive voice source modeling with applications to speech coding and processing

We discuss the use of low-dimensional physical models of the voice source for speech coding and processing applications. A class of waveform-adaptive dynamic glottal models and parameter identification procedures are illustrated. The model and the identification procedures are assessed by addressing signal transformations on recorded speech, achievable by fitting the model to the data, and then acting on the physically oriented parameters of the voice source. The class of models proposed provides in principle a tool for both the estimation of glottal source signals, and the encoding of the speech signal for transformation purposes. The application of this model to time stretching and to fundamental frequency control (pitch shifting) is also illustrated. The experiments show that copy synthesis is perceptually very similar to the target, and that time stretching and “pitch extrapolation” effects can be obtained by simple control strategies.     

Horizontal wells and steam-assisted gravity drainage

Petroleum can be produced more efficiently using horizontal wells instead of conventional wells. For a typical 16 hectare well spacing, the pressure drawdown is as small as one-fiftieth of that for conventional wells. In some cases, where coning is a problem in conventional production, horizontal wells allow operation with much less coproduction of the displacing fluid. In the thermal recovery of bitumen and heavy oils, the Steam-Assisted Gravity Drainage process with horizontal production wells allows the systematic sweeping of the reservoir with economic production rates and without steam bypass. This paper described and reviews the application of horizontal wells to the production of heavy crude oils and bitumen by both non-thermal and thermal methods.     

乳液聚合导致一种新的转相过程

借助电导率仪、光学显微镜和亚微粒子分析仪等测试手段。研究了乳液聚合导致一种新的转相过程,并用于八甲基环四硅氧烷的聚合中。研究表明:体系以 W/O 相态开始,单体由连续相向水相(分散相)内的胶束中扩散并发生聚合反应,形成 O/W/O 复合乳液。反应过程中连续相体积不断减小,分散相(O/W 复相)体积不断增大,当达到某一临界相比时,体系发生转相,转相后乳液为 O/W。对本实验物系,转相点临界相比主要由初始水油比和乳化剂浓度决定。同常规的乳液聚合相比,伴有转相现象的乳液聚合有其自身的特点,转相使得聚合速率、聚合物粒径及分布、乳液稳定性等发生变化。     

加权条件熵在异常检测中的应用

通过分析信息熵在异常检测中的应用和条件熵的固有特性, 提出了一种基于条件熵和加权熵理论的异常检测方法。分析网络流量特征, 选取具有内在相关性的网络特征属性, 给出了加权系数矩阵的公式和异常检测的具体实现方法。通过实验验证了该方法的有效性和实用性, 根据不同属性特征在加权条件熵理论中的应用效果, 分析了不同特征属性选择造成检测效果差异的原因。     

低速率拒绝服务攻击研究与进展综述

低速率拒绝服务攻击是新型的拒绝服务攻击,对Internet的安全造成严重的潜在威胁,引起众多研究者的兴趣和重视,成为网络安全领域的重要研究课题之一.自2003年以来,研究者先后刻画了Shrew攻击、降质攻击、脉冲拒绝服务攻击和分布式拒绝服务攻击等多种低速率拒绝服务攻击方式,并提出了相应的检测防范方法.从不同角度对这种新型攻击的基本机理和攻击方法进行了深入的研究;对TCP拥塞控制机制进行了安全性分析,探讨了引起安全问题的原因;对现有的各种各样的LDoS攻击防范和检测方案,从多个方面进行了分类总结和分析评价;最后总结了当前研究中出现的问题,并展望了未来研究发展的趋势,希望能为该领域的研究者提供一些有益的启示.     

基于改进符号化度量方法的机场噪声异常检测

机场噪声中的异常情况拥有很大价值,利用它能够及时完善飞机和机场的设备。结合机场噪声数据的特点,对上述问题进行研究并提出一种基于改进的符号化聚集近似(Symbolic Aggregate Approximation,SAX)相似性度量的单监测点的时间序列异常检测方法。其运用相似性度量方法计算出度量结果,再运用k近邻异常检测方法进行异常发现,最后发现异常时间段。该方法在理论验证可行性之后在某机场的实测数据中进行应用,取得了良好的效果。     

基于磁通门传感器的铁磁探测系统设计

在核磁共振检查前需要进行无磁化确认,针对核磁共振检查所处的环境背景磁场复杂、干扰较多,系统出现误报警高、探测失效等问题,设计了基于磁通门传感器的铁磁探测系统。系统使用二次谐波法测量磁场信号,设计模拟电路进行信号相敏检测。通过积分反馈提高闭环系统的线性度和抗干扰性,探头工作在稳定的状态。采用卡尔曼滤波对背景磁场和磁异信号进行处理,提高信号信噪比,同时设计能量检测器对磁异信号进行检测。试验测试结果表明,系统在核磁共振室外复杂磁场环境可以减少设备工作时的误报警,有效探测出铁磁性物质。     

地震前后基准站GPS数据异常提取算法

目前对地震前兆异常的研究主要集中在“热”和“电”等方面,很少涉及基准站的GPS数据。然而,已经有学者证明震中附近基准站的GPS时间序列坐标数据中也蕴含着大地震的前兆信息。针对2001~2010年间美国本土发生的具有代表性的三个地震进行了研究,首次将Martingale理论运用于GPS数据处理,提出一种异常提取算法,进而对地震前后,震中附近多个基准站的GPS数据进行分析。实验结果表明算法能够有效的反映大地震前后GPS数据中异常的变化趋势,为使用GPS数据对大地震进行预报提供了更多可能。