Nitrogen dioxide effect in the reduction of nitric oxide by propane in oxidizing atmosphere

The role of nitrogen dioxide in the selective reduction of NO by propane over a Cu-MFI zeolite is investigated. NO₂ and NO reductions were carried out under similar conditions of reaction. In the presence of oxygen, the reduction of NO by C₃H₈ does not differ significantly from that of NO₂. In the absence of oxygen, the reduction of NO₂ by propane occurs with a partial decomposition of the nitric dioxide molecule. Such a decomposition leads to the formation of oxygen, which is responsible for the increase in catalytic activity by comparison with the same reaction performed with NO. NO₂ formed and released in the gas phase during the reduction of NO by propane in the presence of oxygen does not play a predominant role in the catalytic process.     

IR spectroscopic study of Pt/Kl zeolites using adsorption of CO as a molecular probe

FTIR spectra of CO adsorbed on Pt/KL catalysts show that the relative band intensities and the total dispersion markedly depend on the catalyst preparation method (ion exchange, incipient wetness impregnation or co-impregnation with KCl). The CO stretching frequency of the dominant band for linear CO is shifted to higher wavenumbers, parallel with the proton concentration in the reduced catalyst, which is derived independently from the intensity of the IR bands of the OH groups. The results are in accordance with the model that electron-deficient platinum particles are platinum-proton adducts.On leave from: N.D. Zelinsky Institute of Organic Chemistry, Academy of Sciences, Moscow, USSR.     

Effect of the particle size ratio on the conductivity of conductor-insulator powder composites: Numerical simulation

A theoretical method for determining the percolation limit and effective conductivity of composites based on polydisperse mixtures of insulator and conductor powders is proposed. The effect of the particle size ratio between the insulator and conductor on the percolation limit and effective conductivity is studied. Numerical simulation of the microstructure, effective properties, and percolation limit in composites is discussed. __________ Translated from Poroshkovaya Metallurgiya, Vol. 46, No. 1–2(453), pp. 31–40, 2007.     

重油催化裂化反应技术的新进展

近十几年来，重油催化裂化技术作为主要的重质油轻质化手段得到了迅速发展，国内外围绕催化裂化装置的提升管反应器也开发了许多新技术。综述了重油催化裂化反应技术的新进展，并对新技术的开发进行了讨论。     

从废钼合金催化剂中提取钼等有价元素方法的研究

ＭｏＣｏＮｉ合金料首先氧化焙烧碱浸出，滤饼再加纯碱焙烧水浸出使钼与钴镍分离，最后用萃取法分离钴镍的工艺流程，对废钼合金催化剂进行了综合回收。采用该工艺流程和生产线分别生产出合格的工业级钼酸钠、氧化钴和氧化镍。     

重症监护病房紧急状况预警算法

重症监护病房中的病人身体状况通常很不稳定,常出现各种需要医护人员介入治疗的紧急状况。由于医疗资源有限,医护人员可能无法及时发现并处理这些紧急状况,给病人的存活率带来严重的负面影响。如果可以预测这些紧急状况的发生,并及时通知相关医护人员,将大大提高病人的存活率。常见重症监护病房紧急状况包括突然死亡、败血症、肺部感染、急性低血压、以及器官衰竭等。紧急状况预警建模主要采用病人的长时间生命体征监测数据,预测在一定时间之后发生某种紧急状况的可能性。预警模型所采用的监测数据分为静态数据、事件数据和时间序列数据等三类。静态数据具有容易采集、但预测准确性偏低的特点。事件数据或时间序列数据、以及多种类型数据的混合数据对于紧急状况预警模型的预测性能的提高有重要作用,将会获得更广泛的应用。     

卷积融合文本和异质信息网络的学术论文推荐算法

针对交互数据稀疏和推荐多样性问题,基于卷积协同过滤推荐框架提出卷积融合文本和异质信息网络的学术论文推荐算法（WN-APR）。首先学习不同语义下用户和论文的多样化特征,缓解数据稀疏问题;然后基于外积设计不同语义特征相互增强的方式融合它们,并使用三维卷积神经网络代替二维卷积神经网络充分挖掘不同特征对性能的影响;最后改进贝叶斯个性化排序损失函数增强推荐多样性。在CiteuLike-a、CiteuLike-t数据集上的实验结果表明,相比于基线模型,WN-APR在准确率和多样性的四个指标上都有所提升。     

Cell处理器访存特征研究

Cell处理器是一款异构多核处理器,拥有强大的计算能力。但是,在进行应用并行化时,却受到本地存储器容量、访存带宽和数据传输延时等的限制。DMA传输是隐藏长延时、提高存储带宽利用率的有效方法。本文在分析Cell处理器结构基础上,进行了一系列详细的DMA测试,并利用指数拟合技术得到DMA平均带宽模型,发现参与DMA传输的SPE数量和每次DMA传输规模是影响DMA访存带宽的主要因素。     

Reactant induced restructuring and corrosion of germanium-palladium catalysts during hydrogenation reactions

An anomalous rate enhancement with increasing conversion has been observed during the liquid phase hydrogenation of nitrobenzene and crotonaldehyde over Ge/Pd/C catalysts at ambient temperature and atmospheric pressure. Inductive coupled plasma atomic emission spectroscopy and electrochemical measurement of the oxidation state of catalysts during reaction revealed that the bimetallic particles were partially oxidized by the reactants, which resulted in Ge-dissolution and increased exposure of Pd on the surface. It is proposed that the surface and bulk composition of Ge/Pd catalysts are a function of their oxidation state. This behaviour is due to the unusually high mobility of Ge in the Pd lattice and to the good solubility of GeO₂ in polar solvents. The influence of hydrogen transport on the corrosion process and the stability of other X/Pd type bimetallic catalysts during liquid phase hydrogenation are also discussed.     

Olefins polymerization on titania and titania-supported rhodium

The adsorption of ethene and propene on titania and titania-supported rhodium has been studied, observing a continuous adsorption even after 24 h. The samples have been reduced at 623 or 773 K, but no difference was observed, whichever the reduction temperature or the presence of rhodium, on the amount of gas adsorbed per unit of surface area of the solid. A study of the polymerization has been done following the equal reactivity hypothesis, and it has been concluded that the role played by the rhodium particles is to facilitate adsorption of the gaseous molecule, that is then transfered to the surface of the support, where it polymerizes.