用于烯烃复分解反应的钌茚基催化剂的合成研究进展

基于钌金属的烯烃复分解反应现今已成为一种至关重要且快速有效的催化反应类型,在聚合领域以及现代有机合成的应用方面起着改革性的推进作用。作为烯烃复分解反应催化剂的一种,钌茚基催化剂在该领域得到成功应用。结合近年来钌茚基催化剂在烯烃复分解反应中的合成研究进展,简述了其发展过程,介绍了该领域创新性的研究成果,重点论述了一些新型钌茚基催化剂的合成方法,并且探讨了辅助配体的结构对催化剂稳定性和活性的影响,最后对其发展方向以及应用前景进行了展望。     

New Insight into Procedure of Interface Electron Transfer through Cascade System with Enhanced Photocatalytic Activity

Recombination of photogenerated electron–hole pairs is extremely limited in the practical application of photocatalysis toward solving the energy crisis and environmental pollution. A rational design of the cascade system (i.e., rGO/Bi₂WO₆/Au, and ternary composites) with highly efficient charge carrier separation is successfully constructed. As expected, the integrated system (rGO/Bi₂WO₆/Au) shows enhanced photocatalytic activity compared to bare Bi₂WO₆ and other binary composites, and it is proved in multiple electron transfer (MET) behavior, namely a cooperative electron transfer (ET) cascade effect. Simultaneously, UV–vis/scanning electrochemical microscopy is used to directly identify MET kinetic information through an in situ probe scanning technique, where the “fast” and “slow” heterogeneous ET rate constants (K_eff) of corresponding photocatalysts on the different interfaces are found, which further reveals that the MET behavior is the prime source for enhanced photocatalytic activity. This work not only offers a new insight to study catalytic performance during photocatalysis and electrocatalysis systems, but also opens up a new avenue to design highly efficient catalysts in photocatalytic CO₂ conversion to useful chemicals and photovoltaic devices.     

直接Z-型立方/六方ZnIn2S4复合光催化剂的制备及其光催化性能

通过水热反应方法制备出立方相ZnIn₂S₄和六方相ZnIn₂S₄和系列不同摩尔比的复合相ZnIn₂S₄光催化剂,使用X射线衍射、扫描电子显微镜、电子能谱、透射电子显微镜、光致发光光谱、N₂吸附-脱附法及紫外-可见光漫反射等手段表征了样品的晶体结构、显微结构及吸光特性并在可见光照射下进行了甲基橙降解实验。结果表明,复合相ZnIn₂S₄样品都具有比立方相、六方相和机械混合的ZnIn₂S₄更好的可见光催化活性,当复合相ZnIn₂S₄样品中立方相与六方相摩尔比为3:7时体系的催化活性最高。这种样品被可见光照射30 min后,甲基橙的降解率达到95.2%。其降解机理与样品较大的比表面积以及样品中的立方相与六方相之间的密切接触而形成直接Z-型光催化过程有关。     

Highly Exposed ?NH2 Edge on Fragmented g-C3N4 Framework with Integrated Molybdenum Atoms for Catalytic CO2 Cycloaddition: DFT and Techno-Economic Assessment

This study focuses on the applicability of single-atom Mo-doped graphitic carbon nitride (GCN) nanosheets which are specifically engineered with high surface area (exfoliated GCN),  NH₂ rich edges, and maximum utilization of isolated atomic Mo for propylene carbonate (PC) production through CO₂ cycloaddition of propylene oxide (PO). Various operational parameters are optimized, for example, temperature (130 °C), pressure (20 bar), catalyst (Mo₂GCN), and catalyst mass (0.1 g). Under optimal conditions, 2% Mo-doped GCN (Mo₂GCN) has the highest catalytic performance, especially the turnover frequency (TOF) obtained, 36.4 h⁻¹ is higher than most reported studies. DFT simulations prove the catalytic performance of Mo₂GCN significantly decreases the activation energy barrier for PO ring-opening from 50–60 to 4.903 kcal mol⁻¹. Coexistence of Lewis acid/base group improves the CO₂ cycloaddition performance by the formation of coordination bond between electron-deficient Mo atom with O atom of PO, while  NH₂ surface group disrupts the stability of CO₂ bond by donating electrons into its low-level empty orbital. Steady-state process simulation of the industrial-scale consumes 4.4 ton h⁻¹ of CO₂ with PC production of 10.2 ton h⁻¹. Techno-economic assessment profit from Mo₂GCN is estimated to be 60.39 million USD year⁻¹ at a catalyst loss rate of 0.01 wt% h⁻¹.     

靶场仿真中分布式异构网关技术研究

为快速、高效地实现试验与训练领域各靶场、设施和仿真的互操作、重用和可组合,构建实物的、虚拟的、构造的(LVC)分布式网络,研究了目前主要存在的高级分布式仿真架构,包括分布式交互仿真(DIS)、高层体系架构(HLA)及试验与训练使能体系结构(TENA);在对它们的异同进行分析比较的基础上,确定以TENA网关对异构靶场进行无缝连接是实现靶场互联的最佳方案;对网关进行了总体设计并对关键技术进行了分析,网关原型的建立为网关的深入研究和开发奠定了基础。     

部署服务器虚拟化的安全风险

虚拟化技术究竟是怎样一种技术?本文将探讨服务器虚拟化到底有哪些优势以及部署安全服务器虚拟化所存在的安全风险。     

Consensus of second-order multi-agent systems with nonsymmetric interconnection and heterogeneous delays

In this paper, a consensus algorithm of multi-agent second-order dynamical systems with nonsymmetric interconnection and heterogeneous delays is studied. With the hypothesis of directed weighted topology graph with a globally reachable node, decentralized consensus condition is obtained by applying generalized Nyquist criterion. For the systems with both communication and input delays, it is shown that the consensus condition is dependent on input delays but independent of communication delays.     

System supports for protocol and application adaptation in vertical handoffs

In overlay networks, the network characteristics before and after a vertical handoff would be drastically different. Consequently, in this paper, we propose an end‐to‐end based scheme to support protocol and application adaptation in vertical handoffs. First, we proposed a Vertical‐handoff Aware TCP, called VA‐TCP. VA‐TCP can identify the packet losses caused by vertical handoffs. If segments losses are due to vertical handoffs, VA‐TCP only retransmits the missing segments but does not invoke the congestion control procedure. Moreover, VA‐TCP dynamically estimates the bandwidth and round‐trip time in a new network. Based on the estimated bandwidth and round‐trip time, VA‐TCP adjusts its parameters to respond to the new network environment. Second, during a vertical handoff, applications also need to be adapted accordingly. Therefore, we design a programming interface that allows applications to be notified upon and adapt to changing network environments. To support our interface, we utilize the signal mechanism to achieve kernel‐to‐user notification. Nevertheless, signals cannot carry information. Thus, we implement the shared memory mechanism between applications and the kernel to facilitate parameters exchange. Finally, we also provide a handoff‐aware CPU scheduler so that tasks that are interested in the vertical‐handoff event are given preference over other processes to attain a prompt response for new network conditions. We have implemented a prototype system on the Linux kernel 2.6. From the experimental results, our proposed protocol and application adaptation mechanisms are shown to effectively improve the performance of TCP and applications during vertical handoffs. Copyright © 2008 John Wiley & Sons, Ltd.     

基于Web Service的异构集成查询方案

提出一种基于Web Service的异构集成综合查询系统,采用B/S和C/S相结合的多层分布式体系结构,能够有效提高系统的实用性,并屏蔽数据的异构性和各种系统模式的差别,仿真实验结果表明,该设计方案提升了异构系统的可集成性,且能实现用户透明查询的功能,保证数据源的安全。     

Controllability of heterogeneous multi-agent systems under directed and weighted topology

This paper considers the controllability problem for both continuous- and discrete-time linear heterogeneous multi-agent systems with directed and weighted communication topology. First, two kinds of neighbour-based control protocols based on the distributed protocol of first-order and second-order multi-agent systems are proposed, under which it is shown that a heterogeneous multi-agent system is controllable if the underlying communication topology is controllable. Then, under special leader selection, the result shows that the controllability of a heterogeneous multi-agent system is solely decided by its communication topology graph. Furthermore, some necessary and/or sufficient conditions are derived for controllability of communication topology from algebraic and graphical perspectives. Finally, simulation examples are presented to demonstrate the effectiveness of the theoretical results.