Unprecedented Surface Plasmon Modes in Monoclinic MoO2 Nanostructures

Developing stable plasmonic materials featuring earth-abundant compositions with continuous band structures, similar to those of typical metals, has received special research interest. Owing to their metal-like behavior, monoclinic MoO₂ nanostructures have been found to support stable and intense surface plasmon (SP) resonances. However, no progress has been made on their energy and spatial distributions over individual nanostructures, nor the origin of their possibly existing specific SP modes. Here, various MoO₂ nanostructures are designed via polydopamine chemistry and managed to visualize multiple longitudinal and transversal SP modes supported by the monoclinic MoO₂, along with intrinsic interband transitions, using scanning transmission electron microscopy coupled with ultrahigh-resolution electron energy loss spectroscopy. The identified geometry-dependent SP energies are tuned by either controlling the shape and thickness of MoO₂ nanostructures through their well-designed chemical synthesis, or by altering their length using a developed electron-beam patterning technique. Theoretical calculations reveal that the strong plasmonic behavior of the monoclinic MoO₂ is associated with the abundant delocalized electrons in the Mo d orbitals. This work not only provides a significant improvement in imaging and tailoring SPs of nonconventional metallic nanostructures, but also highlights the potential of MoO₂ nanostructures for micro–nano optical and optoelectronic applications.     

Edge-Mediated Annihilation of Vacancy Clusters in Monolayer Molybdenum Diselenide (MoSe2) under Electron Beam Irradiation

Annihilation of vacancy clusters in monolayer molybdenum diselenide (MoSe₂) under electron beam irradiation is reported. In situ high-resolution transmission electron microscopy observation reveals that the annihilation is achieved by diffusion of vacancies to the free edge near the vacancy clusters. Monte Carlo simulations confirm that it is energetically favorable for the vacancies to locate at the free edge. By computing the minimum energy path for the annihilation of one vacancy cluster as a case study, it is further shown that electron beam irradiation and pre-stress in the suspended MoSe₂ monolayer are necessary for the vacancies to overcome the energy barriers for diffusion. The findings suggest a new mechanism of vacancy healing in 2D materials and broaden the capability of electron beam for defect engineering of 2D materials, a promising way of tuning their properties for engineering applications.     

一种正前视宽扇区高分辨雷达扫描成像方法

合成孔径雷达（Synthetic Aperture Radar,SAR）只有照射到飞行方向左、右两侧的感兴趣成像区域时才能处理出高分辨率SAR图像,飞行方向正前方的成像区域就成为了SAR成像的固有盲区。三通道（和、方位差、俯仰差）毫米波单脉冲成像雷达能够实现对正前视场景的二维成像,获取单脉冲图像。提出对SAR/单脉冲图像进行图像配准和融合拼接的方法：首先利用多尺度多方向二维Gabor滤波器组分别对SAR/单脉冲图像进行特征提取,然后对两组特征矩阵进行归一化互相关匹配,对匹配好的图像进行像素级融合处理,得到完整的正前视宽扇区高分辨雷达图像。试验数据成像处理结果表明,所提复合成像算法能够对飞行正前方宽扇区范围内进行高分辨成像,有效解决了工程实际中碰到的正前视高分辨成像盲区的难题,对于前视雷达成像侦察、弹载雷达目标区域景象匹配、飞行器夜航、盲降等具有一定的工程实际意义。     

烷氧基取代金属酞菁固态薄膜光谱及结构的研究

本文选用一种烷氧基取代的金属酞菁化事物，溶解旋涂于玻璃基板上，分别经有机溶剂 加热处理，发现都可以使吸收光谱范围向长波方向拓宽。Ｘ－射线衍射研究表明；经上述方法处理后都可使染料分子的聚集程度发生变化，堆砌方式由微晶型向晶型结构转变，高分辩率扫描电镜观察进一步主宰上述结果。     

基于目标子空间的雷达自动识别系统

分析了HRRP空间RATR方法的冗余噪声匹配问题．探讨基于目标子空间的RATR方法．与HRRP空间相比,目标子空间理论上不存在冗余噪声,能够更加准确地反映目标的结构特征．对外场ISAR实测数据的处理表明,此目标子空间算法的识别结果比传统的HRRP空间算法的效率更高,比常规方法具有明显的优越性．     

吉林一号轻型高分辨率遥感卫星光学成像技术

为了实现吉林一号光学遥感卫星轻量化设计与高分辨率多光谱多模式成像,采用星载一体化设计理念及敏捷多模式成像策略,完成了吉林一号卫星的指标、方案及关键技术的设计与在轨多模式光学成像。吉林一号整星的质量为450kg,有效载荷比高达40%,机动能力达2.1(°)/s,可实现大侧摆、同轨立体与条带拼接等多模式成像,结合星上800GB的FLASH存储能力和X波段双通道600 Mbps的数据传输能力,卫星每天可获取近150 000km~2的图像数据。吉林一号轻型高分辨率光学卫星于2015年发射入轨,运行在656km太阳同步轨道,地面全色和多光谱分辨率分别优于0.72m和2.88m,满足多行业应用及商业化运营的需求。     

基准面变化与岩相及砂体展布的沉积响应——以鄂尔多斯盆地苏南地区盒八段辫状河三角洲为例

为了弄清岩相变化及砂体展布样式的成因,文中针对基准面升降分析了其与岩相及砂体展布的沉积响应关系。以高分辨率层序地层学理论为指导,结合岩心、测井曲线在基准面变化时的识别标志,将鄂尔多斯盆地苏南地区盒八段划分为上、下2个小段,各小段又分2个IV级层序(中期旋回)。建立研究区层序地层格架,选取垂直物源和顺物源2条连井剖面,刻画剖面砂体展布样式,厘清了基准面变化与砂体展布的沉积响应关系,并在此基础上,建立了河流及三角洲相基准面升降与岩相和砂体展布的响应模式。     

测井高分辨率层序地层自动划分技术与应用尝试

在河流-三角洲沉积体系中采用泥砂比定量描述了决定地层沉积模式的可容纳空间与沉积物供给速率比这一抽象而又重要的变量,使用的关键技术包括:测井岩相自动划分、泥砂比曲线定量计算以及测井曲线滤波等。并综合利用测井岩相、泥砂比曲线以及自然伽马趋势分析曲线自动划分高分辨率层序。利用这一技术可极大提高高分辨率层序地层划分的效率和精度。     

Electron diffraction from micro- and nanoparticles of hydroxyapatite

Hydroxyapatite (HAP) obtained from aqueous solutions under different conditions has been examined by high-resolution transmission electron microscopy (HRTEM) and electron diffraction, including selected-area electron diffraction (SAED) and microdiffraction. A Philips CM300 field-emission gun electron microscope with a Schottky W/ZrO field-emission tip and a spherical aberration constant of 0.65 mm was used at 300 kV. The HAP crystals had different sizes, ranging from a few nanometres to a few micrometres. Single-crystal diffraction patterns have been obtained from the largest microcrystals using the conventional SAED technique. Assemblies of nanoparticles gave only broad diffuse rings. Nevertheless, microdiffraction with electron microprobes 3.5–10 nm in diameter clearly indicated the crystalline character of the nanoparticles in these assemblies. Experimental HRTEM images, Fourier transforms and calculated images exhibited the fine structure of the HAP crystals.     

TEM characterization of self-organized CdSe/ZnSe quantum dots

CdSe quantum dots (QDs) grown on ZnSe were investigated by various transmission electron microscopy (TEM) techniques including diffraction contrast imaging, high-resolution and analytical transmission electron microscopy both of plan-view as well as cross-section specimens. The size of the QDs ranges from about 5–50 nm, where from the contrast features in plan-view imaging two classes can be differentiated. In the features of the smaller dots there is no inner fine structure resolvable. The larger ones exhibit contrast features of fourfold symmetry as expected for pyramid-like islands. Corresponding simulations of diffraction contrast images of truncated CdSe pyramids with the edges of the basal plane orientated parallel to <100> are in relatively good agreement with this assumption. In TEM diffraction contrast imaging of cross-section samples the locations of the quantum dots are visualized by additional dark contrast features. The QDs have a distinct larger extension in growth direction compared to the almost uniformly thick CdSe wetting layer. The presence of the CdSe QDs was also confirmed by energy-dispersive X-ray spectroscopy.