高分辨率层序地层学在划分流动单元中的应用

针对濮城油田南区沙二上2 3油藏构造相对简单、完整,油层厚度大,层内非均质严重,开发效果差的特点,以高分辨率层序地层学为基础,通过对钻井、测井基准面旋回的识别划分流动单元,进而通过基准面旋回对比完成流动单元的对比.最终将储层细化为19个小层,细化后,使得无法解决的部分层内矛盾转化为层间矛盾,为开发调整提供了一定的依据.     

一种大行程高精度微执行器的研究

为了解决宏/微驱动系统中大行程和高精度之间的矛盾,研制了一种基于摩擦工作原理的压电陶瓷驱动的新型大行程、高分辨率步进式微执行器,该微执行器的行程为300mm、位移分辨率为0.02μm.提出了一种新型的基于压电陶瓷的柔性四杆型可调预压装置,并进行有限元分析.建立了微执行器系统的动力学模型,基于Karnopp“粘滞-滑移“摩擦模型分析微执行器力学特性.对微执行器的运动特性进行实验测试.     

离焦和球差效应对高分辨率电镜性能参数的影响

从离焦效应和球差效应出发，分析了它们对高分辨率电子显微镜分辨率和通带宽度的影响。得出了最佳欠焦量下分辨率与球差系数和电子波长的关系．在最佳欠焦条件下，分辩率与球差系数的-1/4次方成正比，与电子波长的-3/4次方成正比，通带宽度随欠焦量绝对值的增大而减小．     

Aspects regarding measurement of thickness of intergranular glassy films

Materials such as Si₃N₄, SiC and SrTiO₃ can have grain boundaries characterized by the presence of a thin intergranular amorphous film of nearly constant thickness, in some cases (e.g. Si₃N₄) almost independent of the orientation of the bounding grains, but dependent on the composition of the ceramic. Microscopy techniques such as high‐resolution lattice fringe imaging, Fresnel fringe imaging and diffuse dark field imaging have been applied to the study of intergranular glassy films. The theme of the current investigation is the use of Fresnel fringes and Fourier filtering for the measurement of the thickness of intergranular glassy films. Fresnel fringes hidden in high‐resolution micrographs can be used to objectively demarcate the glass–crystal interface and to measure the thickness of intergranular glassy films. Image line profiles obtained from Fourier filtering the high‐resolution micrographs can yield better estimates of the thickness. Using image simulation, various kinds of deviation from an ideal square‐well potential profile and their effects on the Fresnel image contrast are considered. A method is also put forth to objectively retrieve Fresnel fringe spacing data by Fourier filtering Fresnel contrast images. Difficulties arising from the use of the standard Fresnel fringe extrapolation technique are outlined and an alternative method for the measurement of the thickness of intergranular glassy films, based on zero‐defocus (in‐focus) Fresnel contrast images is suggested. The experimental work is from two ceramic systems: Lu‐Mg‐doped Si₃N₄ and SrTiO₃ (stoichiometric and nonstoichiometric). Further, a comparison is made between the standard high‐resolution lattice fringe technique, the standard Fresnel fringe extrapolation technique and the methods of analyses introduced in the current work, to illustrate their utility and merits. Taking experimental difficulties into account, this work is intended to be a practical tool kit for the study of intergranular glassy films.     

Te concentration dependent photoemission and inverse-photoemission study of FeSe1?xTex

We have characterized the electronic structure of FeSe_1−xTe_x for various x values using soft x-ray photoemission spectroscopy (SXPES), high-resolution photoemission spectroscopy (HRPES) and inverse photoemission spectroscopy (IPES). The SXPES valence band spectral shape shows that the 2 eV feature in FeSe, which was ascribed to the lower Hubbard band in previous theoretical studies, becomes less prominent with increasing x. HRPES exhibits systematic x dependence of the structure near the Fermi level (E_F): its splitting near E_F and filling of the pseudogap in FeSe. IPES shows two features, near E_F and approximately 6 eV above E_F; the former may be related to the Fe 3d states hybridized with chalcogenide p states, while the latter may consist of plane-wave-like and Se d components. In the incident electron energy dependence of IPES, the density of states near E_F for FeSe and FeTe has the Fano lineshape characteristic of resonant behavior. These compounds exhibit different resonance profiles, which may reflect the differences in their electronic structures. By combining the PES and IPES data the on-site Coulomb energy was estimated at 3.5 eV for FeSe.     

Polyaniline sensitized Pt@TiO2 for visible-light-driven H2 generation

Polyaniline is a typical conducting polymer with high migration electron rate, good stability, eco-friendly properties, and high absorption coefficients for visible light. In the present study, polyaniline decorated Pt@TiO₂ for visible light-driven H₂ generation is reported for the first time. The above-mentioned nanocomposite is prepared through a simple oxidative-polymerization and characterized by infrared spectroscopy, transmission electron microscopy, X–ray diffraction, thermogravimetric analysis, and ultraviolet–visible diffuse reflectance spectra. Polyaniline modification improves the absorption of the nanocomposite in visible light region via a photosensitization effect similar to dye–sensitization but does not influence the crystal structure and size of Pt@TiO₂. The polyaniline modified Pt@TiO₂ exhibits a remarkable visible light activity (61.8 μmol h⁻¹ g⁻¹) and good stability for H₂ generation (with an average apparent quantum yield of 10.1%) with thioglycolic acid as an electron donor. This work provides new insights into using conducting polymers, including polyaniline, as a sensitizer to modify Pt@TiO₂ for visible-light hydrogen generation.     

Radiation- and Photo-Induced Oxidation Pathways of Methionine in Model Peptide Backbone under Anoxic Conditions

Within the reactive oxygen species (ROS) generated by cellular metabolisms, hydroxyl radicals (HO^•) play an important role, being the most aggressive towards biomolecules. The reactions of HO^• with methionine residues (Met) in peptides and proteins have been intensively studied, but some fundamental aspects remain unsolved. In the present study we examined the biomimetic model made of Ac-Met-OMe, as the simplest model peptide backbone, and of HO^• generated by ionizing radiation in aqueous solutions under anoxic conditions. We performed the identification and quantification of transient species by pulse radiolysis and of final products by LC-MS and high-resolution MS/MS after γ-radiolysis. By parallel photochemical experiments, using 3-carboxybenzophenone (CB) triplet with the model peptide, we compared the outcomes in terms of short-lived intermediates and stable product identification. The result is a detailed mechanistic scheme of Met oxidation by HO^•, and by CB triplets allowed for assigning transient species to the pathways of products formation.     

Measurements of Photon Mass Attenuation Coefficients for Ge and BGO Crystals at 10 Me V

The photon mass attenuation coefficients of the important materials for γ-ray detection, Ge and BGO (Bi₄Ge₃O₁₂) crystals, have been measured for 10.0 MeV γ-rays. The measurement system using the laser-Compton backscattering γ-rays and the high-resolution high-energy photon spectrometer has been developed and utilized. The effectiveness of the system achieving the total systematic uncertainties of 0.5% for the measurements of the photon mass attenuation coefficients was demonstrated. It was shown that the measured photon mass attenuation coefficients, 318.1 ± 1.7 [cm²/g] for the Ge crystal and 425.2 ± 2.4 [cm²/g] for the BGO crystal, agree within the achieved experimental uncertainties with the evaluated values including atomic and nuclear processes at 10.0 MeV.     

Effective Characterization of DNA Ligation Kinetics by High-Resolution Melting Analysis

High-resolution melting (HRM) analysis has been improved and applied for the first time to quantitative analysis of enzymatic reactions. By using the relative ratios of peak intensities of substrates and products, the quantitativity of conventional HRM analysis has been improved to allow detailed kinetic analysis. As an example, the ligation of sticky ends through the action of T4 DNA ligase has been kinetically analyzed, with comprehensive data on substrate specificity and other properties having been obtained. For the first time, the kinetic parameters (k_obs and apparent K_m) of sticky-end ligation were obtained for both fully matched and mismatched sticky ends. The effect of ATP concentration on sticky-end ligation was also investigated. The improved HRM method should also be applicable to versatile DNA-transforming enzymes, because the only requirement is that the products have T_m values different enough from the substrates.     

Growth mechanism and gas-sensing characteristics of organic-additive-free zinc oxide of various shapes

Zinc oxide is widely used in gas sensors, solar cells, and photocatalysts because of its wide bandgap and exciton binding energy of 60 meV in various metal oxides. To use ZnO as a gas sensor, it is necessary to synthesize it with surface defects and a large specific surface area. In this study, hydrothermal synthesis without surfactants was employed to obtain organic-additive-free ZnO. For morphology control, we varied the ratio of the hydroxide ion concentration to the zinc ion concentration. To confirm the growth mechanism of ZnO, we performed X-ray diffraction, scanning electron microscopy, and transmission electron microscopy analyses. Raman spectroscopy and photoluminescence measurements were performed to analyze the surface properties. The Brunauer–Emmett–Teller method and probe stations were used to measure the specific surface area and sensitivity of the gas sensor, respectively. The results confirmed that flower-shaped ZnO is the most suitable gas-sensing material.