C/纳米[Ni0.96Co0.04(OH)2-C]混合超级电容器

以纳米Ni0.96Co0.04(OH)2-C复合材料[Ni0.96Co0.04(OH)2(90%)+FJC(10%)]为正极,活性炭为负极,KOH水溶液为电解液组成混合超级电容器.其工作电压为0.75～1.5 V;适合的充电方法是恒流恒压充电;具有快速充电、高倍率放电和循环性良好的特点.8min可充满80%容量,2 200W/kg(以正、负极活性物总质量计算)放电时,比能量达23.2Wh/kg.     

基于支路追加法的配电网混联线路电力线载波通信信道建模

提出了一种基于支路追加法的中压配电网混联线路的电力线载波通信信道建模方法。根据配电网拓扑结构,利用支路追加法,逐一追加网络各条支路,列写该支路的伏安特性独立方程和基尔霍夫定律电流方程,生成一组具有唯一解的网络矩阵方程。通过该矩阵方程中各未知变量的比值关系,求解信号的传输函数,分析信道的传输特性。当配电网网络结构发生改变时,只需在原代数矩阵方程基础上,增减矩阵中的相关行与列即可得修改后的新矩阵方程。该建模方法原理清晰,运算量小,适用于树形网络、手拉手网络及环网等各种拓扑结构。仿真及实验测试验证了所提方法的正确性。     

燃煤电厂新型静电布袋复合除尘器的开发与气流分布试验研究

提出一种新的燃煤电厂静电布袋复合除尘器，分析其技术经济特点，并提出一些需解决的技术闯题。其中静电除尘单元与布袋除尘单元之间的结合形式是一个技术难点，将影响整个除尘系统的效率和布袋的使用寿命。研究开发出一套气流分布试验台，采用一定形式的气流分布板进行冷态试验研究，分析了几个关键截面的流场，掌握了气流分布规律，确定了气流分布板的开孔分布，为进一步进行中试试验和实现工程化奠定了基础。研究表明，采用具有独创性的结合形式后，该新型静电布袋复合除尘器应用于工程后将具有非常大的经济和环保优势。     

Copper‐Free Clickable Coatings

The copper‐catalyzed azide–alkyne 1,3‐dipolar cycloaddition (CuAAC) is extensively used for the functionalization of well‐defined polymeric materials. However, the necessity for copper, which is inherently toxic, limits the potential applications of these materials in the area of biology and biomedicine. Therefore, the first entirely copper‐free procedure for the synthesis of clickable coatings for the immobilization of functional molecules is reported. In the first step, azide‐functional coatings are prepared by thermal crosslinking of side‐chain azide‐functional polymers and dialkyne linkers. In a second step, three copper‐free click reactions (i.e., the Staudinger ligation, the dibenzocyclooctyne‐based strain‐promoted azide–alkyne [3+2] cycloaddition, and the methyl‐oxanorbornadiene‐based tandem cycloaddition?retro‐Diels?Alder (crDA) reaction) are used to functionalize the azide‐containing surfaces with fluorescent probes, allowing qualitative comparison with the traditional CuAAC.     

激光-感应复合熔覆Ni基WC复合层的工艺研究

为了提高熔覆效率与消除熔覆层的裂纹,采用激光-感应复合熔覆的方法在A3表面获得了无气孔与裂纹的Ni基WC复合层。研究了不同的加工参量对复合层质量的影响,结果表明,随着激光比能的增加,粉末面密度增加;在相同的激光比能条件下,随着粉末面密度增加,熔覆层的高度增加,稀释率减小;在相同的粉末面密度条件下,随着激光比能的增加,熔覆层的宽度略有增加。此外,相对于单纯的激光熔覆技术,激光-感应复合熔覆的效率约可以提高5倍。在激光-感应复合熔覆过程中,熔覆层与基材间的温度梯度大大降低,这是Ni基WC复合层无裂纹的关键原因。     

机械化学促成可调谐光-电多功能响应二维杂化钙钛矿材料

二维有机-无机杂化钙钛矿因在光伏、光电子等领域的巨大应用潜力而备受关注.此外,该类材料具有突出的结构可调性和材料稳定性,为功能性质的设计调控及器件应用提供了丰富的材料设计平台.然而,将多种物理通道的性质整合实现材料的多功能性仍具有挑战性,而对其进行快速有效的调节更是难上加难.迄今为止,尚未成功实现可调谐的光电多通道响应...     

Chl1, an ATP-Dependent DNA Helicase,Inhibits DNA:RNA Hybrids Formation at DSB Sites to Maintain Genome Stability in S. pombe

As an ATP-dependent DNA helicase, human ChlR1/DDX11 (Chl1 in yeast) can unwind both DNA:RNA and DNA:DNA substrates in vitro. Studies have demonstrated that ChlR1 plays a vital role in preserving genome stability by participating in DNA repair and sister chromatid cohesion, whereas the ways in which the biochemical features of ChlR1 function in DNA metabolism are not well understood. Here, we illustrate that Chl1 localizes to double-strand DNA break (DSB) sites and restrains DNA:RNA hybrid accumulation at these loci. Mutation of Chl1 strongly impairs DSB repair capacity by homologous recombination (HR) and nonhomologous end-joining (NHEJ) pathways, and deleting RNase H further reduces DNA repair efficiency, which indicates that the enzymatic activities of Chl1 are needed in Schizosaccharomyces pombe. In addition, we found that the Rpc37 subunit of RNA polymerase III (RNA Pol III) interacts directly with Chl1 and that deletion of Chl1 has no influence on the localization of Rpc37 at DSB site, implying the role of Rpc37 in the recruitment of Chl1 to this site.     

Research on a New Hybrid System of a Tyre Crane Using Supercapacitors

Research on a hybrid system of a crane is a focus which considers environmental protection and energy saving.A new environmental protection and energy saving hybrid system of tyre crane.which utilizes supercapacitors as the energy store device,is presented.Analyzing the pdneiple of supercapacitors,the model of the crane's hybrid system is set up in this paper,and the model of main blocks are established.Through simulation analyzing,the energy saving result of the new hybrid system is obtained,and the good application value of the new hybrid system is explained.     

四川盆地剑阁地区多层系储层叠前描述

近期龙岗62井长兴组及剑门102井须家河组须三段获得重大突破,证实长兴组生物礁储层及须家河组碎屑岩储层均具有较大的勘探潜力。通过对研究区资料特征进行分析对比,在攻关中采用了纵横波阻抗叠前同时反演、体曲率属性、瞬时振幅属性等针对性技术,准确地刻画了生物礁台缘发育相带,预测了碎屑岩裂缝发育和油气有利聚集区,为研究区下一步井位部署提供了准确的资料基础,并形成了一套有效的技术流程。     

Theranostic Agent Combining Fullerene Nanocrystals and Gold Nanoparticles for Photoacoustic Imaging and Photothermal Therapy

Developing photoactivatable theranostic platforms with integrated functionalities of biocompatibility, targeting, imaging contrast, and therapy is a promising approach for cancer diagnosis and therapy. Here, we report a theranostic agent based on a hybrid nanoparticle comprising fullerene nanocrystals and gold nanoparticles (FGNPs) for photoacoustic imaging and photothermal therapy. Compared to gold nanoparticles and fullerene crystals, FGNPs exhibited stronger photoacoustic signals and photothermal heating characteristics by irradiating light with an optimal wavelength. Our studies demonstrated that FGNPs could kill cancer cells due to their photothermal heating characteristics in vitro. Moreover, FGNPs that are accumulated in tumor tissue via the enhanced permeation and retention effect can visualize tumor tissue due to their photoacoustic signal in tumor xenograft model mice. The theranostic agent with FGNPs shows promise for cancer therapy.