Ti-42.85Al-12.3Nb-2Cr合金相组成对高温抗氧化性能的影响

通过热处理获得了合金Ti-42.85Al-12.3Nb-2Cr铸态(As-cast)、炉冷(FC)和水淬(WQ)3种含不同组成相和微观组织的合金,研究了这3种合金在1000℃静止空气中的断续氧化行为,采用XRD、SEM和EPMA分析了氧化膜的结构和组成.研究表明,Nb的加入能够显著提高合金的抗氧化性,但是高含量Nb的加入导致高温亚稳β相在室温组织中残留,β相使外层氧化膜的粘附性变差,促使氧化膜整体剥落.通过热处理消除β相后,获得的以γ α2为主相的炉冷合金中形成了有效的保护性氧化膜.     

Co-Ni-Al-Ti系L2_1/L1_2型双相金属间化合物合金的显微组织和力学行为研究

对于由 L2 1 型 ( Co,Ni) 2 Al Ti和 L12 型 ( Co,Ni) 3( Al,Ti)两种有序相组成的 Co- Ni- Al- Ti系新型金属间化合物高温结构用合金 ,经热处理后获得不同显微组织的高温压缩和室温断裂等力学行为进行了分析研究 ,确立了合金成分、显微组织和机械性能之间的关系 ,找到了进一步提高高温强度和室温塑性的途径。     

NiAl-Fe金属间化合物超塑性的研究

本文研究了金属间化合物NiAl－Fe的超塑性行为及其机理结果表明：该合金的显微组织由β－NiAl相基体和γ－Ni无序固溶体相组成．在1123—1253K,1．04×10(－4)－1．04×10(－2)s(－1)拉伸变形时,表现超塑性行为．最大伸长率233％,超塑性变形试样的断口呈韧性特征,在断裂区没有空洞产生,通过SEM分析发现,γ相在变形过程中发生碎化、β相存在动态再结晶     

Effect of minor boron addition on mechanical properties of wrought TiAl alloy

1　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅγ ＴｉＡｌｂａｓｅｄｉｎｔｅｒｍｅｔａｌｌｉｃａｌｌｏｙｓｈａｖｅｒｅ ｃｅｎｔｌｙｒｅｃｅｉｖｅｄｍｏｒｅａｎｄｍｏｒｅａｔｔｅｎｔｉｏｎｂｅｃａｕｓｅｏｆｔｈｅｉｒｐｏｔｅｎｔｉａｌａｓａｄｖａｎｃｅｄｈｉｇｈ ｔｅｍｐｅｒａｔｕｒｅｓｔｒｕｃ ｔｕｒａｌｍａｔｅｒｉａｌｓ.ＭｉｃｒｏｓｔｒｕｃｔｕｒｅｈａｓｂｅｅｎｆｏｕｎｄｔｏｈａｖｅａｃｏｎｓｉｄｅｒａｂｌｅｅｆｆｅｃｔｏｎｍｅｃｈａｎｉｃａｌｐｒｏｐｅｒｔｉｅｓｏｆＴｉＡｌａｌｌｏｙｓ,ｗｈｉｌｅｄｕｐｌ…     

Microstructure and mechanical properties of mechanically alloyed and spark plasma sintered amorphous–nanocrystalline Al65Cu20Ti15 intermetallic matrix composite reinforced with TiO2 nanoparticles

Multiphase Al₆₅Cu₂₀Ti₁₅ intermetallic alloy matrix composite, dispersed with 10 wt.% of TiO₂ nanoparticles, has been processed by mechanical alloying, followed by spark plasma sintering under pressure in the temperature range of 623–873 K. Differential scanning calorimetry and X-ray diffraction suggest that equilibrium crystalline phases evolve from the amorphous or intermediate crystalline phases. Transmission electron microscopy shows that the composite sintered at 873 K has partially amorphous microstructure, with dispersion of equilibrium, crystalline, intermetallic precipitates of Al₅CuTi₂, Al₃Ti, and Al₂Cu of 25–50 nm size, besides the TiO₂. The composite sintered at 873 K exhibits little porosity, hardness of 5.6 GPa, indentation fracture toughness in the range of 3.1–4.2 MPa√m, and compressive strength of 1.1 GPa. Indentation crack deflection by TiO₂ particle aggregates causes increase in fracture resistance with crack length, and suggests R-curve type behaviour. The study provides guidelines for processing high strength amorphous–nanocrystalline intermetallic composites based on the Al–Cu–Ti ternary system.     

铝/镀锌钢板CMT熔钎焊界面区组织与接头性能

采用冷金属过渡方法(CMT)对铝和镀锌钢板异种材料进行了熔钎焊连接.使用扫描电镜(SEM)、能谱分析(EDAX)和拉伸试验对焊接接头界面区显微组织及接头性能进行研究.试验结果表明,铝和镀锌钢能得到成形良好的搭接接头.在CMT熔钎焊的方法下,形成了中间厚两边薄的界面区,并且在熔化区一侧边缘形成了富锌区,界面区组织成分也由致密的FeAl3金属间化合物层变为α固溶体和FeAl3化合物混合层,而富锌区是由富铝的α固溶体和残留的铝组成.在进行拉伸试验时,断裂发生在铝母材的热影响区,接头强度为72.09MPa.     

高速电弧喷涂Fe-Al金属间化合物涂层

采用粉芯丝材和高速电弧喷涂技术(HVAS)制备了Fe-Al金属间化合物涂层,并研究了涂层的显微组织和室温至650℃的滑动摩擦磨损性能.结果表明:Fe-Al涂层的平均成分为Fe-20.0Al-14.1O(摩尔分数,%),主要相是Fe3Al,FeAl,α-Fe,Al2O3及少量Al;涂层具有较高的结合强度和硬度、较低的孔隙率及较高的高温耐磨性;高温下磨损面形成了大面积的氧化物保护层,降低了涂层的摩擦因数,而剥层磨损是涂层的主要磨损机制.涂层中Fe3Al和FeAl金属间化合物相较高的高温强度和硬度能有效地阻碍裂纹的产生、扩展及扁平颗粒的断裂,从而使Fe-Al涂层表现出优异的高温耐磨性.     

超重力对燃烧合成NiAl金属间化合物的影响

在超重力条件下，采用Ni、Al粉末为原料，燃烧合成NiAl金属间化合物。对所得产物进行了XRD、SEM分析、密度测定和晶粒尺寸计算。结果表明：超重力下燃烧合成所得产物为单相NiAl块体材料，断口晶粒变小，密度随离心力增大而增大，晶粒尺寸随离心力增大而减小，单一块体材料中晶粒尺寸自上而下减小。     

TiAl金属间化合物与42CrMo钢的真空扩散连接

对TiAl金属间化合物与 4 2CrMo钢进行了真空扩散连接。采用扫描电镜对连接接头的显微组织和成分分布进行了初步地分析。研究发现 ,母材与中间层发生了扩散反应 ,采用加入中间层的真空扩散连接TiAl金属间化合物与 4 2CrMo钢具有良好的可焊性。     

Growth morphology and crystallography of precipitate in a new high-temperature structural intermetallic Ti–40Al–10Fe

Based on TiAl alloys bearing high levels of Nb, which are prospective high-temperature intermetallics, a new dual-phase alloy (Ti–40Al–10Fe (at%)) with precipitate growth direction close to the slipping plane normal of the matrix was developed. Transmission electron microscopy revealed that the annealed alloy was composed of equiaxed grains of τ₂-TiAl₂Fe and γ-TiAl phases. Aging treatment at 1000 °C produced polygon-shaped γ-TiAl precipitate from the τ₂-TiAl₂Fe matrix. The precipitation reaction of the face-centered cubic structure of τ₂-TiAl₂Fe into the ordered face-centered tetragonal structure of γ-TiAl phase was systematically investigated in terms of crystallographic features, including mutual orientation relationship, growth direction, habit plane, side facets, and interfacial dislocation structure. The observed growth direction <973> was close to the normal of the slip plane {111}, with a discrepancy angle of ∼20°. Thus, the observed two-phase microstructure might significantly improve strengthening. It could also be quantitatively controlled by selection of precipitate and matrix with phase structures and lattice parameters that meet a certain requirement.