新型阳离子聚丙烯酰胺微粒的研究 Ⅱ.含PEO支链阳离子聚丙烯酰胺微粒的絮凝性能

以丙烯酰胺、丙烯酰氧基乙基三甲基氯化铵、聚氧乙烯大单体和N ,N’ -亚甲基双丙烯酰胺为单体 ,进行四元反相微乳液共聚合 ,制备出新型含PEO支链的阳离子微粒絮凝剂。然后用该微粒絮凝剂分别对针叶木纸浆和特种纸白水进行了助留和絮凝性能的研究 ,结果表明 ,本新型微粒具有能单独使用、絮凝效果好和抗剪切性强等优点。     

反偏移法三维波动方程正演

三维地震资料的处理与解释往往都需要三维正演模型给予验证，以得到准确的处理、解释结果。本文提出的三维正演方法是一种偏移算法的逆运算方法－有限差分反偏移法。这一算法具有算法简单、运算量小及深度方向分辨率高的特点，是一种快速、高精度的正演算法。反偏移法虽是偏移算法的逆运算法，却出现常规偏移算法中所没有的很多问题。为此，本文进行了三种不同反偏移方法试验，并采用了一种新的浮动坐标变换，使正演结果精度得到很大     

GENERALIZED INVERSE GROUP OF SIGNAL AND ITS IMPLEMENTATION WITH NEURAL NETWORKS

A new concept, the generalized inverse group (GIG) of signal, is firstly proposed and its properties, leaking coefficients and implementation with neural networks are presented. Theoretical analysis and computational simulation have shown that (1) there is a group of finite length of generalized inverse signals for any given finite signal, which forms the GIG; (2) each inverse group has different leaking coefficients, thus different abnormal states; (3) each GIG can be implemented by a grouped and improved single-layer perceptron which appears with fast convergence. When used in deconvolution, the proposed GIG can form a new parallel finite length of filtering deconvolution method. On off-line processing, the computational time is reduced to O(N) from O(N2). And the less the leaking coefficient is, the more reliable the deconvolution will be.     

高层建筑损伤识别中的补偿算法

本文在已有研究工作的基础上，提出了处理激励测量信息不完备情况下的补偿算法。此方法主要针对高层建筑动力检测中强迫激励的情况，是一种基于时域的识别方法，该方法实际上是利用客观工程实际中结构系统激励所具有的物理持征作为识别计算的辅助条件，来解决测量信息的不完备性问题。算例分析表明了该方法的可行性。     

A study of suppression of vapor explosions by adding inversely soluble polymers

The mechanism of the suppression of vapor explosions by adding inversely soluble polymers in water is studied. Vapor explosion experiments and quench experiment are conducted using a silver test piece. Polymetric solution (polyethylene oxide), of concentrations from 0 to 500 wppm, whose normalized viscosity (by water) varies from 1.00 to 2.00, is used. No vapor explosion is observed in the aqueous polymer solution at a concentration higher than 200 wppm. Quench experiments using the silver test piece submerged in the polymer solution and water are performed in order to examine the stability of film boiling. The suppression of the vapor film collapse is attributed to the precipitation of polyethylene as a gel around the vapor film. © 2002 Wiley Periodicals, Inc. Heat Trans Asian Res, 31(4): 297–306, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.10037     

新型阳离子聚丙烯酰胺微粒的研究--含PEO支链阳离子聚丙烯酰胺微粒的合成、助留性能及作用机理

本文采用反相微乳液聚合的方法合成了丙烯酰胺(AM)/丙烯酰氧基乙基三甲基氯化铵(AD-AMQUAT)/聚氧乙烯大单体(PEO-A)/N,N'-亚甲基双丙烯酰胺(Bis)的四元共聚物微粒.研究了该微粒助留剂的结构与性能.这种微粒和纸纤维能够通过离子键和氢键作用显著地增强助留效果.     

基于旋量和臂形标志的机器人运动学逆解计算

讨论了用旋量和指数积公式计算PUMA类型6自由度机器人运动学逆解的方法。在子问题的计算过程中，通过引入臂形标志来选取关节变量的合理解，以得到运动学逆解的唯一解。这种方法避免了对无效解的计算，可以减少计算量，提高计算效率。通过一个实验机器人的运动学逆解计算验证了算法的有效性。     

混凝土大坝导温系数反演及其随时间变化的规律

随着时间的推移,混凝土的导温系数将发生变化,为了了解参数随时间的变化规律,利用原型观测资料对导温系数进行分段反演,从而拟合出大坝混凝土导温系数随时间的变化规律.     

Material constant sensitivity boundary integral equation for anisotropic solids

In this paper, the material constant sensitivity boundary integral equation is presented, and its numerical solution proposed, based on boundary element techniques. The formulation deals with plane problems with general rectilinear anisotropy. Expressions for the computation of sensitivities for displacements, tractions, strains and stresses are derived, both for boundary and interior points. The sensitivities can be computed with respect to the bulk material properties or to the properties of part of the domain (inclusions, coatings, etc.). To assess the accuracy of the proposed approach, the computed results are compared to analytical ones derived from exact solutions obtained by complex potential theory, when possible, or finite difference derivatives otherwise. Copyright © 2005 John Wiley & Sons, Ltd.     

Negative effect of [bmim][PF6] on the catalytic activity of alcohol dehydrogenase: mechanism and prevention

BACKGROUND: [bmim][PF₆] is a hydrophobic ionic liquid which could be considered as an environmentally friendly solvent for biocatalysis. In pure [bmim][PF₆], however, alcohol dehydrogenase from yeast (YADH) has no catalytic activity. The aim of the present work was (1) to quantitatively study the negative effect of [bmim][PF₆] on the catalytic activity of YADH and the related mechanism and (2) to made an attempt to lessen the negative effect of [bmim][PF₆] on YADH by microemulsifying [bmim][PF₆]. RESULTS: The activity of YADH in the homogeneous solution formed by H₂O, CH₃CH₂OH and [bmim][PF₆] decreased rapidly with the increase of the molar fraction of [bmim][PF₆]. The inhibitory effect of [bmim][PF₆] on YADH was probably caused by the competition of the imidazole group of [bmim][PF₆] with the coenzyme NAD⁺ for the binding sites on YADH. In a water‐in‐[bmim][PF₆] microemulsion, YADH was catalytically active due to the formation of the interfacial membrane of the nonionic surfactant TritonX‐100, which separated YADH from [bmim][PF₆] and avoided the direct inactivation of [bmim][PF₆] on YADH. Under optimal conditions, the activity of YADH was as high as 51 µmol L^?1 min^?1. CONCLUSION: [bmim][PF₆] was an inhibitor of YADH and its negative effect on YADH could be lessened by its microemulsification. Copyright © 2008 Society of Chemical Industry