Constructing a novel single-layer white organic light-emitting device through a new sky-blue fluorescent bipolar host

A novel device concept was realized for simple single-layer small-molecule white organic light emitting devices. The single organic active layer here is simply comprised of a newly synthesized sky-blue fluorescent bipolar host (TPASO) and a common orange phosphorescent dopant. Suppressed singlet Föster energy transfer induced by a low-concentration doping and spontaneous high- to low-lying triplet energy transfer, respectively, lead to sky-blue fluorescence from TPASO and orange phosphorescence from the dopant. The resulting two-organic-component device exhibits a low turn-on voltage of 2.4 V, maximum current/power efficiencies up to 11.27 ± 0.02 cd A⁻¹ and 14.15 ± 0.03 lm W⁻¹, and a warm-white CIE coordinate of (0.42, 0.45) at 1000 cd m⁻².     

Photoelectric Synaptic Plasticity Realized by 2D Perovskite

Recently, several light‐stimulated artificial synaptic devices have been proposed to mimic photonic synaptic plasticity for neuromorphic computing. Here, the photoelectric synaptic plasticity based on 2D lead‐free perovskite ((PEA)₂SnI₄) is demonstrated. The devices show a photocurrent activation in response to a light stimulus in a neuron‐like way and exhibit several essential synaptic functions such as short‐term plasticity (STP) and long‐term plasticity (LTP) as well as their transmission based on spike frequency control. The strength of synaptic connectivity can be effectively modulated by the duration, irradiance, and wavelength of light spikes. The ternary structure of (PEA)₂SnI₄ causes it to possess varied photoelectric properties by composition control, which enhances the complexity and freedoms required by neuromorphic computing. The physical mechanisms of the memory effect are attributed to two distinct lifetimes of photogenerated carrier trapping/detrapping processes modulated by controlling the proportion of Sn vacancies. This work demonstrates the great potential of (PEA)₂SnI₄ as a platform to develop future multifunctional artificial neuromorphic systems.     

Harnessing “Click”‐Type Chemistry for the Preparation of Novel Electronic Materials

Sequence‐independent or “click”‐type chemistry is applied for the preparation of novel π‐conjugated oligomers. A variety of bi‐functional monomers for Wittig–Horner olefination are developed and applied in a sequential protection–deprotection process for the preparation of structurally similar π‐conjugated oligomers. Selected oligomers are incorporated as the organic semiconductors in light‐emitting diodes and a field‐effect transistor, demonstrating the potential of the approach.     

基于氧化石墨烯功能材料提高PEDOT:PSS电极性研究

基于聚(3,4-乙烯二氧噻吩)-聚苯乙烯磺酸(PE DOT:PSS)/氧化石墨烯(GO)混合溶液,利用旋涂法制 备了高电导率透明阳极,并采用硫酸(H₂SO₄)浸渍处理的方式,使其导电特性进一步 增强。采用最佳方式 处理的PEDOT:PSS/GO混合薄膜在厚度为40 nm时,其方阻为80 Ω/□,在550 nm时的透过率达到87.7％。 基于表面形貌的AFM图,吸收光谱和拉曼光谱,在少量氧化石墨烯掺杂和硫酸处理后,PSS －和PEDOT⁺链 相分离,使得PEDOT:PSS的结构发生了变化,提高了混合薄膜的电导率。与ITO和纯PEDOT: PSS分 别作为阳极的OLED器件相比,采用优化的PEDOT:PSS/GO混合薄膜作为阳极时的OLED器件具有 最低 的启亮电压和最高的电流效率,其最大亮度是纯PEDOT:PSS作为阳极的OLED的1.7倍。较高 的透过率, 电导率和HOMO能级,尤其是表面形貌的改变都有利于PEDOT:PSS/GO阳极OLED器件性能的改善 。     

单轴晶体双折射率随温度变化的双光路测量

为了研究单轴晶体最大双折射率在某一波长下随温度的变化情况,根据偏振光干涉的理论分析,推导出了单轴晶体最大双折射率随温度变化的解析式.在此基础上,设计、建立了一套双光路对比测试实验系统.利用该实验系统对石英晶体样品进行测试,获得了其实验数据变化曲线,并总结出了在测试波长下,石英晶体最大双折射率随温度变化的数学式.结果表明,单轴晶体在某一波长下的最大双折射率基本上与温度成线性关系;实验过程中,只要精确调整仪器,并注意控制好实验所需温度,其测量结果是可靠的.     

简并量子拍频三能级系统中的光场压缩效应

本文讨论了V-型简并量子拍频三能级原子与单模相干辐射场相互作用时的动力学行为，并研究了光场的压缩效应。     

时空域三维结构图象噪声及信噪比测试

微光ＣＣＤ电视系统性能测试是微光成象技术的重要组成部分。本文提出了时空域三维结构图象噪声的测试模型，建立了测试和分析系统，对微光ＣＣＤ电视系统信号和噪声进行测试与分析，并且分别给出了时间域噪声和空间域噪声分布情况的三维曲线。     

TN—LCD电光特性曲线的凸起现象

研究了用白光及单色光作入射光的扭曲向列相液晶显示器电光特性曲线的凸起部分，指出对于ＴＮ－ＬＣＤ的电光特性曲线出现凸起现象的必然性。最后定性地分析了在商品化的ＴＮ－ＬＣＤ中，将起偏偏振片的偏振方向置于与摩擦方向正交的原因。     

The performance of innovative daylighting systems

Innovative daylighting systems have four key aims; to increase daylight levels deep within rooms, to improve daylight uniformity, to control direct sunlight and to reduce glare. Results from experimental studies at the Building Research Establishment (BRE) indicated that the systems tested (prismatic glazing, prismatic film, mirrored louvres and light shelves) usually reduced illuminances at the rear of rooms compared with unshaded windows. It is concluded that, in the UK at least, innovative daylighting systems should be designed primarily as shading devices, controlling glare while admitting more daylight than conventional blinds.