氨氮监测中样品蒸馏预处理对结果的影响分析

氨氮监测采用预蒸馏处理后，比色测定结果明显偏低。在样品预蒸馏处理过程中，硼酸作为吸收液，使显色时溶液pH值偏低，导致显色不充分是其主要影响因素。通过采取增加显色剂加入量的方法，解决了显色pH值偏低的问题，得到满意的测定结果。     

The GENIUS-test-facility—first results on background from Rn daughters

GENIUS-TF (Nucl. Instr. and Meth. A 511 (2003) 341; Nucl. Instr. and Meth. A 481 (2002) 149.) is a test-facility for the GENIUS project (GENIUS-Proposal, 20 November 1997; Z. Phys. A 359 (1997) 351; CERN Courier, November 1997, 16; J. Phys. G 24 (1998) 483; Z. Phys. A 359 (1997) 361; in: H.V. Klapdor-Kleingrothaus, H. Pas. (Eds.), First International Conference on Particle Physics Beyond the Standard Model, Castle Ringberg, Germany, 8–14 June 1997, IOP Bristol (1998) 485 and in Int. J. Mod. Phys. A 13 (1998) 3953; in: H.V. Klapdor-Kleingrothaus, I.V. Krivosheina (Eds.), Proceedings of the Second International Conference on Particle Physics Beyond the Standard Model BEYOND’ 99, Castle Ringberg, Germany 6–12 June 1999, IOP Bristol (2000) 915), a proposed large scale underground observatory for rare events which is based on operation of naked germanium detectors in liquid nitrogen for an extreme background reduction. Operation of naked Ge crystals in liquid nitrogen has been applied routinely already for more than 20 years by the CANBERRA Company for technical functions tests (CANBERRA Company, private communication, 5 March 2004.), but it never had found entrance into basic research. Only in 1997 first tests of application of this method for nuclear spectroscopy have been performed, successfully, in Heidelberg (Klapdor-Kleingrothaus et al., 1997, 1998; J. Hellmig and H.V. Klapdor-Kleingrothaus, 1997).

On May 5, 2003 the first four naked high-purity germanium detectors (total mass 10.52 kg) were installed in liquid nitrogen in the GENIUS Test Facility at the Gran Sasso underground laboratory. Since then the experiment has been running continuously, testing for the first time the novel technique in an underground laboratory and for a long-lasting period.

In this work, we present the first analysis of the GENIUS-TF background after the completion of the external shielding, which took place in December 2003. We focus especially on the background coming from ²²²Rn daughters. This is found to be at present by a factor of 200 higher than expected from simulation. It is still compatible with the scientific goal of GENIUS-TF, namely to search for cold dark matter by the modulation signal, but on the present level would cause serious problems for a full GENIUS—like experiment using liquid nitrogen.     

Generation of interfacial instabilities in charged electrified viscous liquid films

This study is concerned with the stability of a two-dimensional incompressible conducting liquid film surrounded by a passive conducting medium, when an electric field is applied in a direction parallel to the initially flat bounding fluid interfaces. Currents generate charges at the bounding interfaces which in turn affect the stress balances there. In the absence of an electric field, the viscous liquid film is stable (instability can be induced by the inclusion of van der Waals forces for ultra thin films). A complete model is presented, at arbitrary Reynolds number, which accounts for conductivity and permittivity contrasts between the fluid and surrounding medium, as well as surface tension. The linear stability of the system is considered for arbitrary Reynolds numbers and it is shown that the stable film can become unstable if, (i) σ _R ɛ _p >1, or (ii) σ _R ɛ _p <1 and (σ _R −1)(1−ɛ _p )<0, where σ _R is the ratio of outer to inner conductivity and ε _p is the ratio of inner to outer permittivity. Instability is possible only if the electric field is non-zero and the scalings near bifurcation points that can be used to construct nonlinear theories are calculated. Several asymptotic limits are also considered including zero Reynolds numbers and short or long waves. The instability criteria given above are constructed explicitly in the case of Stokes flow.     

Study of liquid injection impact on the performance of new refrigerant mixtures

In this paper, the test results of liquid injection impact on the performance of new alternative refrigerant mixtures such as: R-410A, R-507, R-407C and R-404A are discussed, analysed and presented. The test results were obtained using an air-source heat pump set-up with enhanced surface tubing under various liquid injection ratios. Performance tests were conducted according to the ARI/ASHRAE standards. The performance data demonstrated that as liquid injection ratio increases, compressor head pressure and discharge temperature decrease. This has a positive effect in protecting the compressor. The effect of liquid injection on mixture behaviour varies from one mixture to another depending upon the mixture's composition. Furthermore, liquid injection appears to have a significant influence on R-410A behaviour compared to the other mixtures in question. Copyright © 2002 John Wiley & Sons, Ltd.     

绒类织物增光增艳整理

选用多功能复合型绒类织物增光增艳整理剂FSR－2，对纯棉条绒织物进行光泽整理，讨论了光泽剂、交联剂及工艺条件对整理效果的影响，得出了最佳的增光增艳整理工艺。     

Synthesis of TiO<Subscript>2</Subscript> Hybrid Molecular Imprinted Polymer for Ethofumesate Linked by Silane Coupling Agent

TiO₂ hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as testified by UV spectrometric method. KH570 modified TiO₂ nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive adsorption capacity were achieved, which made it promising in chemical sensor applications.     

陶瓷减水剂、助磨剂、增强剂的发展现状、趋势及展望

阐述了陶瓷行业所用添加剂的分类，以及目前国际上主要生产陶瓷添加剂的厂家及主要产品，详细介绍了陶瓷坯体减水剂、助磨剂、增强剂的种类、应用、性能特点和它们与陶瓷材料的作用机理，并对陶瓷添加剂的发展前景进行了展望。     

有机羧酸钠盐对PET结晶和熔融行为的影响

采用差示扫描量热仪研究了5种具有不同取代基的苯甲酸钠盐作为结晶成核剂对聚对苯二甲酸乙二醇酯（HET）结晶和熔融行为的影响，并同滑石粉进行了对比。结果表明，成核剂的加入能明显改变PET的结晶和熔融行为。苯甲酸钠、对苯二甲酸甲酯单羧酸钠和对羟基苯甲酸钠提高既汀的熔融结晶温度（Tc）分别达22．93、21．7和19．37℃，但使PET降解严重；对苯酚钠甲酸钠能够提高Tc达17．75℃且对PET相对分子质量影响很小；对苯二甲酸二钠成核作用最差。低于滑石粉。此外，成核剂的成核能力越强，PET双熔融峰中的低温峰顶温度就越高。     

阴离子表面活性剂测定方法的探讨

本文对“阴离子表面活性剂的测定方法”进行探讨,优化了显色剂、萃取剂的用量及萃取频率等分析条件,有效地降低了方法的检出浓度,提高了分析精度及准确度,节约大量试剂。本法最低检出浓度的0.019mL/L。     

HACCP在保健食品西洋参口服液生产中的应用

保健食品行业GMP的实施有利HACCP的应用推广。本文应用HACCP于传统保健食品西洋参口服液生产过程中，将生产及加工过程中危害因素降最低限度，以确保产品的质量与安全。