醋酸纤维素—纤维素增强膜的结构特征和分离性能

本文描述了醋酸纤维素－纤维素大孔增强超滤膜的结构特征一分离性能之间的关系。详细论述了膜材料含量和粘连剂含量及其分子量对膜结构和性能的影响。论述了不同配方铸膜液的膜，其孔径，水通量和截留率随操作压力的变化规律。实验证明这种高强度的ＣＡＣ膜经多次重复使用后，其结构性能保持完好。     

聚乙烯醇膜的阻醇及导电性能(Ⅱ)戊二醛交联聚乙烯醇膜

为提高直接甲醇燃料电池(DMFC)用膜的阻醇性能，采用在渗透蒸发领域广泛使用且具有良好分离效果的聚乙烯醇(PVA)为主要材料，制备了戊二醛(GA)交联PVA膜，考察了此类膜的阻醇及质子导电能力。PVA(GA)膜的阻醇效果较目前在DMFC中广泛使用的Nation膜有显著提高，但其自身不具有质子导电能力，需外加电解质溶液以提高其电导率。     

Application of the blind source separation method to feature extraction of machine sound signals

As the result of vibration emission in air, a machine sound signal carries important information about the working condition of machinery. But in practice, the sound signal is typically received with a very low signal-to-noise ratio. To obtain features of the original sound signal, uncorrelated sound signals must be removed and the wavelet coefficients related to fault condition must be retrieved. In this paper, the blind source separation technique is used to recover the wavelet coefficients of a monitored source from complex observed signals. Since in the proposed blind source separation (BSS) algorithms it is generally assumed that the number of sources is known, the Gerschgorin disk estimator method is introduced to determine the number of sound sources before applying the BSS method. This method can estimate the number of sound sources under non-Gaussian and non-white noise conditions. Then, the partial singular value analysis method is used to select these significant observations for BSS analysis. This method ensures that signals are separated with the smallest distortion. Afterwards, the time-frequency separation algorithm, converted to a suitable BSS algorithm for the separation of a non-stationary signal, is introduced. The transfer channel between observations and sources and the wavelet coefficients of the source signals can be blindly identified via this algorithm. The reconstructed wavelet coefficients can be used for diagnosis. Finally, the separation results obtained from the observed signals recorded in a semi-anechoic chamber demonstrate the effectiveness of the presented methods .     

A study on the interaction between ibuprofen and bilayer lipid membrane

Ibuprofen is a well-known nonsteroidal anti-inflammatory drug, which can interact with lipid membranes. In this paper, the interaction of ibuprofen with bilayer lipid membrane was studied by UV-vis spectroscopy, cyclic voltammetry and AC impedance spectroscopy. UV-vis spectroscopy data indicated directly that ibuprofen could interact with lipid vesicles. In electrochemical experiments, ibuprofen displayed a biphasic behavior on bilayer lipid membrane supported on a glassy carbon electrode. It could stabilize the lipid membrane in low concentration, while it induced defects formation, even removed off bilayer lipid membrane from the surface of the electrode with increasing concentration. The mechanism about the interaction between ibuprofen and supported bilayer lipid membrane was discussed.     

Effects of multiple weak interactions on the binding of phenolic compounds by polymeric adsorbents

To investigate the effects of multiple weak interactions on the binding of phenolic compounds by polymeric adsorbents, macroporous polystyrene (PS) resin and PS‐based adsorbents with different hydrogen‐bond acceptor atoms (PS CH₂( OCH₂CH₂)_n OCH₃, n = 0, 1, 2, and 3, denoted as PS‐EG₀, PS‐EG₁, PS‐EG₂, and PS‐EG₃) were prepared. The phenol adsorption strength order on these adsorbents was PS/PS‐EG₀ < PS‐EG₁ < PS‐EG₂ < PS‐EG₃, indicating that the adsorption on PS and PS‐EG₀ was driven by hydrophobic and π–π interactions, and the adsorption on PS‐EG₁, PS‐EG₂, and PS‐EG₃ was driven by a hydrogen bond in addition to hydrophobic and π–π interactions. PS‐EG₂ may adsorb a second phenol molecule on each binding site and PS‐EG₃ may adsorb second and third ones. The adsorption strength of resorcinol increased in the order of PS, PS‐EG₁, and PS‐EG₂, indicating that the adsorption was driven by 0, 1, and 2 hydrogen bonds in addition to hydrophobic and π–π interactions. Similarly, the adsorption of phloroglucinol on PS, PS‐EG₁, PS‐EG₂, and PS‐EG₃ was driven by 0, 1, 2, and 3 hydrogen bonds in addition to hydrophobic and π–π interactions because the adsorption strength increased in this order. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4652–4658, 2006     

从生产角度论述空分设备“有效产品成本”

引入空分设备“有效产品成本”概念，以气体成本算法和液体成本算法对空分设备正常产品单位成本和有效产品单位成本进行了比较，举例计算了液化装置的产品成本，提出利用“有效产品成本”概念来组织空分设备生产。     

Thermodynamic state of reinforced interpenetrating polymer networks

The free energies of mixing of two networks in the interpenetrating polymer network based on crosslinked polyurethane and poly(ester acrylate) have been determined by the vapour sorption method. It was established that the constituent networks in the IPN are not miscible. The introduction of fillers of different chemical nature increases the compatibility. The thermodynamic affinity of the fillers to the individual networks and IPN was estimated. It was established that when the free energy of interaction of one or both components of the IPN with the filler is negative, reinforcement leads to the formation of a compatible and equilibrium system. For fillers having no affinity to the polymers, compatibilization is observed, which is connected with slowing down of phase separation in the system in the presence of filler.     

小剂量辐照小鼠胸腺细胞膜流动性的变化

报道了以茈为荧光探针,探讨小剂量~(60)Co γ射线照射后小鼠胸腺细胞膜流动性的变化。结果表明,剂量在0.25-1.00Gy范围,胸腺细胞膜流动性降低与剂量之间呈明显线性关系。从0.50Gy起,辐照组荧光强度比值I_1/I_2与I_3/I_2与对照组的比较存有显著差异(P<0.05)。提示淋巴细胞膜流动性的变化可作为小剂量辐照早期效应的敏感指标。     

二硫代磷酸硫化氧钼与硫,磷添加剂的复配特性研究

研究了二烷基二硫代磷酸硫化氧钼（ＭｏＤＴＰ）摩擦改进剂及其与硫、磷、硫－磷型添加剂复合的抗磨减摩性能。试验表明，经过适当复配后，这类合活性元素的添加剂对ＭｏＤＴＰ的抗磨减摩性能均有增效作用，同一类型添加剂的活性愈高，增效作用愈显著。同时利用扫描电镜和Ｘ－射线能谱仪进行摩擦副表面膜的形貌照相及元素分析，对复合作用的机理进行了初步探讨。     

Process conditions for separating fatty acid esters by supercritical CO2

The solubilities of ethyl palmitate, ethyl oleate, ethyl eicosapentaenoate (EPA) and ethyl docosahexaenoate (DHA) in supercritical carbon dioxide were determined by a continuous flow method. The solubilities of fatty acid ethyl esters increased with pressure and decreased as the temperature was increased. An empirical equation, similar to Chrastil's equation, was used to describe the relationship between solute solubility and the density of carbon dioxide. The empirical equation was further used to qualitatively estimate the separation efficiency of isolating EPA and DHA ethyl esters from fatty acid esters. The operating conditions yielding high solubility gave fast extraction rate but resulted in low separation efficiency. Experiments were conducted to separate ethyl EPA and ethyl DHA from a model mixture containing four fatty acid ethyl esters and from esterified squid visceral oil. The experimental data compared closely with the calculated values.